全文获取类型
收费全文 | 1179篇 |
免费 | 16篇 |
国内免费 | 16篇 |
专业分类
安全科学 | 48篇 |
废物处理 | 55篇 |
环保管理 | 141篇 |
综合类 | 229篇 |
基础理论 | 198篇 |
环境理论 | 3篇 |
污染及防治 | 389篇 |
评价与监测 | 75篇 |
社会与环境 | 54篇 |
灾害及防治 | 19篇 |
出版年
2023年 | 24篇 |
2022年 | 30篇 |
2021年 | 39篇 |
2020年 | 27篇 |
2019年 | 27篇 |
2018年 | 55篇 |
2017年 | 55篇 |
2016年 | 64篇 |
2015年 | 43篇 |
2014年 | 69篇 |
2013年 | 83篇 |
2012年 | 72篇 |
2011年 | 97篇 |
2010年 | 64篇 |
2009年 | 47篇 |
2008年 | 71篇 |
2007年 | 61篇 |
2006年 | 65篇 |
2005年 | 50篇 |
2004年 | 44篇 |
2003年 | 23篇 |
2002年 | 20篇 |
2001年 | 9篇 |
2000年 | 8篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1997年 | 9篇 |
1996年 | 2篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1986年 | 3篇 |
1984年 | 1篇 |
1966年 | 2篇 |
1961年 | 2篇 |
1960年 | 1篇 |
1959年 | 2篇 |
1958年 | 1篇 |
1957年 | 2篇 |
1954年 | 3篇 |
1951年 | 3篇 |
1950年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有1211条查询结果,搜索用时 15 毫秒
91.
Tanning processes performed in drums consume large amounts of water and chemicals, most of which end up in the wastewater. This study explores an alternative approach at an industrial scale to the traditional pickle-chrome tanning method. The new method replaces formic and sulphuric acids with sulphonic aromatic acid. Because it is done without float, there is a sizeable reduction in the amount of added salt and chrome salt as well as an increase in temperatures at the end of the tanning process. From an environmental perspective, the new method offers important advantages. For instance, there is no float addition in the tannage. Also, there are reductions of 94% and 99%, respectively, in the discharge of chlorides and chrome, as well as a 75% reduction in the residual float. Our financial assessment demonstrated that the new method is 42% cheaper than a traditional approach. 相似文献
92.
This study tests an alternative method to the traditional unhairing method used during the process of tanning the hides. The new method is based on the substitution of sodium sulfide by hydrogen peroxide as an unhairing agent in both hair recovery and recirculation of the floats employed in the process. The properties of the hides obtained using the two methods have been compared and the results indicate that those hides have similar physical, chemical, and organoleptic properties. However, the differences existing from an environmental point of view are significant. These include reductions of water consumption (approx 70%), chemical oxygen demand (approx 35%), toxicity (98%) and total kjendhal nitrogen (50%). Also, the risk associated with the production of hydrogen sulfide is eliminated, which implies a great improvement in terms of safety for the workers. Given the large amounts of water and chemical pollution discharged in the process, the reductions in absolute values represent a significant improvement. A financial assessment was carried out to demonstrate that the proposed new system is 16% more economic than the traditional one. 相似文献
93.
Markéta Julinová Marie Dvořáčková Jan Kupec Jitka Hubáčková Martina Kopčilová Jaromír Hoffmann Pavol Alexy Anna Nahálková Ida Vašková 《Journal of Polymers and the Environment》2008,16(4):241-249
Improving biodegradability of PVA/starch blends is a reality already documented by a number of works. Admittedly, mechanical
properties of products (for example, tensile strength) are somewhat worse, but suitable composition optimizing or chemical
modifying of starch may eliminate the problem to a large degree. This work is an attempt to find another potential effect
influencing biodegradability, that of technological procedure for producing films from these blends on an extruder. The procedure
with a so-called pre-extrusion step (two-stage) and dry-blend (single-stage) produced blends of slightest differences in achieved
biodegradability (virtually within limits of experimental error) in aerobic (76 vs. 79%) as well as anaerobic breakdown (48
vs. 52%). Conversely, morphological analysis exhibited superior homogeneity of films prepared by the two-stage process; their
tensile strength was also higher. 相似文献
94.
95.
96.
Trace amounts of bismuth(III) and uranium(VI) can be simultaneously determined in a single scan by adsorptive cathodic stripping voltammetry in the presence of cupferron as a complexing agent. Optimal conditions were found to be: 0.1 mol?L?1 acetate buffer (pH 5.3), 5?×?10?5?mol?L?1 cupferron, accumulation potential of ?0.25 V, and accumulation time of 30 s. The linear range of Bi(III) and U(VI) was observed over the concentration range from 2?×?10?9 to 2?×?10?7?mol?L?1 and from 1?×?10?8 to 5?×?10?7?mol?L?1, respectively. The influence of the main components of real water samples such as foreign ions and organic substances (surface active substances, humic substances) was precisely investigated. The method was applied to the simultaneous measurements of bismuth and uranium in natural water samples. 相似文献
97.
98.
Mikołaj Urbanowski Paweł Socha Paweł Dąbrowski Wioletta Nowaczewska Anna Sadakierska-Chudy Tadeusz Dobosz Krzysztof Stefaniak Adam Nadachowski 《Die Naturwissenschaften》2010,97(4):411-415
An upper second permanent molar from a human was found alongside numerous tools of the Micoquian tradition and was excavated
in Stajnia Cave, which is located over 100 km North of the Carpathian Mountains in southern Poland. The age of these finds
has been established within a time-span of late Saalian to early Weichselian, most likely to OIS 5c or 5a, according to the
palaeontological, geological, archaeological and absolute dating of the layer from which they were obtained. An examination
of the morphology of the human molar indicates that this tooth exhibits many traits frequently occurring in Neanderthal upper
molars. Although the occurrence of derived Neanderthal traits in the Stajnia molar cannot be firmly established because of
degradation of its cusps, the presence of the above-mentioned features allows the assertion that this tooth belonged to a
Neanderthal. The age of the Stajnia tooth and the archaeological context of this find also indicate that this molar is of
Neanderthal origin. 相似文献
99.
In the present study, endpoints including in vitro pollen performance (i.e., germination and tube growth) and lethality were used as assessments of nanotoxicity. Pollen was treated with 5-10 nm-sized Pd particles, similar to those released into the environment by catalytic car exhaust converters. Results showed Pd-nanoparticles altered kiwifruit pollen morphology and entered the grains more rapidly and to a greater extent than soluble Pd(II). At particulate Pd concentrations well below those of soluble Pd(II), pollen grains experienced rapid losses in endogenous calcium and pollen plasma membrane damage was induced. This resulted in severe inhibition and subsequent cessation of pollen tube emergence and elongation at particulate Pd concentrations as low as 0.4 mg L−1. Particulate Pd emissions related to automobile traffic have been increasing and are accumulating in the environment. This could seriously jeopardize in vivo pollen function, with impacts at an ecosystem level. 相似文献
100.