Recovery of benthic invertebrate communities from acidification in Killarney Park lakes

Using a reference-condition comparison, recovery of benthic invertebrate communities from acidification was assessed in three lakes in Killarney Wilderness Park approximately 40–60 km from the massive metal smelters in Sudbury, Canada. Test site analyses (TSAs) were used to compare the park lakes to 20 reference lakes near Dorset Ontario, 200 km to the east. An extension of a previous survey (1997–2001) of two sensitive mayfly species (Stenonema femoratum and Stenacron interpunctatum) was conducted in one of the lakes. TSA results indicate that the three Killarney lakes remain significantly different from reference condition due primarily to higher abundances of a few acid-tolerant families and the presence of some less abundant sensitive families. Colonization rates differ greatly between the two mayfly species presumably because of competition for available habitat. Overall, this study suggests that early colonizers will gain an advantage to out-compete subsequent arrivals, and these competitive interactions will delay the return of communities to reference condition.     

Release of silver nanoparticles from outdoor facades

In this study we investigate the release of metallic silver nanoparticles (Ag-NP) from paints used for outdoor applications. A facade panel mounted on a model house was exposed to ambient weather conditions over a period of one year. The runoff volume of individual rain events was determined and the silver and titanium concentrations of 36 out of 65 runoff events were measured. Selected samples were prepared for electron microscopic analysis. A strong leaching of the Ag-NP was observed during the initial runoff events with a maximum concentration of 145 μ Ag/l. After a period of one year, more than 30% of the Ag-NP were released to the environment. Particles were mostly <15 nm and are released as composite colloids attached to the organic binders of the paint. Microscopic results indicate that the Ag-NP are likely transformed to considerably less toxic forms such as Ag₂S.     

Ubiquitination and carbonylation of proteins in the clam Ruditapes decussatus, exposed to nonylphenol using redox proteomics

Ubiquitination and carbonylation of proteins were investigated in the gill and digestive gland of Ruditapes decussatus exposed to NP (nonylphenol) (100 μgL(-1)) using redox proteomics. After 21 d of exposure, clams were dissected and cytosolic proteins of both tissues separated by 2DE SDS-PAGE. Protein expression profiles were tissue-dependent and differently affected by NP exposure. Ubiquitination and carbonylation were also tissue-specific. NP exposure induced significantly more ubiquitinated proteins in gills than in digestive glands, compared to controls. Digestive gland showed a significant higher number of carbonylated proteins than gills after NP exposure. Protein ubiquitination and carbonylation are therefore independent processes. Results showed that NP exposure generated ROS in gill and digestive gland of R. decussatus that significantly altered the proteome. Results also highlighted the advantage of using redox proteomics in the assessment of protein ubiquitination and carbonylation, which may be markers of oxidative stress in R. decussatus.     

Alkyl nitrate photochemistry during the tropospheric organic chemistry experiment

Alkyl nitrates (C₁–C₅) were measured at two sites (near urban and rural) in southeast England during the Tropospheric Organic Chemistry Experiment (TORCH). Methyl nitrate was the dominant species during both campaigns accounting for on average about one third of the total measured alkyl nitrates. High mixing ratios (>50 pptv) and variability of methyl nitrate were observed at the near urban site (TORCH1) that were not seen at the rural site (TORCH2) and which could not be explained by local photochemical production or direct emissions. The diurnal variation of methyl nitrate during TORCH1 showed a morning maximum that would be consistent with nighttime chemistry followed by transport to the surface by boundary layer dynamics. Similarly, elevated morning mixing ratios were also observed during TORCH2 although the magnitudes were much smaller. As a result, methyl nitrate could represent a tracer for nighttime chemistry seen at the ground the following day. At both campaigns, the dominant source of short chain alkyl nitrates and carbonyl precursor radicals (≤C₄) were from decomposition of larger compounds. The magnitude of the source increased with decreasing carbon number consistent with increasing total precursor abundance. Non-photochemical emissions of acetaldehyde and acetone could not be accounted for by automobile exhaust emissions alone and indicated that other direct sources are likely important in this environment.     

Environmental forensics: an emerging discipline within UK higher education?

Environmental forensics is an established discipline in North America, but has yet to make an impact within Europe and more specifically within the UK. In this paper we explore the reasons for this and explore the nature and fundamental philosophy that underlies this discipline. Case studies can be used to explore the complexity that can be associated with an environmental forensic investigation and we argue that there is a demand for professionals with skills in forensic practice within the environmental sector today. The paper finishes by suggesting that environmental forensics is a discipline of its moment within Europe for which the Higher Education sector must now cater.     

An improved dual channel PERCA instrument for atmospheric measurements of peroxy radicals

This paper describes a new dual-channel PEroxy RadiCal Amplification (PERCA) instrument, which has been designed to improve the time resolution and signal to noise and to reduce the interference caused by variations in ambient ozone concentrations. The instrument was run at the Weybourne Atmospheric Observatory (WAO), North Norfolk, during WAOWEX (Weybourne Atmospheric Observatory Winter Experiment) in January/February 2002 and INSPECTRO (Influence of clouds on the spectral actinic flux in the lower troposphere) in September 2002. The performance of the instrument is assessed and compared to that of a single channel instrument. In particular, it is shown how the precision is greatly improved in fluctuating background ozone conditions. In addition the improved time response of the instrument allows changes in peroxy radical concentrations to be related to rapid changes in nitric oxide concentrations and the ozone photolysis frequency, j(O(1)D).     

Riparian buffer strips as a multifunctional management tool in agricultural landscapes: introduction

Catchment riparian areas are considered key zones to target mitigation measures aimed at interrupting the movement of diffuse substances from agricultural land to surface waters. Hence, unfertilized buffer strips have become a widely studied and implemented "edge of field" mitigation measure assumed to provide an effective physical barrier against nitrogen (N), phosphorus (P), and sediment transfer. To ease the legislative process, these buffers are often narrow mandatory strips along streams and rivers, across different riparian soil water conditions, between bordering land uses of differing pollution burdens, and without prescribed buffer management. It would be easy to criticize such regulation for not providing the opportunity for riparian ecosystems to maximize their provision for a wider range of ecosystem goods and services. The scientific basis for judging the best course of action in designing and placing buffers to enhance their multifunctionality has slowly increased over the last five years. This collection of papers aims to add to this body of knowledge by giving examples of studies related to riparian buffer management and assessment throughout Europe. This introductory paper summarizes discussion sessions and 13 selected papers from a workshop held in Ballater, UK, highlighting research on riparian buffers brought together under the EU COST Action 869 knowledge exchange program. The themes addressed are (i) evidence of catchment- to national-scale effectiveness, (ii) ecological functioning linking terrestrial and aquatic habitats, (iii) modeling tools for assessment of effectiveness and costs, and (iv) process understanding enabling management and manipulation to enhance pollutant retention in buffers. The combined understanding led us to consider four principle key questions to challenge buffer strip research and policy.     

Periphyton Nutrient Limitation and Maximum Potential Productivity in the Beaver Lake Basin,United States1

Ludwig, Andrea, Marty Matlock, Brian Haggard, and Indrajeet Chaubey, 2012. Periphyton Nutrient Limitation and Maximum Potential Productivity in the Beaver Lake Basin, United States. Journal of the American Water Resources Association (JAWRA) 48(5): 896‐908. DOI: 10.1111/j.1752‐1688.2012.00657.x Abstract: The objectives of this study were to measure periphytic growth responses to enrichment with nitrogen (N), phosphorus (P), and simultaneous N and P using in situ bioassays in streams draining Beaver Reservoir Basin, Northwest Arkansas; compare periphytic growth responses measured with in situ bioassays with a range of land use and point sources; and test the lotic ecosystem trophic status index (LETSI) as a simplifying metric to compare effects of nonpoint‐source pollutant‐limiting variables of N, P, and sediment across the basin. P limitation was observed at sites across a transect of stream orders throughout the basin; however, at the two sites with highest ambient nitrogen concentrations, limitation was often coupled with nitrogen limitation. Nutrients were at nonlimiting levels at both of two sites below wastewater treatment plants in all seasonal deployments. A Michaelis‐Menten growth equation described LETSI as a function of ambient PO₄‐P concentrations (p < 0.05); the midpoint (LETSI of 0.50) corresponded with a PO₄‐P concentration of approximately 3 μg/l. Change‐point analysis indicated a threshold point at LETSI of 0.80 and 15 μg/l PO₄‐P. These low values show that the periphytic community has a high affinity for available P, and that the watershed as a whole is sensitive to available nutrient inputs.     

Streamflow Changes in the South Atlantic,United States During the Mid‐ and Late 20th Century1

Abstract: Repeated severe droughts over the last decade in the South Atlantic have raised concern that streamflow may be systematically decreasing, possibly due to climate variability. We examined the monthly and annual trends of streamflow, precipitation, and temperature in the South Atlantic for the time periods: 1934‐2005, 1934‐1969, and 1970‐2005. Streamflow and climate (temperature and precipitation) trends transitioned ca. 1970. From 1934 to 1969, streamflow and precipitation increased in southern regions and decreased in northern regions; temperature decreased throughout the South Atlantic. From 1970 to 2005, streamflow decreased, precipitation decreased, and temperature increased throughout the South Atlantic. It is unclear whether these will be continuing trends or simply part of a long‐term climatic oscillation. Whether these streamflow trends have been driven by climatic or anthropogenic changes, water resources management faces challenging prospects to adapt to decadal‐scale persistently wet and dry hydrologic conditions.     

Channel Evolution Model of Semiarid Stream Response to Urban‐Induced Hydromodification1

Hawley, Robert J., Brian P. Bledsoe, Eric D. Stein, and Brian E. Haines, 2012. Channel Evolution Model of Semiarid Stream Response to Urban‐Induced Hydromodification. Journal of the American Water Resources Association (JAWRA) 48(4): 722‐744. DOI: 10.1111/j.1752‐1688.2012.00645.x Abstract: We present a novel channel evolution model (CEM) that qualitatively describes morphologic responses of semiarid channels to altered hydrologic and sediment regimes associated with urbanization (hydromodification). The CEM is based on southern California data from 83 detailed channel surveys, hundreds of synoptic surveys, and historical analyses of aerial photographs along 14 reaches. Channel evolution sometimes follows the well‐known sequence described by Schumm et al. (Incised Channels: Morphology, Dynamics, and Control, Water Resources Publications, Littleton, Colorado, 1984) for incising, single‐thread channels; however, departures from this sequence are common and include transitions of single thread to braided evolutionary endpoints, as opposed to a return to quasi‐equilibrium single‐thread planform. Thresholds and risk factors associated with observed channel response are also presented. In particular, distance to grade control and network position emerged as key controls on channel response trajectory. The CEM and quantitative extensions provide managers with a framework for understanding channel responses and rehabilitation alternatives, and may be transferable to other semiarid settings. It also offers insights regarding channel susceptibility to hydromodification, highlights key boundary conditions for high‐risk channels, and underscores critical knowledge gaps in predicting the complex, discontinuous response trajectories that are highly prevalent in urbanized watersheds.