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201.
ABSTRACT

This study reports the first field measurements of airborne exavalent chromium (Cr(vi)) in southwestern Ontario. Hexavalent chromium was identified as an inhalation carcinogen and an air toxic of concern during the 1991-93 Windsor Air Quality Study. The results of that study indicated that approximately 20% of the routinely monitored ambient airborne chromium (Cr) was in the hexavalent form. In addition, the range of carcinogenic health risks attributable to airborne Cr(vi) was determined to be between 1.4 x IO6 and 3.0 x 10-4 for people living in the Windsor area. During the summer of 1993, analyses of concurrent indoor and outdoor 24-hour air quality samples taken at 33 residences in Hamilton resulted in geometric mean Cr(vi) concentrations of 0.20 r|g/m3 and 0.55 r|g/m3, respectively, and little or no relationship between the indoor and outdoor sample sets. During the summer of 1994, an airborne Cr(vi) size-fractionation study was conducted in Hamilton, the results of which suggested that the majority of the Cr(vi) was in the inhalable fraction.  相似文献   
202.
Global degradation of coastal ecosystems is influencing the provision of ecosystem services, including fisheries maintenance services. Degradation of the Australian coastal zone and its resources following European occupation has been recognised for some time. This includes the loss of ecologically important coastal wetlands, which have strong trophic and habitat links to fisheries. In NSW, structural flood mitigation works are a principle driver of the decline of coastal wetlands; however, little action has been taken to quantify the extent of decline due to limited information of the pre-European settlement extent of coastal wetlands. We use spatial data sets in GIS to quantify prime fish habitat and calculate the loss of fish habitat for the large coastal floodplains of northern NSW, which are significant contributors to the commercial and recreational fisheries of NSW. The technique is validated by comparison with early maps of wetland distribution. We identified pre-European distribution of available fish habitat of approximately 477,000 ha, of which 87,000 ha was identified as prime fish habitat. Approximately 62,000 ha of prime fish habitat was impacted by drainage of the coastal floodplains in association with flood mitigation works which intensified in the mid-1950s and were largely completed by 1971, equating to a loss of approximately 72 % of prime fish habitat. The declining value of the ecosystem services provided by prime fish habitat following drainage is likely to be substantial. Some actions have taken place to restore the functions of this habitat although significant opportunities remain to reverse this decline through management actions that restore natural drainage and reinstate tidal exchange. These actions become even more important as pressures on coastal wetlands increase with climate change and associated sea-level rise.  相似文献   
203.
Landscaping paradigms that encourage high‐input, intensively managed and mono‐culture turf/lawn landscapes have raised concerns about water quality. We conducted a watershed‐scale assessment of landscaping practices that included turf, urban, forest, native meadow, and mixed landuse watersheds with a professional golf course and a parking lot. The turf site was moderately managed and had lower fertilizer inputs than those typically used by homeowners and golf courses. Stream water sampling was performed during base flow and storm events. Highest nitrate and total nitrogen concentrations in runoff were observed for the mixed watershed draining the golf course. In contrast, concentrations in base flow from the turf watershed were lower than expected and were comparable to those measured in the surrounding meadow and forest sites. Total nitrogen concentrations from the turf site increased sharply during the first storms following fertilization, suggesting that despite optimal management there exists a risk for nutrient runoff following fertilization. Overall, this study suggests that turf or lawns, when managed properly, pose minimal water quality risk to surface waters. Rate, timing of application, and the type of fertilizer appear to be the key factors affecting water quality. Better education of homeowners and landscaping professionals with regard to these factors may be a cost‐effective strategy to reduce nonpoint source pollution.  相似文献   
204.
Land-use change is one of the major factors that alter local and regional hydrology. For areas experiencing fast expansion of urban and agriculture areas, land-use changes often adversely affect stream flow and water resources at the local and watershed scale. The Sekong, Sesan, and Srepok (3S) Sub-basins are a part of the Lower Mekong River Basin and include land in Cambodia, Lao People’s Democratic Republic (Laos), and Viet Nam. The region is experiencing a dynamic land-use transition because of rapid changes in its economy, society, and environment. Major land-use changes include deforestation of native rain forest, expansion of agricultural and urban areas, and expansion of commercial plantation such as rubber trees. These land-use alterations have affected local and regional hydrologic processes, resulting in stream flow shortages during the dry season and flash flooding due to deforestation. In this research, deforestation in the 3S Sub-basins over the period 1993–1997 was analyzed using multi-logistic regression. The regression analysis indicated that density of agricultural cells within a 5-km radius from each forest cell and slope strongly affected the deforestation process. A land-use forecast model to simulate deforestation and urbanization sites was developed in GIS based on local land-use change trends. The model was applied to 2003 land use to forecast 2033 land use and future water demand, which was further compared with present stream flow measurements during the dry season at various places in the region. The entire approach from the land-use forecast to its impact assessment on stream flow could help local stakeholders understand watershed-wide future water resources risks and develop future water resources plans. With the 3S Sub-basins being used as a case study area, this article presents a land-use forecast tool; simulated 2033 land-use and water demand; and the estimation of the impact of the forecasted future water demand on the local stream flow.  相似文献   
205.
The prey naivety hypothesis posits that prey are vulnerable to introduced predators because many generations in slow gradual coevolution are needed for appropriate avoidance responses to develop. It predicts that prey will be more responsive to native than introduced predators and less responsive to introduced predators that differ substantially from native predators and from those newly established. To test these predictions, we conducted a global meta-analysis of studies that measured the wariness responses of small mammals to the scent of sympatric mammalian mesopredators. We identified 26 studies that met our selection criteria. These studies comprised 134 experiments reporting on the responses of 36 small mammal species to the scent of six introduced mesopredators and 12 native mesopredators. For each introduced mesopredator, we measured their phylogenetic and functional distance to local native mesopredators and the number of years sympatric with their prey. We used predator and prey body mass as a measure of predation risk. Globally, small mammals were similarly wary of the scent of native and introduced mesopredators; phylogenetic and functional distance between introduced mesopredators and closest native mesopredators had no effect on wariness; and wariness was unrelated to the number of prey generations, or years, since first contact with introduced mesopredators. Small mammal wariness was associated with predator-prey body mass ratio, regardless of the nativity. The one thing animals do not seem to recognize is whether their predators are native.  相似文献   
206.
This paper presents a practical risk assessment methodology to provide drinking water infrastructure (DWI) decision-makers with an objective risk assessment tool. The purpose of this risk assessment tool is to maintain the desired level-of-service or systems reliability [r(f)], while managing the financial uncertainty of the expected budgetary impact within the capital improvement program (CIP). The goal of this paper is to demonstrate the value of an objective risk assessment tool for estimating the DWI decision-maker's sensitivity to the risk of systems failure (R). The objectives are to: (1) incorporate probability of systems failure [p(f)] into the CIP budgetary analysis process and (2) evaluate the affects of p(f) on the expected CIP budgetary outcome. The magnitude of the expected budgetary impact is managed through the DWI decision-maker's sensitivity to R, which is represented by the level of the rate of reinvestment (RR). The expected result of the proposed risk assessment tool demonstrates that by proactively managing R to maintain a desired r(f) will effectively manage the impact of uncertainty on the expected budgetary outcome within the CIP. The expected contribution of the practical risk assessment methodology is to provide DWI decision-makers with the ability to reduce budgetary uncertainty when allocating limited financial resources among competing operational, repair, maintenance, and expansion activities within the CIP. The conclusions of the paper reveal that if DWI decision-makers assume risk-avoidance positions through proactive asset management (AM) strategies, they will achieve positive affects on expected budgetary outcomes.  相似文献   
207.
The weathering of coal combustion products (CCPs) in a lotic environment was assessed following the Tennessee Valley Authority (Kingston, TN) fly ash release of 2008 into surrounding rivers. Sampled materials included stockpiled ash and sediment collected from 180 to 880 days following the release. Total recoverable concentrations of heavy metals and metalloids in sediment were measured, and percent ash was estimated visually or quantified by particle counts. Arsenic and selenium in sediment were positively correlated with percent ash. For samples collected 180 days after the release, total concentrations of trace elements downstream of the release were greater than reference levels but less than concentrations measured in stockpiled ash. Total concentrations of trace elements remained elevated in ash-laden sediment after almost 2.5 years. A sequential extraction procedure (SEP) was used to speciate selected fractions of arsenic, copper, lead, nickel, and selenium in decreasing order of bioavailability. Concentrations of trace elements in sequentially extracted fractions were one to two orders of magnitude lower than total recoverable trace elements. The bulk of sequentially extractable trace elements was associated with iron-manganese oxides, the least bioavailable fraction of those measured. By 780 days, trace element concentrations in the SEP fractions approached reference concentrations in the more bioavailable water soluble, ion exchangeable, and carbonate-bound fractions. For each trace element, the percentage composition of the bioavailable fractions relative to the total concentration was calculated. These SEP indices were summed and shown to significantly decrease over time. These results document the natural attenuation of leachable trace elements in CCPs in river sediment as a result of the loss of bioavailable trace elements over time.  相似文献   
208.
At all levels, the understanding of uncertainty associated with risk of major chemical industrial hazards should be enhanced. In this study, a quantitative risk assessment (QRA) was performed for a knockout drum in the distillation unit of a refinery process and then probabilistic uncertainty analysis was applied for this QRA. A fault tree was developed to analyze the probability distribution of flammable liquid released from the overfilling of a knockout drum. Bayesian theory was used to update failure rates of the equipment so that generic information from databases and plant equipment real life data are combined to gain all available knowledge on component reliability. Using Monte Carlo simulation, the distribution of top event probability was obtained to characterize the uncertainty of the result. It was found that the uncertainty of basic event probabilities has a significant impact on the top event probability distribution. The top event probability prediction uncertainty profile showed that the risk estimation is improved by reducing uncertainty through Bayesian updating on the basic event probability distributions. The whole distribution of top event probability replaces point value in a risk matrix to guide decisions employing all of the available information rather than only point mean values as in the conventional approach. The resulting uncertainty guides where more information or uncertainty reduction is needed to avoid overlap with intolerable risk levels.  相似文献   
209.
This study, informed by phenomenology and ethnography, explores urban children’s relationship with their urban environment: In what ways do urban children exhibit “insideness” in their sense of place? This study proposes “insideness” as a conceptual construct to understand urban children’s sense of place in its ecological and dynamic nature. Employing qualitative research methods, the study explores place stories of urban children who live in low-income, immigrant neighborhoods in New York City. The study finds that as children cultivate their sense of place, they construct “insideness” in their sense of place including 1) environmental understanding (i.e., contextualized, comprehensive, and critical understanding of a place), 2) environmental competence (i.e., knowing how to navigate and engage in a place), and 3) diverse, strong affective relationships with a place. Using “insideness” as a conceptual tool, this study discusses children’s emplaced understanding and active and dialogical positionality in the development of their sense of place.  相似文献   
210.
Non-migration is an adaptive strategy that has received little attention in environmental migration studies. We explore the leveraging factors of non-migration decisions of communities at risk in coastal Bangladesh, where exposure to both rapid- and slow-onset natural disasters is high. We apply the Protection Motivation Theory (PMT) to empirical data and assess how threat perception and coping appraisal influences migration decisions in farming communities suffering from salinization of cropland. This study consists of data collected through quantitative household surveys (n = 200) and semi-structured interviews from four villages in southwest coastal Bangladesh. Results indicate that most respondents are unwilling to migrate, despite better economic conditions and reduced environmental risk in other locations. Land ownership, social connectedness, and household economic strength are the strongest predictors of non-migration decisions. This study is the first to use the PMT to understand migration-related behaviour and the findings are relevant for policy planning in vulnerable regions where exposure to climate-related risks is high but populations are choosing to remain in place.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-021-01552-8.  相似文献   
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