δ 13C and δ 15N variations in organic matter pools, Mytilus spp. and Macoma balthica along the European Atlantic coast

Stable carbon (δ ¹³C) and nitrogen (δ ¹⁵N) isotope (SI) values of sedimentary organic matter (SOM), seston and two dominant bivalves, Mytilus spp. and Macoma balthica, were studied at 18 stations along the European coast in spring and autumn 2004. Three main regions, the Baltic Sea (BS), the North Sea and English Channel (NS), and the Bay of Biscay (BB), were tested for possible geographic (latitudinal) differences in the SI values. In spring, only BS showed lower δ ¹³C values of seston and Mytilus spp., and higher δ ¹⁵N values of SOM, than NS and BB. No significant differences between the 3 regions were found in autumn. Irrespective of season and regions, Mytilus spp. was more ¹³C-depleted than M. balthica. δ ¹³C values of M. balthica, but not those of Mytilus spp., were significantly correlated with SOM. These results are consistent with differences in feeding behavior of Mytilus spp. and M. balthica, as the two species are known as obligatory-suspension and facultative-deposit feeders, respectively. In contrast, no differences in the δ ¹⁵N values of Mytilus spp. and M. balthica were found at individual stations, indicating the same trophic level of the two bivalves within the food webs. At some stations, irrespective of geographic location, both bivalves showed δ ¹⁵N values up to 18–20 ‰. These were two trophic levels higher than those found at the other stations, indicating local and/or episodic eutrophic conditions, probably due to waste water discharge, and the effectiveness of both Mytilus spp. and M. balthica as bio-indicators of anthropogenic eutrophication. Overall, our results suggest that pathways of energy flow from OM pools to dominant bivalves is more related to local environmental conditions than to geographic regions across the European coastline. This has implications for food web studies along the Atlantic coast because most of the values are consistent over a large area and show no significant differences. Therefore, the present study can be used twofold for the determination of trophic baselines and for the correction of the trophic position of consumers higher up in the food web in the case of differences in waste water discharge.     

A Field Intercomparison and Fundamental Characterization of Various Dust Samplers with a Reference Sampler

The European Economic Community Council Directive 80/779/EEC¹ describes air quality limit values and guide values for sulfur dioxide and suspended particulates. However, article 10, paragraph 1 does not define well enough the reference method required, amongst others, for the gravimetric measurement of suspended particulates. It is explicity stated in article 10, paragraph 5 of the directive, that “the commission shall, in selected locations in the member states and in cooperation with the latter, carry out studies on the sampling…of suspended particulates. These studies shall be designed in particular to promote the harmonization of methods of sampling and analysis of these pollutants.” Therefore, in a joint research program the Umweltbundesamt (grant #104 02263), the commission of European Communities (grant #84-B-6642-11-017-11-N) and the U.S. EPA (grant #2-43211-3580) funded the development of a reference dust sampler by the Fraunhofer-lnstitute of Toxicology and Aerosol Research (FhITA, in Hannover, Federal Republic of Germany) in order: ? to study the particle size distribution of ambient air aerosol at a number of selected sites;

? to compare the results obtained with the reference dust sampler with those of particle samplers operated in Europe and the United States;

? to verify the applicability of wind tunnel results to sampling behaviour in the free atmosphere.

     

An assessment of long term ecosystem research activities across European socio-ecological gradients

Integration of European long term ecosystem research (LTER) would provide important support for the management of the pan-European environment and ecosystems, as well as international policy commitments. This does require appropriate coverage of Europe and standardised frameworks and research methods between countries. Emerging interest in socio-ecological systems prompted the present assessment of the distribution of LTER activities across European socio-ecological gradients. This paper presents a European stratification with a 1 km² resolution, delineating 48 broad socio-ecological regions. The dataset is based on an existing biogeophysical stratification constructed using multivariate clustering of mainly climatic variables and a newly developed socio-economic stratification based on an economic density indicator. The coverage of European LTER facilities across the socio-ecological gradients is tested using this dataset. The analysis shows two strong biases in the present LTER effort. Firstly, urban and disturbed regions are consistently under-represented, illustrating a bias for traditional ecological research away from human activity. Secondly, the Mediterranean, for which some of the most extreme global change impacts are projected, is receiving comparatively little attention. Both findings can help guide future investment in the European LTER network – and especially in a Long Term Socio-Ecological Research (LTSER) component– to provide a more balanced coverage. This will provide better scientific understanding of pan-European environmental concerns and support the management of natural resources and international policy commitments in the European Union.     

Characterizing sources of nitrate leaching from an irrigated dairy farm in Merced County, California

Dairy farms comprise a complex landscape of groundwater pollution sources. The objective of our work is to develop a method to quantify nitrate leaching to shallow groundwater from different management units at dairy farms. Total nitrate loads are determined by the sequential calibration of a sub-regional scale and a farm-scale three-dimensional groundwater flow and transport model using observations at different spatial scales. These observations include local measurements of groundwater heads and nitrate concentrations in an extensive monitoring well network, providing data at a scale of a few meters and measurements of discharge rates and nitrate concentrations in a tile-drain network, providing data integrated across multiple farms. The various measurement scales are different from the spatial scales of the calibration parameters, which are the recharge and nitrogen leaching rates from individual management units. The calibration procedure offers a conceptual framework for using field measurements at different spatial scales to estimate recharge N concentrations at the management unit scale. It provides a map of spatially varying dairy farming impact on groundwater nitrogen. The method is applied to a dairy farm located in a relatively vulnerable hydrogeologic region in California. Potential sources within the dairy farm are divided into three categories, representing different manure management units: animal exercise yards and feeding areas (corrals), liquid manure holding ponds, and manure irrigated forage fields. Estimated average nitrogen leaching is 872 kg/ha/year, 807 kg/ha/year and 486 kg/ha/year for corrals, ponds and fields respectively. Results are applied to evaluate the accuracy of nitrogen mass balances often used by regulatory agencies to assess groundwater impacts. Calibrated leaching rates compare favorably to field and farm scale nitrogen mass balances. These data and interpretations provide a basis for developing improved management strategies.     

Ecotoxicological effects assessment in the Netherlands: Recent developments

In a recently published annex to the National Environmental Policy Plan of the Netherlands (1989), attention was paid to ecotoxicological effects assessment. The proposed procedure was based on the advice of the Health Council of the Netherlands (1989) on risk assessment of toxic chemicals for ecosystems. The various extrapolation methods described by the Health Council are critically discussed in this paper. The extrapolation method of Van Straalen and Denneman (1989) is evaluated for eight chemicals and 11 aquatic species. Conclusions are drawn about the quality and quantity of the ecotoxicological data needed for aquatic effects assessment. For the soil—a compartment that is often at risk—ecotoxicological effects assessment is not possible because suitable ecotoxicological test methods still have to be developed.     

Planning and design of Berg-en-Dal,a new camp in Kruger National Park

The premise of this article is that the planning and design of new rest camps in conservation areas should be based on ecological principles in such a way that the plant ecology within the camp be an integral part and extension of the natural ecology of its immediate vicinity. This is desirable so that visitors to the camp will be provided not only with facilities for resting, eating, and sleeping, but also be able to enjoy and study the natural environment in a relaxed atmosphere. The Berg-en-Dal rest camp, which was established in Kruger National Park, was planned in such a way and designed according to the principles outlined by the authors in a companion article. The planning included six zones: a control zone, day visitor zone, overnight visitor zone, staff accommodation zone, recreation zone, and service zone. The point is stressed that plant species selected to be used as additional vegetation to those already growing in the camp were endemic to the nine landscape facets identified in the camp. The design allowed for separation of the various land-use zones in such a way that they would complement each other rather than be a hindrance to each other. The camp has been built according to the plans included in this article and has proved to be a great success. The conclusion is drawn that the planning principles are sound and should be used in the future for the planning and design of rest camps for conservation areas in South Africa.     

Structure-biodegradation relationships of polymeric materials. 1. Effect of degree of oxidation on biodegradability of carbohydrate polymers

The biodegradability of oxidized starch and inulin has been studied in relation to the degree of periodate oxidation to dialdehyde derivatives, by measuring oxygen consumption and mineralization to carbon dioxide. A higher degree of oxidation of dialdehyde starch and dialdchyde inulin results in a lower rate at which the polymers are biodegraded. It is demonstrated that the biodegradation rate of dialdehyde inulin derivatives decreases more than that of equivalent starch derivatives. The differences in biodegradation behavior between dialdehyde starch and dialdehyde inulin, resulting from comparable modifications, are discussed in terms of conformational structure.