新吹填软土地基复式负压固结技术开发

新吹填土含泥量大、含水率大、渗透性差、零承载力,常规地基处理工法无法开展,地基处理面临诸多困难。针对该问题,提出了复式负压固结技术,该技术包括3道工序:改性真空预压、电渗降水和强夯动力固结。改性真空预压使地基得到初步固结,具备一定强度,为后序工作做准备;电渗降水可有效降低夯前地下水位和土体含水率,并促进夯后超孔隙水压力的消散;电渗降水和强夯动力固结多遍耦合,共同对吹填土进行地基加固。现场开展了复式负压固结技术工艺试验、土性试验和沉降变形监测。结果表明,应用于吹填泥的地基处理,改性真空预压可快速提高承载力,电渗法可迅速降低地下水位,有效避免强夯时"弹簧土"现象的发生,从而提高了最佳夯击能。复式负压固结技术可以有效地应用于新吹填软土地基。     

混凝土轴压方柱满足目标抗火可靠指标的建议截面

对混凝土轴压柱抗火计算所用荷载比与其常温设计荷载比的换算关系进行了推导和分析,分别针对耐火等级一级和二级情况下的柱耐火极限要求,给出了四面受火轴压方柱满足目标抗火可靠指标的最小截面取值。研究表明:①常温设计荷载比大致为抗火计算所用荷载比的2～5倍,一般混凝土柱可近似取2.5倍;②荷载比小于0.2时,现行规范给出的300mm×300mm截面柱,在抗火可靠指标不小于目标抗火可靠指标的情况下可以满足二级耐火要求;③荷载比和耐火等级是影响轴压柱最小截面取值的主要因素。     

Ca2+对上流式多级厌氧反应器处理蔗渣渗滤液的影响

研究了上流式多级厌氧反应器(UMAR)处理蔗渣渗滤液过程中Ca2+浓度对反应器运行特性和颗粒污泥性质的影响。结果表明,对于蔗渣渗滤液而言,进水中低浓度的Ca2+浓度(80～300 mg/L)对颗粒污泥产甲烷活性无抑制,COD去除率最高可达93.3%;Ca2+浓度达到500 mg/L以上时,对厌氧颗粒污泥的活性有抑制作用;随着Ca2+浓度进一步升高,抑制作用加强,污泥灰分明显升高,活性成分下降,COD去除效率明显降低,污泥粘结沉积在反应器底部,导致系统内循环出现障碍。因此,在实际生产中应减少废水中Ca2+的引入量。     

江苏沿海地区经济联系及物流要素流量空间特征分析

随着经济一体化的发展,城市间经济联系日益加强,必然引起城市间物流需求联系的增加。借鉴引力模型在经济联系中的应用,分析了江苏沿海地区城市间经济联系强度。结果表明：城市间经济联系的强度随着空间距离的递增而递减;并以区域中心城市为中心,向外呈辐射状圈层构造,呈现3个层次结构;沿海中心城市对经济联系腹地间的竞争更加明显。立足运输地理学网络分析基本原理, 从客流、货流和信息流等流量,流向等空间属性进一步探讨城市间的经济联系特征,江苏沿海地区市际间货流量连云港 南通占主要地位;客流量连云港 南通一线最大;城市间信息传递不畅,信息流量较弱。针对城市间经济联系及物流要素流量的空间特征,提出了加强区域经济合作的策略与建议     

中国火灾的时空演变特征——基于GIS的统计分析

研究对象为2000-2009年中国341个地级以上城市(不含台湾及港澳地区)的火灾统计数据。首先应用主成分分析法,计算火灾综合损失(fire composite losts,FCL);再对FCL进行分级,将所有研究单元按FCL从小到大分为5个级别,较高FCL单元主要分布于黑河—腾冲线以东地区。对每个研究单元分别进行时间序列分析,观察其FCL变化趋势,将各区域分为平稳区、改善区、恶化区和波动区,其分别占比41%,40%,8%和11%,表明绝大多数城市FCL呈平稳或下降趋势。恶化区明显地沿黑河—腾冲线、淮河—大别山—雪峰山沿线和东南沿海分布,这可能与气候变化或社会经济发展有关。     

水位变动下三峡库区消落带植物群落特征

水位变动是湿地的基本特征之一,对湿地生态系统意义重大。为了解水位变动对三峡库区消落带植物群落的影响,于2010年8月对白夹溪消落带植物群落进行调查,采用TWINSPAN分类法对植物群落进行分类。结果表明:共发现维管植物85种,隶属34科70属;植物群落可划分为18个类型,狗牙根等5种群落为白夹溪消落带代表性植物群落;随着淹水程度的加深,群落组成呈现出由旱生植物到湿生植物的过渡趋势;植物群落香农指数、均匀度指数、丰富度指数和生物量指数随水位梯度呈“∧”型变化趋势,辛普森指数呈“∨”型变化趋势。与156 m蓄水周期相比,植物物种数量、群落类型及组成、多样性均发生改变。水位变动是消落带新生湿地植物群落变化的主要驱动因子     

Mercury speciation and mobility in mine wastes from mercury mines in China

Mercury (Hg) speciation and mobility were determined in calcines and waste rocks collected from 9 Hg mines in China. Total Hg (THg) concentrations in the mine wastes varied widely in different Hg mines (with a range of 0.369 to 2,620 mg kg^?1). Cinnabar is the dominant form of Hg in the mine wastes. However, Hg²⁺ and Hg⁰ concentrations in the calcines were significantly higher than these in the waste rocks, which suggested the retorting can produce large amounts of by-product Hg compounds. The THg and Hg⁰ concentrations in certain mine wastes exceeded soil guidelines recommended by US Environmental Protection Agency; while total soluble Hg concentrations of leachates in certain mine wastes exceeded National Surface Water Quality Standard of China. Mine wastes are important Hg pollution sources to the aquatic ecosystem and atmosphere.     

Determinants of maternal and fetal exposure and temporal trends of perfluorinated compounds

In recent years, some perfluorinated compounds (PFCs) have been identified as potentially hazardous substances which are harmful to the environment and human health. According to limited data, PFC levels in humans could be influenced by several determinants. However, the findings are inconsistent. In the present study, perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), and perfluorononanoic acid (PFNA) were measured in paired maternal and cord serum samples (N?=?237) collected between 1978 and 2001 in Southern Sweden to study the relationship between these and to investigate several potential determinants of maternal and fetal exposure to PFCs. Time trends of PFCs in Swedish women were also evaluated. The study is a part of the Fetal Environment and Neurodevelopment Disorders in Epidemiological Research project. PFOS, PFOA, and PFNA levels (median) were higher in maternal serum (15, 2.1, and 0.24 ng/ml, respectively) than in cord serum (6.5, 1.7, and 0.20 ng/ml, respectively). PFC levels were among the highest in women originating from the Nordic countries and the lowest in women from the Middle East, North Africa, and sub-Saharan Africa. Multiparous women had lower serum PFOA levels (1.7 ng/ml) than primiparous women (2.4 ng/ml). Maternal age, body mass index, cotinine levels, and whether women carried male or female fetuses did not affect serum PFC concentrations. Umbilical cord serum PFC concentrations showed roughly similar patterns as the maternal except for the gestational age where PFC levels increased with advancing gestational age. PFOS levels increased during the study period in native Swedish women. In summary, PFOS levels tend to increase while PFOA and PFNA levels were unchanged between 1978 and 2001 in our study population. Our results demonstrate that maternal country of origin, parity, and gestational age might be associated with PFC exposure.     

炭化柚子皮对废水中双酚A的吸附

采用磷酸二氢钾活化原材料柚子皮,分别在300℃和600℃对活化后柚子皮进行炭化,制得吸附剂（CC300和CC600）,通过静态吸附实验研究了炭化柚子皮对双酚A的吸附性能。采用比表面积分析仪对炭化柚子皮进行表征,实验考察了pH值、吸附时间和温度对双酚A吸附的影响,并详细研究了炭化柚子皮对双酚A的吸附行为和机理。结果表明,高温炭化柚子皮（CC600）吸附双酚A能力比低温炭化（CC300）的强,其吸附较好地满足Langmuir和Freundlich等温方程;动力学研究表明,其吸附速率快,在150min内能达到吸附平衡,准二级动力学模型较好地描述该吸附行为,相关系数高达0．99：计算了热力学参数△G、△H和△S的值,△G为负值,说明该吸附过程为自发过程。     

Tracer-based source apportionment of polycyclic aromatic hydrocarbons in PM2.5 in Guangzhou, southern China, using positive matrix factorization (PMF)

From 28 November to 23 December 2009, 24-h?PM_2.5 samples were collected simultaneously at six sites in Guangzhou. Concentrations of 18 polycyclic aromatic hydrocarbons (PAHs) together with certain molecular tracers for vehicular emissions (i.e., hopanes and elemental carbon), coal combustion (i.e., picene), and biomass burning (i.e., levoglucosan) were determined. Positive matrix factorization (PMF) receptor model combined with tracer data was applied to explore the source contributions to PAHs. Three sources were identified by both inspecting the dominant tracer(s) in each factor and comparing source profiles derived from PMF with determined profiles in Guangzhou or in the Pearl River Delta region. The three sources identified were vehicular emissions (VE), biomass burning (BB), and coal combustion (CC), accounting for 11?±?2 %, 31?±?4 %, and 58?±?4 % of the total PAHs, respectively. CC replaced VE to become the most important source of PAHs in Guangzhou, reflecting the effective control of VE in recent years. The three sources had different contributions to PAHs with different ring sizes, with higher BB contributions (75?±?3 %) to four-ring PAHs such as pyrene and higher CC contributions (57?±?4 %) to six-ring PAHs such as benzo[ghi]perylene. Temporal variations of VE and CC contributions were probably caused by the change of weather conditions, while temporal variations of BB contributions were additionally influenced by the fluctuation of BB emissions. Source contributions also showed some spatial variations, probably due to the source emission variations near the sampling sites.