Factors affecting adolescents’ use of urban public spaces in their leisure time: an exploratory study from the city of Vienna

Urban public spaces are important areas for leisure, recreation and physical activity and therefore contribute to the quality of life in cities. In particular, for adolescents they provide important spaces to meet with their peers, away from parental or school control. In many cities worldwide, public spaces have undergone severe developmental processes, and often a withdrawal from public space is noted. With regard to the opportunities those spaces provide for adolescents, it is necessary to investigate their current meaning for adolescents in a leisure context. In this article, qualitative research methods were used to investigate factors affecting adolescents’ use of public spaces in Vienna, Austria. In total 45 adolescents were interviewed. Results show that public open spaces are not regarded as important leisure spaces, and data reveal a strong retreat to private areas for leisure purposes. Perceived insecurities and fears support these processes and often result in avoidance of public spaces but also the wish for more control by authorities.     

Radionuclides and metals in freshwater mussels of the upper South Alligator River, Australia

During an inspection of the old Rockhole Mine area in Kakadu National Park in 1999, it was found that a small amount of tailings from the former South Alligator uranium (U) mill had been uncovered by wet season rain and road works. Samples of sediment, water and freshwater mussels, Velesunio angasi, were collected from the South Alligator River, near and at the confluence of Rockhole Mine Creek, and adjacent to the exposed tailings. The 228Ra/226Ra activity ratios in sediments and mussel tissue indicate a small influence from the tailings and from Rockhole Mine adit water on 226Ra concentrations. The uptake of 226Ra in mussels does not correlate with other alkaline-earth metals. Mussel U concentrations are higher immediately downstream of Rockhole Mine Creek, but there is no noticeable increase in the immediate vicinity of the tailings area. A hypothetical ingestion of 2 kg of mussels from the sites was used to estimate the committed effective dose for a 10-year-old child resulting in a figure of 0.23 mSv per annum, of this total dose, 69% is attributed to 210Po. Only 0.03 mSv per annum can be directly linked to impacts of the tailings.     

CO2-emission reduction in China’s residential building sector and contribution to the national climate change mitigation targets in 2020

Between 1980 and 2007, in the Chinese building sector in urban and rural areas, coal was mainly substituted with electricity and natural gas. Growing income will further increase energy consumption and CO₂-emissions in the building sector. Using an econometric model, disaggregated energy demand and related CO₂-emissions in the residential sector as well for the whole economy are estimated and forecasted until 2050. In 2009, the Chinese government pledged itself to reduce CO₂-intensity by 40%?C45% in 2020 compared to 2005. Aim of this article is to assess to which extent the measures in the building sector in China can contribute to this target. Main results of the analysis are: (a) The primary energy source coal was mainly substituted by electricity generated with coal. Apart from convenience gains, the environmental advantages are questionable. (b) Between 2010 and 2050, energy demand in the building sector will grow by 2.0%?C4.1% per annum leading to CO₂-emissions at least almost tripling from about 560 mill. tons in 2010 to about 1,500 mill. tons in 2050. (c) The energy efficiency gains in the building sector and other sectors of the Chinese economy, however, are not enough to fulfill the national CO₂-intensity targets. The reduction of the CO₂-intensity of GDP would be 37.2% in the BAU-scenario, and 31.9% in the LOW-scenario. Only in the HIGH-scenario (46.3%), the economy is growing efficient enough relative to the induced CO₂-emissions. The remaining CO2-emission reductions could be gained by additional promotion of renewable energies (mainly solar and geo-thermal) in the building sector.     

Utilisation of single added fatty acids by consortia of digester sludge in batch culture

Inocula derived from an anaerobic digester were used to study (i) their potential for methane production and (ii) the utilisation rates of different short chain fatty acids (SCFAs) by the microbial community in defined media with mono-carbon sources (formic-, acetetic-, propionic-, butyric acid) in batch culture. It could be demonstrated that the microbial reactor population could be transferred successfully to the lab, and its ability to build up methane was present even with deteriorating biogas plant performance. Therefore, this reduction in performance of the biogas plant was not due to a decrease in abundance, but due to an inactivity of the microbial community. Generally, the physico-chemical properties of the biogas plant seemed to favour hydrogenotrophic methanogens, as seen by the high metabolisation rates of formate compared with all other carbon sources. In contrast, acetoclastic methanogenesis could be shown to play a minor role in the methane production of the investigated biogas plant, although the origin of up to 66% of methane is generally suggested to be generated through acetoclastic pathway.     

Hermaphroditism in brown shrimp: lessons from field data and modelling

This study was undertaken to further clarify whether the brown shrimp, Crangon crangon (Linnaeus 1758), is a gonochorist, a facultative or an obligate hermaphrodite. Juvenile shrimps were sampled from intertidal habitats along the German Wadden Sea coast with a push net and from a power plant water inlet to quantify the share of primary females. Length-based sex ratios were determined for about 27,000 individuals using external characteristics. Observed sex ratios were mainly female-biased, and also large males occurred regularly in the catch. This indicates that sex at hatch is not male as would be characteristic for an obligate protandric hermaphrodite and that not all male shrimps change sex. A cohort-based computer simulation, including sex-specific growth rates, mortality and seasonally varying recruitment, generated sex ratios comparable to the field. The observed decline in the proportion of males with increasing size can be explained solely by faster growth of females without involving hermaphroditism. Based on temperature-dependent growth and moult rates as well as length-specific numbers of eggs per female, the potential egg production of primary and secondary females was modelled, yielding contributions of secondary females of <1%. Sex change in C. crangon has previously been observed and may be interpreted as an evolutionary relict of this species having evolved in a habitat characterized by lower population densities, lower predation levels and increased longevity compared to today’s living conditions in North Sea coastal waters.     

Modelling visitor groups' intentions to displace from an urban trail: a combined stated preference and video monitoring approach

Depending on gender and activity, overcrowding and safety concerns may detract from urban green space use. Differences in use displacement intentions from a recreational trail in a forest in Vienna were investigated for male and female walkers as well as male and female dog-walkers (N = 425) using an image-based stated preference model. The trail scenarios were depicted as digitally calibrated images that systematically displayed combinations of levels of crowding with different mixes of user types and visitor behaviour. Visitors were asked whether the presented recreation scenario was so unacceptable that they would shift their use away from the presented trail. Hours and days of stated non-use of the recreation trail by various user groups are estimated by integrating the results of the behavioural model with annual visitation data. Use displacement intentions differed by gender and activity. High use levels were a greater concern for all respondents than very low use levels, particularly for female dog-walkers. However, only a small proportion of the recorded hours were heavily used. Safety concerns about very low use levels reduced the potential times of forest use for female walkers without a dog.     

车辆间碰撞交通事故计算机辅助鉴定技术综述

在分析车辆间事故过程的基础上,论述车辆间碰撞交通事故计算机辅助鉴定技术的基本原理,回顾碰撞前后阶段的HVOSM,PHASE4,SIMON等事故再现轨迹模型,概要地阐述CRASH类、动量模型类逆向计算系统以及二维、三维正向模拟类软件的计算原理,并进行分析和评述。研究认为,我国车辆间碰撞交通事故鉴定应将逆向计算与正向模拟相结合,建议通过研究交通事故现场勘查技术和建立车辆、轮胎、路面摩擦特性等基础数据库来提高逆向计算系统初始数据的准确性,从而提高交通事故鉴定的精度。     

First evidence for a stereoselective incorporation of nonylphenol diastereomers in soil-derived organo-clay complexes

Environmental processes can affect the stereochemical properties of organic pollutants. In particular, biotic processes like microbial transformations or membrane penetration alter the ratios of enantiomers as well as diastereomers. These effects have been intensively used not only in environmental studies but also in medicine, toxicology, pharmacy, and agricultural sciences. However, in order to identify unambiguously biotic-initiated alteration of organic compounds, the knowledge on the stereoselective effect of all relevant processes is mandatory. Therefore, here we report the first evidence for a stereospecific formation of non-extractable residues of a xeniobiotic in a highly relevant soil subfraction, the organo-clay complexes. In this study, soils were spiked with labeled and unlabeled nonylphenol isomer, and incubation experiments were performed to study its long-term incorporation behavior into soil-derived organo-clay complexes under abiotic and biotic conditions. Besides the extractable particle-associated proportion especially the humic fractions comprising the bound residues have been analyzed by GC/MS. Our results from biotic experiments revealed alterations of the diastereomeric composition of the contaminant in the different soil humic subfractions. A depletion of the first eluting diastereomer as expressed by diastereomeric ratios around 0.6 has been observed for the extractable fraction, whereas the non-extractable proportion was enriched in the first diastereomer (diasteremoric ratio around 1.0). On the contrary, the diastereomeric ratios remained unaffected during the abiotic experiments (diasteremoric ratio around 0.8). These systematic observations give clear evidence that the process of microbial-assisted incorporation of nonylphenol into soil organo-clay complexes is a stereoselective process. To our knowledge, this is the first report on a stereoselective incorporation process of organic substances forming non-extractable residues. Consequently, the formation of non-extractable residues has to be considered in environmental studies dealing with stereoselective analysis of organic pollutants in soils to study their microbial transformation.     

Hydrophobicity of soil colloids and heavy metal mobilization: effects of drying

Drying of soil may increase the hydrophobicity of soil and affect the mobilization of colloids after re-wetting. Results of previous research suggest that colloid hydrophobicity is an important parameter in controlling the retention of colloids and colloid-associated substances in soils. We tested the hypothesis that air-drying of soil samples increases the hydrophobicity of water-dispersible colloids and whether air-drying affects the mobilization of colloid-associated heavy metals. We performed batch experiments with field-moist and air-dried (25 degrees C) soils from a former sewage farm (sandy loam), a municipal park (loamy sand), and a shooting range site (loamy sand with 25% C(org)). The filtered suspensions (<1.2 microm) were analyzed for concentrations of dissolved and colloidal organic C and heavy metals (Cu, Cd, Pb, Zn), average colloid size, zeta potential, and turbidity. The hydrophobicity of colloids was determined by their partitioning between a hydrophobic solid and a hydrophilic aqueous phase. Drying increased hydrophobicity of the solid phase but did not affect the hydrophobicity of the dispersed colloids. Drying decreased the amount of mobilized mineral and (organo-)mineral colloids in the sewage farm soils but increased the mobilization of organic colloids in the C-rich shooting range soil. Dried samples released less colloid-bound Cd and Zn than field-moist samples. Drying-induced mobilization of dissolved organic C caused a redistribution of Cu from the colloidal to the dissolved phase. We conclude that drying-induced colloid mobilization is not caused by a change in the physicochemical properties of the colloids. Therefore, it is likely that the mobilization of colloids in the field is caused by increasing shear forces or the disintegration of aggregates.     

华北平原节水技术、灌溉用水量反弹效应与地区异质性——基于Malmquist和LMDI指数分析

很多地区节水技术的应用并未带来农业灌溉用水总量的下降。通过应用中国华北平原地级（直辖）市2000—2018年的面板数据,采用Malmquist指数和LMDI指数进行分解,测算出节水技术带来的农业灌溉用水反弹量和预期农业节水量。结果表明：中国华北平原节水技术引起的农业灌溉用水反弹效应均值为15.02%,这表明华北平原整体并未完全达到节水技术应用带来的预期农业节水量。节水技术应用放松了水资源约束,农户会扩大灌溉面积或高耗水高收益作物的种植,从而削弱节水技术的节水效果。黄河区的农业节水反弹效应程度最大,部分地区甚至会造成农业灌溉用水的增加。节水灌溉面积的增加是农业节水反弹效应的直接原因,农田灌溉水利建设投资的增加和水权市场建设的不完善则是根本原因。