Nanotechnology innovations,industrial applications and patents

Nanotechnology can be defined as the use of nanomaterials for human benefit. Nanomaterials have unique properties due to their physical and chemical characteristics at the nanoscale (10^?9 nm). Nowadays, nanotechnology is providing new products in all industrial sectors. This article reviews innovations in fields such as biomedical, diagnosis of diseases, therapeutics, agriculture and food, nanofertilizers, oil, gas, textile and cosmeceuticals and packaging. Recent trends of patents and scholarly publications in nanotechnology are also discussed.     

Effective application of ethanol in diesel engines

This work aimed to prove the effects of adding different proportions of ethanol with diesel (DE) and ethanol–water mixture with diesel (DEW) in a single-cylinder diesel engine on the performance, emissions, and combustion parameters. The blends were stabilized by tetra methyl ammonium bromide (TMAB) as the additive. The study was conducted at two operating conditions initially on a normal diesel engine and in the second case the engine piston, valves, and cylinder head coated with zirconia (ZrO₂) alumina (Al₂O₃). The results showed that the addition of 10% ethanol with diesel performed almost equivalent to neat diesel with 29.2% BTE and a 17.7% decrease in smoke and an 11.4% increase in NOx emission at peak load compared to that of the base fuel. Modified engines with thermal barrier coating (TBC) performed superior to normal engines with 4% and 5.5% increase in BTE, respectively, for DE- and DEW-type fuels with reduced exhaust emissions. A 5% addition of water with diesel–ethanol blends favors a higher proportion of ethanol to be employed in diesel engines.     

Seagrass metabolism and carbon dynamics in a tropical coastal embayment

Net ecosystem metabolism and subsequent changes in environmental variables were studied seasonally in the seagrass-dominated Palk Bay, located along the southeast coast of India. The results showed that although the water column was typically net heterotrophic, the ecosystem as a whole displayed autotrophic characteristics. The mean net community production from the seagrass meadows was 99.31 ± 45.13 mM C m^?2 d^?1, while the P/R ratio varied between 1.49 and 1.56. Oxygen produced through in situ photosynthesis, exhibited higher dependence over dissolved CO₂ and available light. Apportionment of carbon stores in biomass indicated that nearly three-fourths were available belowground compared to aboveground. However, the sediment horizon accumulated nearly 40 times more carbon than live biomass. The carbon storage capacities of the sediments and seagrass biomass were comparable with the global mean for seagrass meadows. The results of this study highlight the major role of seagrass meadows in modification of seawater chemistry. Though the seagrass meadows of Palk Bay are increasingly subject to human impacts, with coupled regulatory and management efforts focused on improved water quality and habitat conservation, these key coastal ecosystems will continue to be valuable for climate change mitigation, considering their vital role in C dynamics and interactions with the overlying water column.     

Oxidative and cellular stress as bioindicators for metal contamination in freshwater mollusk Lamellidens marginalis

Environmental Science and Pollution Research - The concentrations of 14 metals, namely, chromium (Cr), manganese (Mn), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), selenium (Se), arsenic (As),...     

Influence of land use and land cover on the spatial variability of dissolved organic matter in multiple aquatic environments

Environmental Science and Pollution Research - Water quality of lakes, estuaries, and coastal areas serves as an indicator of the overall health of aquatic ecosystems as well as the health of the...     

Exploring Persistence in Streamflow Forecasting

In this study, the authors explore three persistence approaches in streamflow forecasting motivated by the need for forecasting model skill evaluation. The authors use streamflow observations with 15 min resolution from the year 2008 to 2017 at 140 United States Geological Survey streamflow gauges monitoring the streams and rivers over the State of Iowa. The spatial scale of the basins ranges from about 7 to 37,000 km². The study explores three approaches: simple persistence, gradient persistence, and anomaly persistence. The study shows that persistence forecasts skill has strong dependence on basin scales and weaker but non‐negligible dependence on geometric properties of the river network for a given basin. Among the three approaches explored, anomaly persistence shows highest skill especially for small basins, under about 500 km². The anomaly persistence can serve as a benchmark for model evaluations considering the effect of basin scales and geometric properties of river network of the basin. This study further reiterates that persistence forecasts are hard‐to‐beat methods for larger basin scales at short to medium forecast range.     

Electricity nanogenerator from egg shell membrane: A natural waste bioproduct

ABSTRACT

In the era of developing technologies, there is always been a crisis of rising demands of energy. There is no skepticism that a lot of energy is being produced every hour for almost each and every field, but still an exploration is needed to come up with new and viable options for energy creation. The same is the objective of this paper which proposes the use of waste biomaterials in association with organic and inorganic materials as a source of energy to power up small electronic devices. In this research egg shell membrane (ESM)-based triboelectric nanogenerator (TENG) is proposed in combination with calotropis (Calo), cellulose from fruit of Bombax Ceiba (BOM), cellulose in form of tissue paper (TISU), dog hair (DH), polytetrafluoroethylene (PTFE), aluminum (Al), and copper (Cu). ESM is eco-friendly waste food by-product and available in abundance. Characterization of ESM is done by scanning electron microscope (SEM), atomic force microscope (AFM), X-ray diffraction (XRD), and Fourier transform infrared spectrophotometer (FTIR). The proposed ESM-PTFE-based TENG power up 462 green LEDs (462 × 2 V = 924 V ~ 1 kV) without rectifier and produced up to 7.61 µJ energy with 4.7 µF capacitor at 200 tapings. All the proposed ESM-based TENG combinations generate sufficient voltage to turn ON the wrist watch. This green-energy-based TENG has potential application in various fields especially related to medical devices.     

Photo-/Bio-degradability of Agro Waste and Ethylene–Propylene Copolymers Composites Under Abiotic and Biotic Environments

Composites were prepared by two methods, (i) graft copolymerization (GFC) of isotactic polypropylene (PP) with maliec anhydride, (MAH) followed by esterification with coir fiber and (ii) by direct reactive mixing (DFC) of polypropylene (PP) and ethylene–propylene (EP) copolymers with MAH and peroxide with coir fiber. These composites, after molding in films (5×5 cm, m thickness) were examined for susceptibility to biological attack by measuring the percentage weight loss in compost upto 6 months, periodically, and fungal colonization on surface of the samples, when kept as sole carbon source for the growth of Aspergillus niger in culture medium upto 40 days. Photodegradation was evaluated by monitoring the variations in FT-IR spectrum and crack formation after successive treatment with UV light (≥290 nm) for 0, 20, 50 and 100 h at 60°C in the presence of air. Specimens of virgin PP were taken as a reference during all period of photo and biodegradation studies. Significant changes were observed depending on the preparation methods during photodegradation and biodisintegration of composites. DFCs samples were disintegrated faster than GFCs during the composting whereas, in culture, GFCs were covered highly in well uniform way by fungi. It was observed that photo-oxidative ageing directly enhanced the biodegradability of composites as the increase in fungal growth rate and decrease in weight during composting were found. It was concluded that extent of compatibilization had a profound effect on photo-oxidation and biodisintegration of composite material; consequently ester bonds were main units during fungal consumption. Composition of monomers in copolymers was also showing significant effect on the degradability which decreased with increasing content of ethylene in ethylene–propylene (EP) copolymers.     

Differential sorption of herbicides as related to soil topography and organic matter 1

Abstract

The sorption of bromacil and simazine by the surface soil (0–15 cm) sampled at various positions along an 8% slope citrus grove (Candler fine sand; Typic Quartzipsamment) and at various depths (0–200 cm) at upper, middle, and lower positions along the slope were investigated. The sorption of both herbicides by the top 15 cm soil decreased considerably from the upper to mid position along the slope and increased at the lower position. The organic matter content and concentrations of Ca, Mg, K, P, and Cu in the soil showed evidence of transport of organic matter and mineral nutrients from the mid position on the slope and accumulation in the lower position. The differential sorption of herbicides by the soil samples taken at various positions along the slope was closely related to changes in organic matter content. Although sorption of bromacil and simazine varied considerably at various positions along the slope, the sorption of bromacil was very similar at depths below 30 cm regardless of positions along the slope. In the case of simazine, however, the sorption was much greater at all depths in the lower than in the upper and mid position of the slope. The sorption of both herbicides decreased considerably at depths below 30 cm at all positions along the slope, thus, indicating the potential for rapid leaching of the herbicides down the soil profile.     

Land application of biomass residue generated from palm oil processing: its potential benefits and threats

Man’s increased demand for food and better living conditions has led to over exploitation of resources and the consequent generation of enormous amounts of liquid and solid waste materials. This is one of the global challenges for mankind. In Malaysia, palm oil mill waste (POMW) contributes the highest proportion of industrial solid wastes produced yearly. Wastes from the mills include palm oil mill effluent, decanter cake, empty fruit bunches, seed shells and the fibre from the mesocarp. Direct application of POMW into agricultural soil has resulted in a number of problems such as water pollution, leaching. However, with application rates specific for targeted plant species, land application can be employed as a permanent solution to the problem of waste from palm oil mills. This review examines the characteristics of each of the palm oil wastes and their potential for use as a future fertilizer supplement.