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Small farmers who supply the city of Bogotá with food are facing many challenges that are jeopardizing their livelihoods and by extension, the food security of Colombia’s capital. We expect future changes in climatic conditions to exacerbate the plight of the small farmers and this is expected to compromise Bogota’s food security even further. This paper specifically seeks to assess the impact of climate change (CC) on the livelihoods of smallholders who supply Bogota with most of its food. In our multidisciplinary methodology, we translated the exposure to CC into direct impact on crops and assessed sensitivity and adaptive capacity using the sustainable rural livelihoods framework. The results show that rainfall (by average of 100 mm) and temperature (by average of 2.1 °C) will increase over the study area, while the future climate suitability of the most important crops such as mango (Mangifera indica), papaya (Carica papaya), corn (Zea mays) and plantain (Musa balbisiana) shows a decrease of 19 % to 47 % climate suitability by the year 2050. The assessment of sensitivity and adaptive capacity demonstrates that farmers participating in a farmers’ market, initiated by several local and international non-governmental organizations (NGOs), are less vulnerable to CC than farmers who sell through intermediaries. Those farmers selling directly to consumers in the farmers’ market have a higher adaptive capacity (3 on a scale of 3) in social and financial capital than those selling to intermediaries with less adaptive capacity (1 on a scale of 3). In light of the reduction in overall climatic suitability of some of the major crops and the change of geographic location of suitability for others, there are likely to be serious threats for Bogotá’s food security, the ecological landscape around the city, and farmers’ livelihoods. We further conclude that unless proper adaptation measures are implemented, the geographical shift in climate suitability may also force farmers to shift their crops to higher elevations including remaining forests and páramos (the Colombian alpine tundra ecosystems), which may be threatened in the near future.  相似文献   
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In smelting processes, a large amount of off-gas emission is often generated, which can cause serious environmental and plant hygiene problems if not properly treated. Off-gas cleaning systems extract and treat the hazardous emissions, and ensure that the smelter operation is in accordance with environmental and industrial hygiene regulations. To this end, it is paramount that a well-designed control structure be incorporated into the system. In this work a plantwide control design procedure is applied to an industrial nickel smelter furnace off-gas cleaning system. We first approach the problem by conducting a steady-state analysis based on a nonlinear model of the process, where the objective is to determine how to achieve safe, clean and economic operation in terms of energy consumption. Results reveal that a large amount of energy can be saved by controlling the temperature in the furnace freeboard at its upper bound (active constraint). For the same reason, the temperatures in the two louvers (active constraints) should be controlled at their respective upper bounds so to minimize air intake into the system. The selection of the “unconstrained” variable to be controlled is found by applying the self-optimizing control technique, and the results indicate that a small loss is acceptable when one of the manipulated variables is fixed at its nominal optimal operating point, a highly desirable choice from an operational viewpoint. The bottleneck of the system is identified as the fans' discharge pressures when we allow the feed rate as a degree of freedom. Furthermore, a design change consisting of the installation of an auxiliary air intake in the smelter furnace shows to be a very effective economic alternative to minimize energy consumption. A control structure is then designed where the issue is to keep pressures in the system well within the negative region by determining the configuration of the regulatory and supervisory control layers such that acceptable dynamic performance in face of known, deterministic disturbance is achieved. Nonlinear dynamic simulations are performed to validate the suggested control structure for both modes of operation in the original system and in the proposed design change. The results showed that both regulatory and supervisory designs should make use of the simplicity of decentralized PI control schemes associated with some cascaded configurations so as to boost the disturbance rejection capabilities of the system.  相似文献   
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Journal of Material Cycles and Waste Management - Hulls are considered residues from rice production, and due to its low commercial value, there is little interest in developing biotechnological...  相似文献   
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A southern Italian area that is characterized by large outcrops of rocks that are rich in titanium oxide (TiO2) phases were investigated to determine the mineralogical risk induced by the natural dispersion of TiO2 minerals. Rock, sediment and surface water samples were collected to determine the physicochemical and mineralogical factors (i.e., size distribution, morphology and alteration) indicative of potential TiO2 toxicity. X-ray diffraction data suggested that titanium oxides were present as rutile and anatase. Scanning electron microscopy images showed elongated TiO2 morphologies; fibres were found as either isolated or embedded/enclosed in flake-like phyllosilicates. The concentration of fibres in stream water ranged from 1.7 to 4.6 million fibres per litre. The highest fibre amounts in the sediments were in the <8-µm fraction, while single fibres were primarily concentrated in the <2-µm fraction. The results indicate that titanium oxide minerals represent a natural source of environmental risk and that the geomineralogical characterization of rich TiO2 areas is indispensable for understanding their geoavailability, dispersion and distribution.

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The solid-solution distribution or partition coefficient (Kd) is a measure of affinity of potentially toxic elements (PTE) for soil colloids. Kd plays a key role in several models for defining PTE guideline values in soils and for assessing environmental risks, and its value depends on edaphic and climatic conditions of the sites where the soils occur. This study quantified Kd values for Cd, Co, Cr, Cu, Hg, Ni, Pb, and Zn from representative soil samples from Brazil’s eastern Amazon region, which measures 1.2 million km2. The Kd values obtained were lower than those set by both international and Brazilian environmental agencies and were correlated with the pH, Fe and Mn oxide content, and cationic exchange capacity of the soils. The following order of decreasing affinity was observed: Pb?>?Cu?>?Hg?>?Cr?>?Cd?≈?Co?>?Ni?>?Zn.  相似文献   
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In the lower Guadalquivir river basin, a system stressed by a wide variety of anthropogenic activities, eight pesticides (four triazines, two chloroacetanilide herbicides, one organochlorine, and one organophosphorus insecticide); and four emerging pollutants (two personal care products, one organophosphorous flame retardant, and one xanthine alkaloid) were analyzed in river water during a 2-year monitoring program, and after rain episodes. Samples were extracted using the solid phase extraction (SPE) technique prior to determination of compounds using gas chromatograph coupled to a mass spectrometer detector. Except for caffeine, recoveries were mostly above 80 %, while limits of detection and quantification were in the low nanograms per liter level (except for dimethoate). Terbuthylazine, simazine (triazine herbicides), and dimethoate (organophosphorus insecticide), present in agrochemicals, were predominant in the river water, although concentrations were below the quality standards established by the EU Water-Framework-Directive. A general trend to increase concentration was observed after rain events, in particular for pesticides, possibly as a consequence of surface runoff.  相似文献   
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