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Paula?Adánez SanjuánEmail author Belinda?Flem Juan?F.?Llamas Borrajo Juan?Locutura Rupérez Angel?Garcia Cortés 《Environmental geochemistry and health》2016,38(2):449-468
Changes in the principal sources of Pb in overbank sediment profiles have been documented for two Spanish areas by using Pb isotopes and Pb concentrations. These locations (Madrid and Tinto–Odiel basin) represent two of the most contaminated regions in Spain. The Community of Madrid is characterized by heavy industrial and urban activity, focused mainly in Madrid City. The Tinto–Odiel basin drains the Iberian Pyrite Belt, which hosts many polymetallic massive sulphides and is heavily affected by mining activities in their headwaters. It has been proven that the influence of anthropogenic activity is reflected in these overbank deposits by variations in Pb concentrations that, in general, correlate with shifts in the 206Pb/207Pb ratio. Rivas profile (downstream of Madrid) was found to be the most anthropogenically influenced site. The sediments within this profile which were recently deposited (170 ± 40 years BP) have the least radiogenic signatures. 206Pb/207Pb ratios ranged between 1.1763 and 1.1876 indicating significant contributions of anthropogenic Pb. In contrast, profiles upstream of Madrid possess an average 206Pb/207Pb ratio of 1.2272. It is difficult to clearly identify the most prominent source as the sediments appear to be characterized by an input from several sources. The floodplain profiles in the Tinto–Odiel basin exhibit uniform 206Pb/207Pb ratios ranging from 1.1627 (Odiel river) to 1.1665 (Tinto river). These ratios are similar to the ones possessed by sulphide ores in the area and differ from the ratios of other nonmineralized formations in the basin, indicating that mining activities are the primary, if not sole, source of Pb to the sediments. 相似文献
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Morton-Bermea Ofelia Beramendi-Orosco Laura Martínez-Reyes Ángeles Hernández-Álvarez Elizabeth González-Hernández Galia 《Environmental geochemistry and health》2016,38(1):195-202
Environmental Geochemistry and Health - Tree rings may be used as indicators of contamination events providing information on the chronology and the elemental composition of the contamination. In... 相似文献
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Lenka Okenicová Mária Žemberyová Simona Procházková 《Environmental Chemistry Letters》2016,14(1):67-77
Some trace metals are highly toxic for the environment. There is therefore a need for reliable methods for the determination of metals at trace levels. To this end, new sample pretreatment methods such as separation, preconcentration and speciation prior to the determination of metal ions have developed rapidly. Biosorption has become a major tool for solid-phase extraction methods. This review covers selected biosorbents such as algae, bacteria, filamentous fungi and yeasts, as new sorbents used in the solid-phase extraction of metal ions from various water sample matrices. A survey of the literature over 2004-2014 shows possible applications of selected new sorbents available for use in trace metal analysis in waters using solidphase extraction. We highlight the preconcentration of the toxic elements prior to their determination by atomic spectrometry. 相似文献