Analysis of priority substituted phenols by micellar electrokinetic chromatography

The use of micellar electrokinetic capillary chromatography (MECC) for the separation of eleven substituted phenols listed by the United States Environmental Protection Agency as priority pollutants was demonstrated. The effects of the pH and ionic strength of the buffer, and the length of the separation column on resolution were investigated. The retention characteristics of the eleven phenols in MECC are discussed.     

The Moral Considerability of Invasive Transgenic Animals

The term moral considerability refers to the question of whether a being or set of beings is worthy of moral consideration. Moral considerability is most readily afforded to those beings that demonstrate the clearest relationship to rational humans, though many have also argued for and against the moral considerability of species, ecosystems, and “lesser” animals. Among these arguments there are at least two positions: “environmentalist” positions that tend to emphasize the systemic relations between species, and “liberationist” positions that tend to emphasize the attributes or welfare of a particular individual organism. Already, this classic conflict provides for some challenging theoretical clashes between environmentalists and animal liberationists. The question of moral considerability is complicated, however, by recent developments in genetic engineering. Some animals, like pigs and fish, have been genetically modified by humans to grow organs that can then be transplanted into humans. If environmental arguments for the moral consideration of species are correct, then we are released from our obligations to morally consider those animals that we have genetically modified, since they are by their nature always an “invader species.” If, instead, the welfare of the animal is of penultimate importance, then there is a case for strengthening the moral considerability of GM animals over “naturally-occurring” animals, since they bear a closer relationship to humans. This would appear to be an intractable problem, a “bad marriage,” as Mark Sagoff once proposed. This paper argues that the case of invasive transgenic animals exposes weaknesses in this classic conflict, and particularly, in the framing of this conflict. To remedy this framing problem, this paper argues for a reconceptualization of the term “moral considerability,” instead urging a strong distinction between moral considerability, moral relevance, and moral significance.     

Satisfying shoppers’ psychological needs: From public market to cyber-mall

In many cities in North America and Europe, shopping centres are replacing the traditional high street shops. At the same time, electronic shopping is growing rapidly. In this paper, the results of a literature review of environment–behaviour research on shopping and shopping environments (e.g., farmer's markets, shopping centres, and electronic shopping) are presented. The focus of analysis is on how the physical features (e.g., layout and background music) influence shoppers’ experiences, and on how well these environments satisfy the psychological needs of their shoppers (e.g., social interaction, sensory stimulation, and security and comfort). Any implications for environmental design, and the future of shopping environments are discussed. A conceptual framework and suggestions for future research are proposed.     

Method for rapid on-site identification of VOCs

Rapid on-site identification of volatile organic compounds (VOCs) in ambient air is an important first step in remediation efforts. This study describes modification of a commercially available, portable GC/MS system and development of an analysis protocol for rapid (<3 min) sampling and identification of VOCs typically found at contaminated sites at the low ppbv level.     

Mixing dynamics of turbidity currents interacting with complex seafloor topography

Direct Numerical Simulations are employed to investigate the mixing dynamics of turbidity currents interacting with seamounts of various heights. The mixing properties are found to be governed by the competing effects of turbulence amplification and enhanced dissipation due to the three-dimensional topography. In addition, particle settling is seen to play an important role as well, as it affects the local density stratification, and hence the stability, of the current. The interplay of these different mechanisms results in the non-monotonic dependence of the mixing behavior on the height of the seamount. Regions of dilute lock fluid concentration generally mix more intensely as a result of the seafloor topography, while concentrated lock fluid remains relatively unaffected. For long times, the strongest mixing occurs for intermediate bump heights. Particle settling is seen to cause turbidity currents to mix more intensely with the ambient than gravity currents.     

Supported single-atom catalysts: synthesis,characterization, properties,and applications

In recent years, there has been a wide research in supported single-atom catalysts (SACs), which contain only isolated individual metal atoms dispersed on an appropriate support or coordinated with the surface atoms of the support. The SACs exhibit many fascinating characteristics including high activity, selectivity, and maximum atomic utilization. These characteristics arise from the low coordination status, quantum size effect, and the strong metal–support interaction, which have proved to be very powerful in many typical heterogeneous catalysis field including oxidation, hydrogenation, the water–gas shift reaction, methanol steam reforming, electrocatalysis, and photocatalysis. In this review, we summarized the recent progress in synthesis, characterizations, properties, and applications of SACs.     

Increased spatial variance accompanies reorganization of two continental shelf ecosystems

Phase transitions between alternate stable states in marine ecosystems lead to disruptive changes in ecosystem services, especially fisheries productivity. We used trawl survey data spanning phase transitions in the North Pacific (Gulf of Alaska) and the North Atlantic (Scotian Shelf) to test for increases in ecosystem variability that might provide early warning of such transitions. In both time series, elevated spatial variability in a measure of community composition (ratio of cod [Gadus sp.] abundance to prey abundance) accompanied transitions between ecosystem states, and variability was negatively correlated with distance from the ecosystem transition point. In the Gulf of Alaska, where the phase transition was apparently the result of a sudden perturbation (climate regime shift), variance increased one year before the transition in mean state occurred. On the Scotian Shelf, where ecosystem reorganization was the result of persistent overfishing, a significant increase in variance occurred three years before the transition in mean state was detected. However, we could not reject the alternate explanation that increased variance may also have simply been inherent to the final stable state in that ecosystem. Increased variance has been previously observed around transition points in models, but rarely in real ecosystems, and our results demonstrate the possible management value in tracking the variance of key parameters in exploited ecosystems.     

Toxicity of atmospheric particle-bound PAHs: an environmental perspective

Atmospheric polycyclic aromatic hydrocarbons (PAHs) are environmental pollutants that represent a risk not only to humans, but to all living organisms. High-molecular weight PAHs are more toxic than lighter relatives, and also have a higher tendency to bind onto air particles (i.e., particle matter, PM). PM is a major constituent of air pollution. Adequate assessment of the biological impact of PM requires the analysis, not only of the effects on human health, but also on the environment. Since the aquatic systems work as a natural sink to these air pollutants, assessing the effects of particle-bound PAHs on aquatic organisms may further characterize its potential aquatic toxicity, also providing simple and low-cost alternative assays to investigate PM biological effects in vivo. We review the current scientific literature, addressing the atmospheric PAHs fate, transformation and deposition, pertinent particle-bound PAHs toxicity data, and the potential aquatic toxic burden. Conceptual and experimental procedures that could improve future investigations and risk assessments are also considered.     

Adaptation of agriculture to climate change in semi-arid Borena,Ethiopia

Livestock production is very risky due to climate variability in semi-arid Sub-Saharan Africa. Using data collected from 400 households in the Borena zone of the Oromia Region, we explored what drives adoption of agricultural practices that can decrease the vulnerability of agro-pastoralists to climate change. Households with more adaptive capacity adopted a larger number of practices. The households’ adaptive capacity was stronger when the quality of local institutions was high. However, adaptive capacity had less explanatory power in explaining adoption of adaptation options than household socio-economic characteristics, suggesting that aggregating information into one indicator of adaptive capacity for site-specific studies may not help to explain the adoption behaviour of households. Strong local institutions lead to changes in key household-level characteristics (like membership to community groups, years lived in a village, access to credit, financial savings and crop income) which positively affect adoption of agricultural practices. In addition, better local institutions were also positively related to adoption of livestock-related adaptation practices. Poor access to a tarmac road was positively related to intensification and diversification of crop production, whereas it was negatively related to the intensification of livestock production, an important activity for generating cash in the region. Our findings suggest that better local institutions lead to changes in household characteristics, which positively affect adoption of adaptation practices, suggesting that policies should aim to strengthen local institutions.     

Apportionment of bioavailable phosphorus loads entering Cayuga Lake,New York

The integration of the phosphorus (P) bioavailability concept into a P loading analysis for Cayuga Lake, New York, is documented. Components of the analyses included the: (1) monitoring of particulate P (PP), soluble unreactive P (SUP), and soluble reactive P (SRP), supported by biweekly and runoff event‐based sampling of the lake's four largest tributaries; (2) development of relationships between tributary P concentrations and flow; (3) algal bioavailability assays of PP, SUP, and SRP from primary tributaries and the three largest point sources; and (4) development of P loading estimates to apportion contributions according to individual nonpoint and point sources, and to represent the effects of interannual variations in tributary flows on P loads. Tributary SRP, SUP, and PP are demonstrated to be completely, mostly, and less bioavailable, respectively. The highest mean bioavailability for PP was observed for the stream with the highest agriculture land use. Point source contributions to the total bioavailable P load (BAP_L) are minor (5%), reflecting the benefit of reductions from recent treatment upgrades. The BAP_L represented only about 26% of the total P load, because of the large contribution of the low bioavailable PP component. Most of BAP_L (>70%) is received during high flow intervals. Large interannual variations in tributary flow and coupled BAP_L will tend to mask future responses to changes in individual inputs.