全文获取类型
收费全文 | 3268篇 |
免费 | 384篇 |
国内免费 | 965篇 |
专业分类
安全科学 | 407篇 |
废物处理 | 147篇 |
环保管理 | 319篇 |
综合类 | 2202篇 |
基础理论 | 432篇 |
环境理论 | 1篇 |
污染及防治 | 549篇 |
评价与监测 | 196篇 |
社会与环境 | 199篇 |
灾害及防治 | 165篇 |
出版年
2024年 | 12篇 |
2023年 | 72篇 |
2022年 | 210篇 |
2021年 | 213篇 |
2020年 | 202篇 |
2019年 | 143篇 |
2018年 | 145篇 |
2017年 | 162篇 |
2016年 | 156篇 |
2015年 | 190篇 |
2014年 | 244篇 |
2013年 | 297篇 |
2012年 | 292篇 |
2011年 | 323篇 |
2010年 | 245篇 |
2009年 | 227篇 |
2008年 | 233篇 |
2007年 | 234篇 |
2006年 | 187篇 |
2005年 | 150篇 |
2004年 | 96篇 |
2003年 | 106篇 |
2002年 | 82篇 |
2001年 | 77篇 |
2000年 | 69篇 |
1999年 | 49篇 |
1998年 | 41篇 |
1997年 | 45篇 |
1996年 | 31篇 |
1995年 | 18篇 |
1994年 | 15篇 |
1993年 | 11篇 |
1992年 | 12篇 |
1991年 | 10篇 |
1990年 | 1篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有4617条查询结果,搜索用时 15 毫秒
151.
The adsorption behavior of 2-mercaptobenzothiazole onto organo-bentonite was investigated.Natural bentonite from Gaozhou in Guangdong Province,China was collected.Organo-bentonite was prepared by intercalation of cetyltrimethyl ammonium bromide into the natural bentonite.The physicochemical properties of the prepared organo-bentonite were characterized by X-ray diffraction,N2 adsorption-desorption isotherm and Fourier transform infrared spectroscopy.The results showed that montmorillonite is the main component of the natural bentonite.The basal spacing of the natural bentonite is 1.47 nm,which increased to 1.98 nm on intercalation with cetyltrimethyl ammonium bromide.Moreover,both the surface area and pore volume increased with intercalation.Clear CH2 stretching(3000-2800 cm-1) and scissoring(1480-1450 cm-1) modes of the intercalated surfactants were observed for organobentonite.Compared with the pseudo first-order kinetic model,the pseudo second-order kinetic model is more suitable to describe the adsorption kinetics of 2-mercaptobenzothiazole onto organo-bentonite.The adsorption capacity of 2-mercaptobenzothiazole onto organo-bentonite increased with increasing initial concentration of 2-mercaptobenzothiazole,but decreased with increasing adsorbent dosage.The adsorption isotherm of 2-mercaptobenzothiazole onto organo-bentonite fits well with the Langmuir model.The maximum adsorption capacity of organo-bentonite for 2-mercaptobenzothiazole was 33.61 mg/g,indicating that organo-bentonite is a promising adsorbent for 2-mercaptobenzothiazole. 相似文献
152.
Although microbial treatments of heavy metal ions in wastewater have been studied, the removal of these metals through incorporation into carbonate minerals has rarely been reported. To investigate the removal of Fe^3+ and Pb^2+, two representative metals in wastewater, through the precipitation of carbonate minerals by a microbial flocculant (MBF) produced by Bacillus mucilaginosus. MBF was added to synthetic wastewater containing different Fe^3+ and Pb^2+ concentrations, and the extent of flocculation was analyzed. CO2 was bubbled into the mixture of MBF and Fe^3+/Pb^2+ to initiate the reaction. The solid substrates were analyzed via X-ray diffraction, transmission electron microscopy and energy dispersive spectroscopy. The results showed that the removal efficiency decreased and the MBF adsorption capacity for metals increased with increasing heavy metal concentration. In the system containing MBF, metals (Fe^3+ and Pb^2+), and CO2, the concentrated metals adsorbed onto the MBF combined with the dissolved CO2, resulting in oversaturation of metal carbonate minerals to form iron carbonate and lead carbonates. These results may be used in designing a method in which microbes can be utilized to combine CO2 with wastewater heavy metals to form carbonates, with the aim of mitigating environmental problems. 相似文献
153.
Critical velocity in phosphorus exchange processes across the sediment-water interface 总被引:3,自引:0,他引:3
Sediments are ultimate sinks of nutrients in lakes that record the pollution history evolutionary processes, and anthropogenic activities of a lake. However, sediments are considered as inner sources of environmental factor changes such as the variation in hydrodynamic conditions because of the nutrients they release. How does this process happen? This study investigates a typical nutrient phosphorus (P) exchange among sediment, suspended particle matter (SPM), and water. Compared with numerical and experimental studies, this study confirms that the critical velocity that occurs at a lower flow rate state exists in the range of 7 to 15 crn/sec. Critical velocity below the critical flow rate promotes the migration of particulate phosphorus (PP) to the SPM. On the other hand, critical velocity above the critical flow rate promotes the release of PP in water. 相似文献
154.
155.
降雨引起边坡地下水位变化、降低岩土体抗剪强度进而引起边坡失稳产生滑坡是电网工程灾害中最常见的地质灾害之一。文章在现场详细工程地质勘察的基础上,基于恢复山体极限平衡法和强度折减法,利用数值分析方法对降雨引起地下水位变化条件下某电网工程边坡稳定性进行了分析。模拟结果表明,现今地下水位条件下,该边坡整体处于极限平衡状态;在最高洪水位条件下边坡则处于失稳状态。边坡的最大变形位于边坡中上部,并呈现出由上部逐渐向下部扩展的趋势。边坡潜在破坏模式为边坡后缘张拉破坏和中下部剪切破坏的复合破坏模式。最后基于数值分析结果,对该边坡的工程治理提出了建议。 相似文献
156.
介绍了餐饮废弃物的特点,处理不当污染环境,探讨餐饮废弃物无害化处理方式,并提出了针对餐饮业废弃物的环境管理对策。 相似文献
157.
实验生态条件下采用半静态急性毒性实验的方法,比较研究了96 h内不同浓度Cd2+和Pb2+对菲律宾蛤仔(Rudi-tapes philippinarum)的急性毒性效应,分析了不同配比的两种重金属离子的复合作用对目标生物的影响。结果表明:(1)在单一污染物胁迫条件下,Cd2+、Pb2+对菲律宾蛤仔的96 h半数致死浓度LC50分别为4.740 mg/L和31.116 mg/L,其对应的安全质量浓度分别为0.677 mg/L、1.844 mg/L。Cd2+的毒性效应更强。(2)Cd2+和Pb2+的复合毒性效应表明:在所设定的不同浓度配比条件和实验时间下,Cd2+、Pb2+对目标生物均表现出明显的协同作用。 相似文献
158.
159.
160.
万玉玲 《安全.健康和环境》2013,13(1):2-5
分析了近期国家陆续出台的各项政策对中国石化建设项目管理的影响,并提出了对策建议. 相似文献