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681.
Investigations on the binding mechanism of the herbicide simazine to dissolved organic matter in leachates of compost 总被引:1,自引:0,他引:1
14C-labelled simazine was composted together with biowaste on a pilot (m3) scale. The herbicide was quickly bound to the compost matrix. By aqueous extraction of 29 and 200 days old compost (equivalent to thermophilic and mesophilic phase of composting) only 4.2% and 3.1% respectively of the radioactivity in the compost samples could be extracted with water. Analysis of the extracts using high-performance size exclusion chromatography (HPSEC) revealed that the dissolved organic matter (DOM) had molecular weights ranging between 2 and 28 kDa. The amount of DOM-associated radioactivity increased from 53% (day 29) to 65% (day 200) of total extractable radioactivity. The type of binding of the 14C-labelled residues and the DOM was elucidated by silylation of humic matter and subsequent HPSEC. The data demonstrated that besides polar metabolites also intact simazine was bound to the DOM. A distinct shift from rather weak interactions to strong covalent linkages of simazine and its metabolites with increasing age of the compost was observed. The results showed that only low amounts of free simazine and its degradates can be extracted with water. We concluded that the shift towards stable covalent linkages is equivalent to a detoxification of the contaminant in aged compost. Consequently, the use of the analysed compost in its mature stage should not pose an environmental risk to the groundwater or the subsoil. 相似文献
682.
Anne M. S. McFarland Larry M. Hauck 《Journal of the American Water Resources Association》2001,37(1):223-236
ABSTRACT: Over a three‐year period, flow and nutrients were monitored at 13 sites in the upper North Bosque River watershed in Texas. Drainage areas above sampling sites differed in percent of dairy waste application fields, forage fields, wood/range, and urban land area. A multiple regression approach was used to develop total phosphorus (TP) and total nitrogen (TN) export coefficients for the major land uses in these heterogeneous drainage areas. The largest export coefficients were associated with dairy waste application fields followed by urban, forage fields, and wood/range. An empirical model was then established to assess nutrient contribution by major sources using developed export coefficients and point source loadings from municipal wastewater treatment. This model was verified by comparison of estimated loadings to measured in‐stream data. Monte Carlo simulation techniques were applied to provide an uncertainty analysis for nutrient loads by source, based on the variance associated with each export coefficient. The largest sources of nutrients contributing to the upper North Bosque River were associated with dairy waste application fields and forage fields, while the greatest relative uncertainty in source contribution was associated with loadings from urban and wood/range land uses. 相似文献
683.
Characterisation of the abiotic degradation pathways of oxytetracyclines in soil interstitial water using LC-MS-MS 总被引:6,自引:0,他引:6
Halling-Sørensen B Lykkeberg A Ingerslev F Blackwell P Tjørnelund J 《Chemosphere》2003,50(10):1331-1342
The fate of oxytetracyclines (OTCs) in soil interstitial water was investigated and the structure of a number of degradation products elucidated in a time-related experiment. A previously developed separation method for LC–MS–MS able to base separate and quantify OTC and three of its epimers and degradation products was applied. Compounds detected were 4-epi-oxytetracycline (EOTC) (tR=3.0 min), OTC (tR=4.4 min), -apo-oxytetracycline (-apo-OTC) (tR=11.4 min) and β-apo-oxytetracycline (β-apo-OTC) (tR=18.4 min). Furthermore, we tentatively identified 4-epi-N-desmethyl-oxytetracycline (E-N-DM-OTC) (tR=3.0 min), N-desmethyl-oxytetracycline (N-DM-OTC) (tR=3.5), N-didesmethyl-oxytetracycline (N-DDM-OTC), 4-epi-N-didesmethyl-oxytetracycline (E-N-DDM-OTC) (tR=3.7 and 4.7 min) and 2-acetyl-2-decarboxamido-oxytetracycline (tR=8.7) in all samples. Most compounds were only present in trace concentrations (less than 2%) relative to the parent OTC. EOTC was on the other hand formed up to a ratio of 0.6 relative to parent OTC concentration. Only EOTC, E-N-DM-OTC, N-DM-OTC, N-DDM-OTC and E-N-DDM-OTC were formed during the time-related experiment. All other compounds were probably only present as impurities in the spiked OTC formulation as they declined in concentration from the start of the experiment. Half-lives (T1/2, days) of the OTCs in soil interstitial water were in the order of 2 days (EOTC) to 270 days (β-apo-OTC). 相似文献
684.
Mark K. Greco Dorothee Hoffmann Anne Dollin Michael Duncan Robert Spooner-Hart Peter Neumann 《Die Naturwissenschaften》2010,97(3):319-323
Workers from social insect colonies use different defence strategies to combat invaders. Nevertheless, some parasitic species
are able to bypass colony defences. In particular, some beetle nest invaders cannot be killed or removed by workers of social
bees, thus creating the need for alternative social defence strategies to ensure colony survival. Here we show, using diagnostic
radioentomology, that stingless bee workers (Trigona carbonaria) immediately mummify invading adult small hive beetles (Aethina tumida) alive by coating them with a mixture of resin, wax and mud, thereby preventing severe damage to the colony. In sharp contrast
to the responses of honeybee and bumblebee colonies, the rapid live mummification strategy of T. carbonaria effectively prevents beetle advancements and removes their ability to reproduce. The convergent evolution of mummification
in stingless bees and encapsulation in honeybees is another striking example of co-evolution between insect societies and
their parasites. 相似文献
685.
Ivar Zekker Ergo Rikmann Toomas Tenno Anne Menert Vallo Lemmiksoo Alar Saluste Taavo Tenno Martin Tomingas 《环境科学学报(英文版)》2011,23(7):1113-1121
Nitrifying biomass on ring-shaped carriers was modified to nitritating one in a relatively short period of time (37 days) by limiting the
air supply, changing the aeration regime, shortening the hydraulic retention time and increasing free ammonia (FA) concentration in the
moving-bed biofilm reactor (MBBR). The most efficient strategy for the development and maintenance of nitritating biofilm was found
to be the inhibition of nitrifying activity by higher FA concentrations (up to 6.5 mg/L) in the process. Reject water from sludge treatment
from the Tallinn Wastewater Treatment Plant was used as substrate in the MBBR. The performance of high-surfaced biocarriers taken
from the nitritating activity MBBR was further studied in batch tests to investigate nitritation and nitrification kinetics with various FA
concentrations and temperatures. The maximum nitrite accumulation ratio (96.6%) expressed as the percentage of NO2??-N/NOx??-N
was achieved for FA concentration of 70 mg/L at 36°C. Under the same conditions the specific nitrite oxidation rate achieved was 30
times lower than the specific nitrite formation rate. It was demonstrated that in the biofilm system, inhibition by FA combined with the
optimization of the main control parameters is a good strategy to achieve nitritating activity and suppress nitrification. 相似文献
686.
687.
Samuel G. Rees Anne E. GoodenoughAdam G. Hart Richard Stafford 《Ecological modelling》2011,222(17):3291-3294
Estimation of small mammal population sizes is important for monitoring ecosystem condition and for conservation. Here, we test the accuracy of standard methods of population size estimation using Capture-Mark-Recapture (CMR) on a simulated population of agents. The use of a computer simulation allows complete control of population sizes and behaviors, thereby avoiding assumptions that may be violated in real populations. We find that the recommended protocol for CMR sampling, using uniformly distributed traps, consistently overestimates population sizes by as much as 100% when studies are conducted over only two trapping periods. More than 20 trapping periods are required before this method, or that of placing traps randomly, gives an accurate estimation of population size (i.e., within a 95% confidence limit of the actual value). Non-random sampling, by placing traps on runways used by small mammals, produces the most accurate, and least variable, estimates of population. However, we show that around 10 trapping periods are still required to produce an accurate population estimate using this method. Given that most real populations do not comply with the ‘ideal’ assumptions made by CMR, we suggest that population estimates based on CMR may be fundamentally flawed, and recommend that protocols for CMR population estimation methods may need revising. 相似文献
688.
Chazdon RL Chao A Colwell RK Lin SY Norden N Letcher SG Clark DB Finegan B Arroyo JP 《Ecology》2011,92(6):1332-1343
We develop a novel statistical approach for classifying generalists and specialists in two distinct habitats. Using a multinomial model based on estimated species relative abundance in two habitats, our method minimizes bias due to differences in sampling intensities between two habitat types as well as bias due to insufficient sampling within each habitat. The method permits a robust statistical classification of habitat specialists and generalists, without excluding rare species a priori. Based on a user-defined specialization threshold, the model classifies species into one of four groups: (1) generalist; (2) habitat A specialist; (3) habitat B specialist; and (4) too rare to classify with confidence. We illustrate our multinomial classification method using two contrasting data sets: (1) bird abundance in woodland and heath habitats in southeastern Australia and (2) tree abundance in second-growth (SG) and old-growth (OG) rain forests in the Caribbean lowlands of northeastern Costa Rica. We evaluate the multinomial model in detail for the tree data set. Our results for birds were highly concordant with a previous nonstatistical classification, but our method classified a higher fraction (57.7%) of bird species with statistical confidence. Based on a conservative specialization threshold and adjustment for multiple comparisons, 64.4% of tree species in the full sample were too rare to classify with confidence. Among the species classified, OG specialists constituted the largest class (40.6%), followed by generalist tree species (36.7%) and SG specialists (22.7%). The multinomial model was more sensitive than indicator value analysis or abundance-based phi coefficient indices in detecting habitat specialists and also detects generalists statistically. Classification of specialists and generalists based on rarefied subsamples was highly consistent with classification based on the full sample, even for sampling percentages as low as 20%. Major advantages of the new method are (1) its ability to distinguish habitat generalists (species with no significant habitat affinity) from species that are simply too rare to classify and (2) applicability to a single representative sample or a single pooled set of representative samples from each of two habitat types. The method as currently developed can be applied to no more than two habitats at a time. 相似文献
689.
The importance of quantifying propagule pressure to understand invasion: an examination of riparian forest invasibility 总被引:1,自引:0,他引:1
The widely held belief that riparian communities are highly invasible to exotic plants is based primarily on comparisons of the extent of invasion in riparian and upland communities. However, because differences in the extent of invasion may simply result from variation in propagule supply among recipient environments, true comparisons of invasibility require that both invasion success and propagule pressure are quantified. In this study, we quantified propagule pressure in order to compare the invasibility of riparian and upland forests and assess the accuracy of using a community's level of invasion as a surrogate for its invasibility. We found the extent of invasion to be a poor proxy for invasibility. The higher level of invasion in the studied riparian forests resulted from greater propagule availability rather than higher invasibility. Furthermore, failure to account for propagule pressure may confound our understanding of general invasion theories. Ecological theory suggests that species-rich communities should be less invasible. However, we found significant relationships between species diversity and invasion extent, but no diversity-invasibility relationship was detected for any species. Our results demonstrate that using a community's level of invasion as a surrogate for its invasibility can confound our understanding of invasibility and its determinants. 相似文献
690.