Comparison of several packings for CO2 chemical absorption in a packed column

CO₂ capture and storage has gained widespread attention as an option for reducing greenhouse gas emissions. Chemical absorption and stripping of CO₂ with hot potassium carbonate (K₂CO₃) solutions has been used in the past, however potassium carbonate solutions have a low CO₂ absorption efficiency. Various techniques can be used to improve the absorption efficiency of this system with one option being the addition of promoters to the solvent and another option being an improvement in the mass transfer efficiency of the equipment. This study has focused on improving the efficiency of the packed column by replacing traditional packings with newer types of packing which have been shown to have enhanced mass transfer performance. Three different packings (Super Mini Rings (SMRs), Pall Rings and Mellapak) have been studied under atmospheric conditions in a laboratory scale column for CO₂ absorption using a 30 wt% K₂CO₃ solution. It was found that SMR packing resulted in a mass transfer coefficient approximately 20% and 30% higher than that of Mellapak and Pall Rings, respectively. Therefore, the height of packed column with SMR packing would be substantially lower than with Pall Rings or Mellapak. Meanwhile, the pressure drop using SMR was comparable to other packings while the gas flooding velocity was higher when the liquid load was above 25 kg m⁻² s⁻¹. Correlations for predicting flooding gas velocities and pressure drop were fitted to the experimental data, allowing the relevant parameters to be estimated for use in later design.     

Bioconcentration of triclosan, methyl-triclosan, and triclocarban in the plants and sediments of a constructed wetland

Constructed wetlands are a potential method for the removal of two pharmaceutical and personal care products from wastewater effluent. Triclosan (TCS; 5-chloro-2-[2,4-dichlorophenoxy]phenol) and triclocarban (TCC; 3,4,4′-trichlorocarbanillide) are antimicrobial agents added to a variety of consumer products whose accumulation patterns in constructed wetlands are poorly understood. Here, we report the accumulation of TCS, its metabolite methyl-triclosan (MTCS; 5-chloro-2-[2,4-dichlorophenoxy]), and TCC in wetland plant tissues and sediments. Three wetland macrophytes: Typha latifolia, Pontederia cordata, and Sagittaria graminea were sampled from a constructed wetland in Denton, Texas, USA. MTCS concentrations were below the method detection limit (MDL) for all species. TCS root tissue concentrations in T. latifolia were significantly greater than root concentrations in P. cordata (mean ± SE in ng g⁻¹: 40.3 ± 11.3 vs. 15.0 ± 1.9, respectively), while for TCC, shoot tissue concentrations in S. graminea were significantly greater than in T. latifolia (22.8 ± 9.3 vs. 9.0 (MDL), respectively). For both TCS and TCC, T. latifolia root tissue concentrations were significantly greater than shoot concentrations (TCS: 40.3 ± 11.3 vs. 17.2 ± 0.2, TCC: 26.0 ± 3.6 vs. 9.0, (MDL)). TCC concentrations in P. cordata roots were significantly greater than in shoots (34.4 ± 5.3 vs. 15.4 ± 2.8, respectively). TCS concentrations in T. latifolia roots and sediments and TCC concentrations in sediments generally decreased from wetland inflow to outflow. To our knowledge, this is the first study documenting species and tissue specific differences in the accumulation of TCS and TCC in plants from an operational constructed wetland. The species specific differences in bioaccumulation suggest TCS and TCC removal from constructed wetlands could be enhanced through targeted plantings.     

Repeatability of Phase 1 habitat survey

As the major part of a Habitat Survey of Wales, over 80% of the land surface was surveyed in the field between 1987 and 1997 using the Phase 1 method. A resurvey of 294 randomly selected points was carried out during the early stages to audit the quality of the data being collected, leading to the development of a set of recommendations for the surveyors to improve the consistency and accuracy of habitat mapping. Recent studies have indicated a high level of discrepancy between organisations in field habitat mapping using the Phase 1 method. The findings of the Phase 1 audit in Wales are presented here to show the level of repeatability that was achieved within an organisation. There was 76% correspondence in habitat mapping between 'surveyor' and 'assessor' at the level of individual Phase 1 habitat classes. The degree of repeatability varied according to habitat strata: it was highest for modified land cover types (88%), lowest for semi-improved types (56%) and intermediate for semi-natural types (75%). An overall estimate of the repeatability of Phase 1 survey in the study area of 83% was obtained by weighting the figures for the three strata by the proportion of land area occupied by each stratum. This figure increased to 85% when habitats were amalgamated into Broad Habitat groups. These results are considerably better than those reported by studies of consistency between organisations. Most of the discrepancies between surveyor and assessor were caused by differences in habitat identification. However, at almost two thirds of the points where such a difference occurred, the assessor noted that the vegetation was transitional or borderline with that mapped by the surveyor.     

Survey of PCDD/Fs and non-ortho PCBs in UK sewage sludges

A survey of PCDD/F and non-ortho PCB concentrations in the mesophilic, anaerobically digested sludge of 14 UK wastewater treatment works was carried out. The range of total Cl1-Cl8DD/F concentrations in the sludges was 8880-428000 pg/g dw with a median of 23300 pg/g dw. The concentrations of the three non-ortho PCBs were in the range 272-63000 pg/g dw with a median of 695 pg/g dw. The PCDD/F I-TEQs of the sludges studied were comparable to those published in the literature with a range of 20-225 pg I-TEQ/g dw and a median of 40.4 pg/g dw. The non-ortho PCBs usually added 2-7 pg/g to the total TEQ with one notable exception which increased the TEQ value 20-fold. With three exceptions, the PCDD/F content of the sludges fell well below the draft EU limit values proposed on 27 April 2000. The homologue group pattern of the PCDD/Fs is dominated by the HpCDDs and OCDD and is consistent with that found in most sewage sludges. There appears to be no correlation between the degree of industrial input and the PCDD/F concentration. This suggests that trade effluent is not always the most significant source of PCDD/Fs to wastewater in the UK.     

Element content in tissues of four rodent species sampled in the Geysers geothermal steamfield

Liver and kidney tissue samples from four rodent species collected in the Geysers geothermal steamfield of northern California were analyzed for content of 28 elements. Element concentrations in samples from the developed region of the Geysers were compared with samples from undeveloped reference regions to determine the influence of geothermal power development on element content in small mammal tissues. Eight elements (B, Ca, Cu, Mg, Mn, P, Sr, Ti) were enriched in samples from the Geysers, 12 (Ag, Al, Co, Cr, Fe, K, Mo, Na, Ni, Pb, Si, Zn) were decreased within the Geysers, Ba and Li were inconclusive, and six (As, Be, Cd, Hg, Sn, V) were below the minimum analytical limits. The longest-lived species (Neotoma fuscipes) had the greatest occurrence of statistically significant differences in element content. Sites in grassland habitat produced more significant differences in element content than either chaparral or streamside habitats for samples from Peromyscus maniculatus. Peromyscus boylii and P. truei provided additional data, but no distinct advantages for element monitoring. The data indicate regional influences from geothermal power development on element levels in rodent tissues.     

Environmental quality management in the united states in the 1980s and beyond: An appraisal

Summary This paper presents an overview of: (1) the institutional context of the environmental pollution sector of environmental quality management; (2) accomplishments and problems in some representative subsectors; and (3) prospects. The author describes levels of government within the US federal system and lists types of organizational structures, explains the division of responsibilities for managing environmental quality among legislative bodies/executive agencies, state and federal courts, and state public utility commission, and notes the significant role of nongovernmental environmental groups. In order to assess both the past performance and present status of environmental quality management in the United States, Bower cites some specific and generic problems in such subsectors as water quality, soil erosion, air quality, and hazardous wastes. He goes on to characterize recent approaches and their results using these observations as a basis for an appraisal of future prospects in the context of intermedia impacts and multiple modes of impact on various species. Remarks prepared for presentation at theColloque International, Les Politiques de l'Environnement Face à la Crise, Paris, 10–12 January, 1984. Blair T. Bower, a Registered Civil Engineer, is a Consultant in Residence at Resources For the Future in Washington, DC. He has worked extensively in the US and abroad on environmental quality management with such international organizations as the UN, WHO, OAS, and OECD. His current involvements include consultancies with the US National Oceans and Atmospheric Administration, Strategic Assessments Branch/Oceans Assessment Division; as Leader for Utilization of Coastal Water Problem Areas/Analyzing Biospheric Change Programme, International Federation of Institutes for Advances Study; and with the Office of Policy Analysis/US Environmental Protection Agency. An early supporter of integrated approaches to natural resource/environmental planning and management and to residuals disposal, Mr Bower is the author of many publications on a wide range of environmental topics and management options.     

Habitat inventory at a regional scale: a comparison of estimates of terrestrial Broad Habitat cover from stratified sample field survey and full census field survey for Wales, UK

Estimates of terrestrial Broad Habitat cover for Wales from the Countryside Survey 2000 stratified sample field mapping programme in Britain are compared with the findings of a full census field mapping project, the Habitat Survey of Wales. The Countryside Survey sampling regime comprised a stratified random sample of 1 km squares [corrected] covering <0.5% of the land surface. Comparative assessment indicates that although few of the sample-derived estimates for individual Broad Habitats are within 30% of the full census survey results, relative extents accord with data from the complete census survey for all Broad Habitats apart from Arable & Horticultural. The accuracy of this estimate is improved when the national boundary of Wales is taken into account in the sample stratification scheme. It is suggested that cultural land-use differences between countries render cropland habitat extent less predictable from physical environmental parameters than semi-natural habitat extent. It is also shown that the precision of sample-derived cover estimates is influenced by habitat pattern: the error term associated with habitats of broadly equal extent is greater for those with the most clumped distributions.