Adsorption of As(III) versus As(V) from aqueous solutions by cerium-loaded volcanic rocks

Environmental Science and Pollution Research - Contamination of drinking water with arsenic causes severe health problems in various world regions. Arsenic exists predominantly as As(III) and As(V)...     

Development of a distance-to-roadway proximity metric to compare near-road pollutant levels to a central site monitor

The primary objective of the Detroit Exposure and Aerosol Research Study (DEARS) was to compare air pollutant concentrations measured at various neighborhoods, or exposure monitoring areas (EMAs), throughout a major metropolitan area to levels measured at a central site or community monitor. One of the EMAs was located near a busy freeway (annual average daily traffic (AADT) of ～130,000) so that impacts of mobile sources could be examined. Air pollution concentrations from the roadway-proximate sites were compared to the central site monitor. The volatile organic compounds (VOCs) selected (benzene, toluene, ethylbenzene, m,p- and o-xylene, 1,3 butadiene, 1,3,5-trimethylbenzene and 4-ethyltoluene) are typically associated with mobile sources. Gradients were also evident that demonstrated the amplification of pollutant levels near the roadway compared to the community monitor. A novel distance-to-roadway proximity metric was developed to plot the measurements and model these gradients. Effective distance represents the actual distance an air parcel travels from the middle of a roadway to a site and varies as a function of wind direction, whereas perpendicular distance is a fixed distance oriented normal to the roadway. Perpendicular distance is often used as a proxy for exposures to traffic emissions in epidemiological studies.Elevated concentrations of all the compounds were found for both a summer and winter season. Effective distance was found to be a statistically significant (p < 0.05) univariate predictor for concentrations of toluene, ethylbenzene, m,p-xylene and o-xylene for summer 2005. For each of these pollutants, effective distance yielded lower p-values than the corresponding perpendicular distance models, and model fit improved. Results demonstrate that this near-road EMA had elevated levels of traffic-related VOCs compared to the community monitor, and that effective distance was a more accurate predictor of the degree to which they were elevated as a function of distance. Effective distance produced a range of distance-to-roadway values for a single site based on wind direction, thus increasing the number and range of values that could be used to plot and predict relative differences in pollutant concentrations between two sites.     

An assessment of hydraulic containment to control vertical DNAPL migration

Because of increased awareness and knowledge about their behavior, dense nonaqueous phase liquids (DNAPLs) are being detected at an increasing frequency at hazardous and solid waste land disposal units. Remedial systems at sites containing DNAPLs need to be designed to address the specific problems presented by DNAPLs. Because of their physical properties, DNAPLs migrate downward and are difficult to remove using conventional recovery methods. Groundwater pumping schemes can be designed to hydraulically contain this vertical migration. The purpose of this article is to present an approach for evaluating the potential to halt the vertical migration of DNAPLs using hydraulic control. Detailed groundwater flow modeling of a group of waste basins indicates that groundwater pumping in low-permeability sands can impose the upward hydraulic gradients required to stop downward DNAPL movement. However, a recovery well system located around the perimeter of the waste basins will not impose the required gradients over a sufficiently large area to effectively contain DNAPLs under the basins because the distribution of vertical gradients that could stop DNAPLs extends only about fifty to sixty feet from the wells. Additional modeling indicates that horizontal recovery wells located directly under the basins can contain the vertical migration of DNAPLs.     

Utility participation in a multispecies plan

Single-species listings under provisions of the federal Endangered Species Act (ESA) have caused, or have been accused of causing, significant regional economic impact. In an attempt to avoid such adverse effects on regional economic development, the state of California passed the Natural Communities Conservation Planning Act (NCCP) in 1991. It is a voluntary, consensus-based approach to balancing protection of sensitive biota and biodiversity with regional economic development. The pilot NCCP program for the conservation of several threatened, endangered, and category 1 species, plus an additional 35 coastal sage scrub-related species in southern California, was completed and submitted to the public for review and comment in December 1995. This program proposes the voluntary establishment of a 86,600-ha multispecies reserve system. Once completed, participating landowners will receive ESA Section 10(a) incidental take permits for present and identified future projects. Utility rights-of-way are incorporated into the program as important connective linkages between reserve units and other adjacent important habitat areas. All data and information regarding the proposed results of the NCCP are subject to change pending agency response to public comments on the draft Habitat Conservation Plan and joint EIR/EIS.     

Dissolved inorganic nitrogen budget for a forested catchment at Beddgelert, North Wales

An input-output budget for dissolved inorganic-N in a small forested catchment in North Wales is presented. From 1982 to 1990, bulk precipitation inputs averaged 10.3 kg ha(-1) year(-1), whereas throughfall inputs in 1983-1984 were 20.3 kg ha(-1) year(-1). Streamwater outputs were consistently larger than bulk precipitation inputs, averaging 14.6 kg ha(-1) year(-1). Inorganic-N in the forest stream was predominantly nitrate and concentrations were substantially higher than in a nearby moorland stream. Both streams showed seasonal trends in nitrate concentration, with highest concentrations occurring in summer in the forest stream but in winter in the moorland stream. Nitrate concentration in the forest stream increased with increasing soil temperature up to approximately 7 degrees C and decreased at higher temperatures. Nitrification is thought to be responsible for nitrate production at temperatures both below and above 7 degrees C, but root uptake becomes significant only at the higher temperatures. In the forest, dry deposition and cloudwater inputs of inorganic-N are responsible for increased nitrogen fluxes in throughfall compared with wet deposition. Mineralization and nitrification in excess of plant needs causes the organic soil horizons to act as a net source of dissolved inorganic-N. Nitrogen transformations in the soil lead to soil acidification at a rate of 1.0 keq ha(-1) year(-1).     

Survey of PCDD/Fs and non-ortho PCBs in UK sewage sludges

A survey of PCDD/F and non-ortho PCB concentrations in the mesophilic, anaerobically digested sludge of 14 UK wastewater treatment works was carried out. The range of total Cl1-Cl8DD/F concentrations in the sludges was 8880-428000 pg/g dw with a median of 23300 pg/g dw. The concentrations of the three non-ortho PCBs were in the range 272-63000 pg/g dw with a median of 695 pg/g dw. The PCDD/F I-TEQs of the sludges studied were comparable to those published in the literature with a range of 20-225 pg I-TEQ/g dw and a median of 40.4 pg/g dw. The non-ortho PCBs usually added 2-7 pg/g to the total TEQ with one notable exception which increased the TEQ value 20-fold. With three exceptions, the PCDD/F content of the sludges fell well below the draft EU limit values proposed on 27 April 2000. The homologue group pattern of the PCDD/Fs is dominated by the HpCDDs and OCDD and is consistent with that found in most sewage sludges. There appears to be no correlation between the degree of industrial input and the PCDD/F concentration. This suggests that trade effluent is not always the most significant source of PCDD/Fs to wastewater in the UK.     

Element content in tissues of four rodent species sampled in the Geysers geothermal steamfield

Liver and kidney tissue samples from four rodent species collected in the Geysers geothermal steamfield of northern California were analyzed for content of 28 elements. Element concentrations in samples from the developed region of the Geysers were compared with samples from undeveloped reference regions to determine the influence of geothermal power development on element content in small mammal tissues. Eight elements (B, Ca, Cu, Mg, Mn, P, Sr, Ti) were enriched in samples from the Geysers, 12 (Ag, Al, Co, Cr, Fe, K, Mo, Na, Ni, Pb, Si, Zn) were decreased within the Geysers, Ba and Li were inconclusive, and six (As, Be, Cd, Hg, Sn, V) were below the minimum analytical limits. The longest-lived species (Neotoma fuscipes) had the greatest occurrence of statistically significant differences in element content. Sites in grassland habitat produced more significant differences in element content than either chaparral or streamside habitats for samples from Peromyscus maniculatus. Peromyscus boylii and P. truei provided additional data, but no distinct advantages for element monitoring. The data indicate regional influences from geothermal power development on element levels in rodent tissues.