Evaluation and optimization of an urban PM2.5 monitoring network

The objective of this study was to evaluate the PM(2.5) monitoring network established in the Greater Cincinnati and Northern Kentucky metropolitan area for measuring the 24 h integrated PM(2.5) concentration, as well as-at selected sites-hourly PM(2.5) concentration and 24 h integrated PM(2.5) speciation. The data collected during three years at 13 measurement sites were analyzed for spatial and temporal variations. It was found that both daily and hourly concentrations of PM(2.5) have low spatial variation due to a regional influence of secondary ammonium sulfate. In contrast, the trace element concentrations had high spatial variation. Seasonal variation accounted for most of the total temporal variation (60%), while yearly, monthly, weekly and daily variations were lower. The variance components and cluster analyses were applied to optimize the number of sites for measuring the 24 h PM(2.5) concentration. It was found that the 13-site network may be optimized by reducing the number of sites to 8, which would result in a relative precision reduction of 9% and a relative cost reduction of 36%. At the same time, the data suggest that the spatial resolution of speciation monitors and real-time PM(2.5) mass monitors should be increased to better represent spatial and temporal variations of the markers of local air pollution sources.     

Human influence over 150 years of coastal evolution in the Volturno delta system (southern Italy)

This paper focused on the past shoreline change rates along the coastal plain of the Volturno River, in southern Italy, western Mediterranean. A wide database comprising historical maps, aerial photographs, topographic sheets, bathymetric data was used to extract the spatial and temporal information of the coastlines at seven time points. Coastline displacement was calculated for two successive time points and relative surface variation (accretion and erosion) was estimated as well as minimum and maximum accretion/erosion linear values and rates. The surface variation analysis has revealed that the studied coast can be considered homogeneous since the 1970s, whereas it exhibits a variety of shoreline evolutionary trends after that time period. Timing and causes of trends and rates of variation were detected. Based on the estimated shoreline change rates, an appropriate morhodynamic one-line model was applied to predict evolutionary scenarios also in presence of port and defence works. The results obtained strongly emphasize that a successful coastal management requires a constant monitoring of the human-induced changes to account for the variability of rates over time.     

Carbon isotope effects during precipitation of barium carbonate: implications for environmental studies

Here we demonstrate that precipitation of dissolved inorganic carbon (DIC) to at pH 10.26, 11.38 and 12.11 does not cause measurable carbon isotope fractionation. However, NaOH solution prepared under standard laboratory procedure and used to increase pH value for precipitation of BaCO₃ can be contaminated by atmospheric CO₂. In our experiment, δ¹³C value in the contaminant DIC was −24.30‰, which resulted in decrease in the δ¹³C(DIC) value by 0.03, 0.07 and 0.22 at pH 10.26, 11.38 and 12.11, respectively.     

Dark, bitter-tasting nectar functions as a filter of flower visitors in a bird-pollinated plant

Floral nectar is offered by plants to animals as a reward for pollination. While nectar is typically a clear liquid containing sugar and trace amounts of amino acids, colored nectar has evolved in several plant families. Here we explore the functional significance of the phenolic compounds that impart a dark brown color to the nectar of the South African succulent shrub Aloe vryheidensis. Flowers of this aloe are visited for their nectar by a suite of short-billed birds that are occasional nectarivores, including bulbuls, white-eyes, rock thrushes, and chats. Dark-capped Bulbuls were more likely to probe model flowers containing dark nectar than those containing clear nectar, suggesting a potential signaling function for dark nectar. However, the main effect of the phenolics appears to be to repel "unwanted" nectarivores that find their bitter taste unpalatable. Nectar-feeding honey bees and sunbirds are morphologically mismatched for pollinating A. vryheidensis flowers and strongly reject its nectar. However, the frugivorous and insectivorous birds that effectively pollinate this aloe are seemingly unaffected by the nectar's bitter taste. Thus the dark phenolic component of the nectar appears to function as a floral filter by attracting some animals visually and deterring others by its taste.     

Antenatal corticosteroids and outcomes in gastroschisis: A multicenter retrospective cohort study

Objective

In gastroschisis, there is evidence to suggest that gut dysfunction develops secondary to bowel inflammation; we aimed to evaluate the effect of maternal antenatal corticosteroids administered for obstetric reasons on time to full enteral feeds in a multicenter cohort study of gastroschisis infants.

Methods

A three center, retrospective cohort study (1992-2013) with linked fetal/neonatal gastroschisis data was conducted. The primary outcome measure was time to full enteral feeds (a surrogate measure for bowel function) and secondary outcome measure was length of hospital stay. Analysis included Mann-Whitney and Cox regression.

Results

Of 500 patients included in the study, 69 (GA at birth 34 [25-38] weeks) received antenatal corticosteroids and 431 (GA at birth 37 [31-41] weeks) did not. Antenatal corticosteroids had no effect on the rate of reaching full feeds (Hazard ratio HR 1.0 [95% CI: 0.8-1.4]). However, complex gastroschisis (HR 0.3 [95% CI: 0.2-0.4]) was associated with an increased time to reach full feeds and later GA at birth (HR 1.1 per week increase in GA [95% CI: 1.1-1.2]) was associated with a decreased time to reach full feeds.

Conclusion

Maternal antenatal corticosteroids use, under current antenatal steroid protocols, in gastroschisis is not associated with an improvement in neonatal outcomes such as time to full enteral feeds or length of hospital stay.     

Sustainability experiments in Asia: innovations shaping alternative development pathways?

Global sustainability is increasingly influenced by processes of industrialisation and urbanization in non-OECD countries, especially in Asia. Growth models suggest that developing economies and regions will become first relatively more resource- and pollution-intensive, before converging on more resource-efficient and low-pollution production and consumption patterns expressed in developed countries. Alternative less resource- and pollution-intensive growth models for latecomer countries promise social and economic benefits in the short- and long-term. Drawing on insights from system innovation research on long-run change in socio-technical systems, we discuss the potential role of ‘sustainability experiments’ to generate innovations that will constitute new ‘greener’ growth models. We observe a great number of technology-based initiatives that we characterize as sustainability experiments in East and South Asian countries. These experiments emerge in the context of the growth of new socio-technical regimes in key sectors, including energy, transport, manufacturing, food and the built environment. We set out a conceptual framework for assessing the role of experiments, and for evaluating how they link with and become anchored into alternative more sustainable regimes. In this paper we argue that sustainability experiments represent a significant new source of innovation and capability-formation, linked to global knowledge and technology flows, which could reshape emergent socio-technical regimes and so contribute to alternative development pathways in latecomer countries. We conclude by summarizing the six papers published in this Special Issue.     

Characterization,heavy metal content and health risk assessment of urban road dusts from the historic center of the city of Thessaloniki,Greece

In the present study, an investigation of the mineralogy and morphology, the heavy metal content and the health risk of urban road dusts from the second largest city of Greece was conducted. For this reason road dust samples from selected sites within the city core area were collected. No differences were observed in the mineralogy of road dusts coming from different sampling sites, and they were mainly consisted of quartz and calcite, while an elevated amorphous content was detected. Morphologically road dusts presented Ca-rich, Fe-rich and silicates particles with various shapes and sizes. The mean concentrations of Cd, Cr, Cu, Mn, Ni, Pb and Zn in road dust were 1.76, 104.9, 662.3, 336.4, 89.43, 209 and 452.8 μg g^?1, respectively. A series of spatial distribution patterns revealed that the hotspot areas were tended to associate with major road junctions and regions with high traffic. Combination of pollution indexes and statistical analyses (correlation analysis, cluster analysis and principal component analysis) revealed that road dusts have a severe influence by anthropogenic activities. In attempt to identify the source of metals through geostatistical and multivariate statistical analyses, it was concluded as follows: Cr, Cu, Fe and Zn mainly originated from tire/break wear and vehicle abrasions, while Cd, Mn and Pb were mainly related to fuel/oil leakage from automobiles along with oil lubricants and vehicle abrasion. Hazard quotient values for children based on total metal concentrations for the road dust ingestion route were lower than safe level (=1). However, the fact that the Hazard Index value for Pb (0.459) which is a particularly toxic metal, was close to safe level, renders essential further investigation in order to provide more reliable characterizations of potential health risks.     

PCDD/PCDF, dl-PCB and PBDE serum levels of Slovak general population

Blood serum specimens from 81 non-occupationally exposed adults residing in four areas close to municipal and waste incinerators as well as metallurgical industry plant and 44 adult subjects coming from control area of Slovakia were analysed for polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), dioxin-like polychlorinated biphenyls (dl-PCBs) and polybrominated diphenylethers (PBDEs). The concentration of total WHO(98)TEQ PCDD/F/dl-PCBs in whole group of donors from areas where known sources causing dioxin contamination are present was significantly higher than in control group of donors (p<0.001). Correlation between the age of donors and PCDD/F and dl-PCB levels was confirmed (Spearman's r(PCDD/Fs)=0.543, r(dl-PCBs)=0.521, p<0.001). Furthermore, this study presents first results concerning the PBDE congeners in human serum of Slovak general population. The total concentration (congeners 28, 47, 99, 100, 153, 154, 183) in control group was approximately 1.5-times higher in comparison to that of residents coming from areas with supposed environmental pollution. The most abundant congeners in all samples were BDE-47 and BDE-153 with median values of 0.24 ng g(-1) lipid and 0.23ngg(-1) lipid, respectively. The positive association between PBDE values and age of donors was not found.     

In Vitro effects of various xenobiotics on Azotobacter chroococcum strains isolated from soils of southern Poland

Fourteen Azotobacter chroococcum strains isolated from soils of Southern Poland were studied concerning resistance to various xenobiotics: heavy metal ions: Cd(2+,) Cu(2+), Fe(3+), Mn(2+), Pb(2+), Zn(2+), pesticides: herbicides linuron (3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea) and combination of mecoprop ((RS)-2-(4-chloro-2-methylphenoxy)propanoic acid), dicamba (3,6-dichloro-2-methoxybenzoic acid) and MCPA (2-methyl-4-chlorophenoxyacetic acid), fungicide copper oxychloride, insecticide fenitrothion (O,O-Dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate) and eight antibiotics commonly used against Gram-negative bacteria. The tested soils were divided into seven groups of land use: forest, field crop, park, urban lawn, industrial area, garden and fallow land, and were analyzed for the following heavy metal ion concentrations using the atomic absorption spectrometry (AAS) technique: Cd(2+,) Cu(2+), Fe(3+), Mn(2+), Pb(2+), Zn(2+). All strains were resistant to Pb(2+), whereas other metals caused the growth inhibition of the analyzed strains. There was no significant relationship between metal concentrations in the analyzed soils and metal resistance of the isolates. Herbicide linuron did not inhibit the growth of A. chroococcum in any of the concentrations. All other pesticides caused the growth inhibition only in the concentrate forms. All isolates were sensitive to β-lactam antibiotic Meropenem, however high intraspecies differentiation was observed concerning resistance to other antibiotics. The obtained results require further study regarding resistance mechanisms and possible use of the xenobiotic-resistant strains in land rehabilitation.