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Perfluorinated chemicals in selected residents of the American continent 总被引:11,自引:0,他引:11
Calafat AM Needham LL Kuklenyik Z Reidy JA Tully JS Aguilar-Villalobos M Naeher LP 《Chemosphere》2006,63(3):490-496
Perfluorinated chemicals (PFCs) are used in multiple consumer products. Perfluorooctane sulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), the most widely studied PFCs, may be potential developmental, reproductive, and systemic toxicants. Although PFCs seem to be ubiquitous contaminants found both in humans and animals, geographic differences may exist in human exposure patterns to PFCs. We measured 11 PFCs in 23 pooled serum samples collected in the United States from 1990 through 2002, and in serum samples collected in 2003 from 44 residents from Trujillo, Peru. PFOS and PFOA were detected in all the pooled samples; perfluorohexane sulfonic acid (PFHxS) was detected in 21. Median concentrations were 31.1 micrograms per liter (mug/l, PFOS), 11.6 microg/l (PFOA), and 2 microg/l (PFHxS). The 90th percentile concentrations of PFCs in the 44 Peruvian residents were 0.7 microg/l (PFOS), 0.1 microg/l (PFOA), and <0.3 microg/l (PFHxS). The frequencies of detection were 20% (PFOS), 25% (PFOA), and 9% (PFHxS). The frequent detection of selected PFCs in the pooled samples from the United States and the lack of clear concentration trends based on a year of collection suggest a sustained widespread exposure to these compounds among US residents, at least since the 1990s. By contrast, the much lower frequency of detection and concentration ranges of PFCs in Peru suggest a lower exposure of Peruvians to PFCs compared with North Americans. Genetic variability, diet, lifestyle, or a combination of all these may contribute to the different patterns of human exposure to PFCs in the United States and Peru. 相似文献
24.
Rodolfo Barreiro Lucia Couceiro María Quintela José Miguel Ruiz 《Marine Biology》2006,148(5):1051-1060
Randomly amplified polymorphic DNA (RAPD) banding patterns were compared between samples of the netted dogwhelk Nassarius reticulatus from 11 locations along the NW Iberian Peninsula coast. To detect if rias (estuaries formed by drowned river valleys) might
promote genetic differentiation, five sampling sites were located within a ria (ria of Muros) and the remaining six were scattered
along open-coast areas at increasing distances from the ria mouth. Population differentiation statistics (Φ-values) were estimated
using a hierarchical analysis of molecular variance (AMOVA) with samples sorted into two groups: open-coast and ria populations.
Despite a high potential to disperse, AMOVA demonstrated a modest, statistically significant genetic heterogeneity among N. reticulatus populations. Most of the genetic structure resided in differences among open-coast populations; ria populations were genetically
homogeneous. No obvious geographical pattern was detected for the pairwise genetic distances (non-metric multidimensional
scaling; UPGMA tree; Mantel test). Unlike previous studies with other species at a variety of estuarine systems other than
rias, there was no evidence that the ria of Muros may enhance the genetic divergence of N. reticulatus populations. This discrepancy is discussed in relation to the biological features of the species (high dispersal potential
and a preference for mid-low estuarine habitat) and the strong hydrographic connectivity between ria and neighbouring off-shore
waters. 相似文献
25.
Felicita?ScapiniEmail author Lorenzo?Chelazzi Isabella?Colombini Mario?Fallaci Lucia?Fanini 《Marine Biology》2005,147(4):919-926
Orientation experiments were carried out on Talitrus saltator (Crustacea Amphipoda) at four points along 3 km on a dynamic sandy beach inside the Maremma Regional Park (Grosseto, Italy) to highlight behavioural variation related to distance from a river mouth, to erosion or accretion of shoreline, and to human trampling on the beach. Tests were performed using circular transparent Plexiglas arenas, contemporaneously at the four points. Replicates were made in 2 different months (September 2002 and May 2003), on 2–3 successive days, in the morning and afternoon. The distributions of the angles of orientation were compared for the different points and seasons, and multiple regression analysis was performed to test the effects of environmental and intrinsic variables on orientation. Sandhoppers showed the highest scatter at the eroded shoreline, intermediate scatter at the accreting beach most distant from the river mouth, and consistent orientation seaward at the least disturbed point. Orientation of sandhoppers was significantly affected by season, global radiation, time of day, distance from the river mouth, and human trampling. Sex and air humidity were of minor significance in the multiple regression model. The results, on the one hand, confirm plasticity in orientation of sandhoppers living on a dynamic shoreline, and on the other hand, show that variation in orientation could potentially be used as a bioindicator of shoreline changes.Communicated by R. Cattanevo-Vietti, Genova 相似文献
26.
This study evaluated the potential toxicological risk posed to human health due to the exposure to heavy metals by water ingestion
in an area affected by tanneries – the Cadeia-Feitoria hydrographic basin (Brazil). River water was collected at 10 sites,
every 3 months, from July 1999 to April 2000. After acid digestion, total metal concentration was determined by inductively
coupled plasma optical emission spectrometry (Cd, Cu, Cr, Ni, Zn), flame atomic absorption (Al, Fe, Pb, Mn), or cold vapor
atomic absorption spectrometry (Hg). Cr(VI) was complexed with diphenyl-carbazide and detected by UV–vis spectrometry. In
order to quantify the risk of exposure, the risk assessment methodology employed by the Environmental Protection Agency of
the United States was applied at a screening level. The assumed scenarios included extreme exposure patterns (ingestion of
untreated water, conversion of Cr(III) to Cr(VI), temporal peaks of pollution). Fe, Al, Cd, Hg, and Pb were not included in
the risk analysis, since they showed a low toxicity potential or were undetected in the samples. The selected metals presented
Hazard Quotients < 1, in the following order of increasing risk: Cu < Cr(III) < Zn < Ni < Mn < Cr(VI). Hazard indexes, representing
the additive effect of contaminants, were also low in the basin (< 1), but comparatively increased in the lower reach of Feitoria
and Cadeia Rivers. Although noncarcinogenic risk levels did not suggest possible adverse toxicological effects to the human
population, a considerable deviation from background conditions was observed downstream the area where tanneries are mainly
located. 相似文献
27.
Lucia Fanini Giovanni Maria Marchetti Felicita Scapini Omar Defeo 《Marine Biology》2007,152(5):1169-1179
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Marco Dellavedova Lucia Gigante Angelo Lunghi Christian Pasturenzi Paolo Cardillo Niccolò P. Gerosa Renato Rota 《Journal of Loss Prevention in the Process Industries》2010,23(4):515-521
Nowadays many chemical industries are SMEs where multi-purpose batch or semi-batch reactors are commonly used. Vent sizing for realistic runaway scenario is not an easy task for such enterprises since they have usually few resources and use multi-purpose reactors with fast process turnovers. As a consequence these batch and semi-batch reactors are usually equipped with emergency relief systems sized once forever when the reactor is designed. This can lead to a large underestimation of the vent area in case of runaway reactions occurring when processes different from the ones considered for originally sizing the vent are carried out.The approach proposed in this work aims to identify the maximum reactor load leading to safe conditions even in case of runaway phenomena to be handled with the emergency relief system already installed (or even with a smaller vent area). This approach allows avoiding the change of the emergency relief system with a larger vent area (as required every time a new more hazardous process has to be carried out on existing reactors) at the price of lower plant productivity. 相似文献
30.
Lucia Mastrorillo Roberto Mazza Fabio Manca Paola Tuccimei 《Journal of Coastal Conservation》2016,20(6):423-441
The coastal aquifer of Rome is hosted in the Tiber River Delta depositional sequence, in a densely populated area, which was reclaimed at the end of the 19th century. Moderate salinization processes characterize this aquifer. Hydrogeological and hydrochemical surveys were carried out in October 2012 and February 2013 in the southern sector of the Delta. Hydrogeological surveys updated knowledge of groundwater morphology and a detailed conceptual hydrogeological model of the coastal aquifer was realized. Hydrochemical analyses helped to identify the salinization spatial distribution and to specify the main groundwater types. The most salinized water was not detected close to the coastline, where seawater intrusion processes would be expected, but in the inner areas. Moreover, the salinization processes resulted to be slightly marked. Results so far suggest that the source of salinization may be related more to a combination of land use and historical development of the Tiber River Delta, rather than to seawater. 相似文献