Co-utilisation of CO2 and steelmaking slags for production of pure CaCO3 – legislative issues

The steel industry is characterised by large amounts of CO₂ emissions, but there is no easy means to reduce these emissions. One interesting option for the reduction of CO₂ emissions could be the utilisation of steelmaking slags for carbon dioxide mineralisation. In this option CO₂ is bound with the calcium of the slag material, producing stable carbonate as an end product. The utilisation of steelmaking slags as the raw material for carbon dioxide mineralisation will change the quality of the slags. If, however, this change degrades the slags it could prevent the use of slags in carbon dioxide mineralisation or make it very expensive.The purpose of the research presented here is to evaluate this issue with the help of a case study where the quality of the residual slag from the recently suggested carbonation method was experimentally investigated. The CO₂ mineralisation method, based on steelmaking slags and ammonium salt solutions, was found to change the quality of the slags: the calcium content was reduced, the CaO and Ca(OH)₂ phases were completely dissolved, and the solubility of the V and Cr increased notably. This residual slag would presumably have to be handled as waste. Currently, the steelmaking slag used in the case study is defined as a by-product, but if it is used for CO₂ mineralisation instead of liming its legal status will be re-evaluated. Subsequently, the CO₂ mineralisation process could possibly be defined as an end-of-waste procedure.     

Increased seawater temperature and light during early springs accelerate receptacle growth of Fucus vesiculosus in the northern Baltic proper

In many temperate estuarine areas, ongoing climatic changes are expected to lead to higher seawater temperatures, to increased inflow of freshwater and nutrients (due to increased rainfall) and to altered light conditions. During the last two decades, several winters have been unusually mild in southern Finland, and the subsequent springs have been early. This may have consequences for the seasonality of many species, including the bladder-wrack, Fucus vesiculosus, whose reproductive cycle may be especially sensitive. In the present study, F. vesiculosus receptacles from the field were weighed regularly during three warm (early) springs and compared with receptacles from three cold (late) springs. On average, the first sign of receptacle growth in the field occurred 5–6?weeks earlier and receptacles probably matured 2–3?weeks earlier during the warm springs than during the cold springs. This may be due to differences in seawater temperatures among years, but significantly heavier receptacles at 0.8?m compared to at 3.1?m further suggests the importance of light for receptacle growth as a measure of maturation, since there were no depth-related differences in seawater temperatures. Also, when plotting receptacle wet weights against seawater temperatures, the importance of light can be seen as different regression relationships (slopes and intercepts). In an outdoor aquarium experiment, the effects of temperature and light on receptacle growth were also tested, and there were significant differences between shallow and deep specimens, but temperature and light had no effects, except on initial receptacle growth. Since oogonian development, and thereby the time for zygote release, followed the receptacle growth curve, this could mean a mismatch between the timing of F. vesiculosus zygote settlement and the cover of competing filamentous algae, but such species interactions require further investigations in order to better understand their possible consequences.     

Intake fraction distributions for benzene from vehicles in the Helsinki metropolitan area

The intake fraction (iF) gives a measure of the portion of a source's emissions that is inhaled by an exposed population over a defined period of time. This study examines spatial and population-based iF distributions of a known human carcinogen, benzene, from a ubiquitous urban source, local vehicular traffic, in the Helsinki Metropolitan Area using three computational methods. The first method uses the EXPAND model (EXPosure to Air pollution, especially to Nitrogen Dioxide and particulate matter), which incorporates spatial and temporal information on population activity patterns as well as urban-scale and street canyon dispersion models to predict spatial population exposure distributions. The second method uses data from the personal monitoring study EXPOLIS (Air Pollution Exposure Distributions of Adult Urban Populations in Europe) to estimate the intake fractions for individuals in the study. The third method, a one-compartment box model provides estimates within an order-of-magnitude or better for non-reactive agents in an urban area. Population intake fractions are higher using the personal monitoring data method (median iF 30 per million, mean iF 39 per million) compared with the spatial model (annual mean iF 10 per million) and the box model (median iF 4 per million, mean iF 7 per million). In particular, this study presents detailed intake fraction distributions on several different levels (spatial, individual, and generic) for the same urban area.     

Ditch network maintenance in peat-dominated boreal forests: Review and analysis of water quality management options

The objective of this study was to evaluate the potential of different water management options to mitigate sediment and nutrient exports from ditch network maintenance (DNM) areas in boreal peatland forests. Available literature was reviewed, past data reanalyzed, effects of drainage intensity modeled, and major research gaps identified. The results indicate that excess downstream loads may be difficult to prevent. Water protection structures constructed to capture eroded matter are either inefficient (sedimentation ponds) or difficult to apply (wetland buffers). It may be more efficient to decrease erosion, either by limiting peak water velocity (dam structures) or by adjusting ditch depth and spacing to enable satisfactory drainage without exposing the mineral soil below peat. Future research should be directed towards the effects of ditch breaks and adjusted ditch depth and spacing in managing water quality in DNM areas.     

Fluoride distribution in the environment along the gradient of a phosphate-fertilizer production emission (southern Brazil)

Airborne fluoride was determined in the rainwater, surface soil and groundwater along a gradient of emission of a phosphate fertilizer factory in Rio Grande, southern Brazil. Concentrations of fluoride in rainwater and groundwater achieved 3 mg l⁻¹ and 5 mg l⁻¹, respectively, and were dependent on pH. The fluoride deposited from emissions accumulated in a superficial horizon of soil in quantities comparable to those in the manufactured end-products—up to 23,000 mg kg⁻¹. Fluoride distribution in the environment is controlled by physical–chemical parameters of emission, rain intensity and soil properties. The highest fluoride concentrations were registered at a close distance of up to 2 km from the factory. The distribution of fluoride in groundwater resembled the same distribution in rainwater due to the high permeability of the local soils. Fluoride penetration to the groundwater also depended on the type of vegetation cover. The groundwater in woodland areas was less affected by contamination of fluoride than in the grassland areas, most probably because of the influence of eucalyptus throughfall, which increases the pH of wet precipitates.     

Causal relationships between African mahoganies exports and deforestation in Ghana: policy implications

When exploiting forest resources, the resource use must be sustainable if its use is to support its function in the natural ecosystem. The African mahogany, a prized timber species, is widely exploited, raising policy concerns about the management of forest resources to meet the social, economic, and ecological needs of present and future generations. This paper explores, for the purpose of policy implication, the relationship between the exportation and deforestation of African mahoganies. The analysis employed a Granger causality test within the error correction model to evaluate the direction of causality between African mahoganies exports and deforestation in Ghana. The results suggested that in the short run, there was significant (P < 0.01) unidirectional causality from African mahoganies exports to deforestation. However, there was no directional causality from deforestation to mahogany exports. Thus, mahogany extraction and logging in general are among the major factors contributing to deforestation in Ghana. The general assessment of historical trends in the extraction levels of the two main genera of African mahoganies revealed that Entandrophragma cylindricum and Khaya ivorensis have been the most exploited species over the years. Improvements in, and the enforcement of, existing forest institutions and incentives, as well as related policies, could minimise the rate of deforestation not only of the African mahogany but also in timber logging, thus stemming forest degradation and deforestation in the country.     

Barriers to Water Conservation in the Rio Grande Basin1

Abstract: The Rio Grande basin shares problems faced by many arid regions of the world: growing and competing demands for water and river flows and uses that are vulnerable to drought and climate change. In recent years legislation, administrative action, and other measures have emerged to encourage private investment in efficient agricultural water use. Nevertheless, several institutional barriers discourage irrigators from investing in water conservation measures. This article examines barriers to agricultural water conservation in the Rio Grande basin and identifies challenges and opportunities for promoting it. Several barriers to water conservation are identified: clouded titles, water transfer restrictions, illusory water savings, insecure rights to conserved water, shared carry‐over storage, interstate compacts, conservation attitudes, land tenure arrangements, and an uncertain duty of water. Based on data on water use and crop production costs, price is found to be a major factor influencing water conservation. A low water price discourages water conservation even if other institutions promote it. A high price of water encourages conservation even in the presence of other discouraging factors. In conclusion, water‐conserving policies can be more effectively implemented where water institutions and programs are designed to be compatible with water’s underlying economic scarcity.