First compound-specific chlorine-isotope analysis of environmentally-bioaccumulated organochlorines indicates a degradation-relatable kinetic isotope effect for DDT

Compound-specific chlorine-isotope analysis (CSIA-Cl) of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (p,p'-DDT) and 1,1-dichloro-2,2-bis(p-chlorophenyl)ethene (p,p'-DDE) in blubber from Baltic Grey seal (Halichoerus grypus) was performed in order to investigate if a kinetic isotope effect (KIE) could be observed concomitant to environmental degradation of DDT. The delta(37)Cl of p,p'-DDT and p,p'-DDE were -0.69 +/- 0.21 per thousand and -2.98 +/- 0.57 per thousand (1s igma, n = 3), respectively. Both samples were enriched relative to the hypothesized initial isotope composition (-4.34 per thousand), thus indicating a composite KIE associated with the degradation mechanisms pertaining to DDT. An isotope fractionation factor for degradation of dichloromethane, from the literature, was adapted and modified for use in the calculation of DDT degradation. A subsequent simplified Rayleigh distillation model of the DDT chlorine-isotope composition yielded an estimated fraction (f) of 7 +/- 2% of released DDT presently remaining as undegraded compound in the environment. The consistency between the result of the Rayleigh model (f approximately 7%) and the use of the DDT/(DDT + DDE) ratio as a measure of DDT degradation ( approximately 10% undegraded DDT) suggests that the KIE of DDT degradation may be significant, and that the novel approach of CSIA-Cl may be a valuable tool for degradation/persistence studies of lipophilic organochlorines in the environment.     

Nighttime lights and population changes in Europe 1992–2012

Nighttime satellite photographs of Earth reveal the location of lighting and provide a unique view of the extent of human settlement. Nighttime lights have been shown to correlate with economic development and population but little research has been done on the link between nighttime lights and population change over time. We explore whether population decline is coupled with decline in lighted area and how the age structure of the population and GDP are reflected in nighttime lights. We examine Europe between the period of 1992 and 2012 using a Geographic Information System and regression analysis. The results suggest that population decline is not coupled with decline in lighted area. Instead, human settlement extent is more closely related to the age structure of the population and to GDP. We conclude that declining populations will not necessarily lead to reductions in the extent of land development.     

Inspiring England's urban fringes: multi-functionality and planning

The urban fringe has been described as 'planning's last frontier'; a zone of transition and interface between town and country where a broad variety of land uses and activities come together, and where development pressure is often intense. In this paper, we argue that the urban fringe possesses special characteristics, making it more than simply a transitional landscape. These characteristics centre on patterns of land use, biodiversity and leisure/development opportunity which are unique to the urban edge and to land extending away from built-up areas. The uniqueness, diversity and particular dynamics of the urban fringe demands a special brand of planning and management response. Therefore we suggest that the principle of 'multi-functionality' provides a framework for action, showing how diversity can be managed and supported. Through brief case studies, we demonstrate how functional interactions at the urban fringe might be promoted in the future.     

The circular economy potential of urban organic waste streams in low- and middle-income countries

Environment, Development and Sustainability - There is growing recognition of the potential environmental and socio-economic benefits of applying a circular approach to urban organic waste...     

Landscape Development During a Glacial Cycle: Modeling Ecosystems from the Past into the Future

Understanding how long-term abiotic and biotic processes are linked at a landscape level is of major interest for analyzing future impact on humans and the environment from present-day societal planning. This article uses results derived from multidisciplinary work at a coastal site in Sweden, with the aim of describing future landscape development. First, based on current and historical data, we identified climate change, shoreline displacement, and accumulation/erosion processes as the main drivers of landscape development. Second, site-specific information was combined with data from the Scandinavian region to build models that describe how the identified processes may affect the site development through time. Finally, the process models were combined to describe a whole interglacial period. With this article, we show how the landscape and ecosystem boundaries are affected by changing permafrost conditions, peat formation, sedimentation, human land use, and shoreline displacement.     

Inhibition of ethoxyresorufin-O-deethylase (EROD) activity in mixtures of 2,3,7,8-tetrachlorodibenzo-p-dioxin and polychlorinated biphenyls

Induction of ethoxyresorufin-O-deethylase (EROD) activity and porphyrin accumulation shows different structure-activity relationships for different polychlorinated biphenyls (PCBs) and 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). Interactions between the two responses can strongly influence the induction and activity of EROD. The results support the conclusion that there are nonadditive interactions between nondioxin-like PCBs and dioxin-like compounds. The interaction between EROD activity and the porphyrin biosynthesis makes the prerequisite of additivity in the toxic equivalency factor concept for environmental mixtures highly spurious. Inhibition of EROD activity caused by non-dioxin like compounds could have a significant impact on the value of EROD activity as a biomarker in the present methods of risk assessment for these compounds.     

Polybrominated aromatic pollutants found in fish in Sweden

Polybrominated biphenyl ethers (PBBEs) have been found in fish caught in Swedish waters. The maximum level detected in muscular tissue was 0.15 mg/kg (27 mg/kg fat) in a pike (Esox lucius) caught in the south-west part of the country. The liver of the same specimen contained 22 mg PBBEs/kg (110 mg PBBEs/kg fat).