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61.
This work presents an unconventional procedure for the recovery of spent Al-rich caustic soda solutions from the pickling of dies for the production of aluminium extrusions. Caustic soda was regenerated at roughly 70%, by precipitating aluminate, after addition of a silica source, in the form of zeolite A, a microporous material that is widely used in many technological sectors. It was shown that the process is reliable and can be repeated for several cycles, provided the concentration of the caustic soda solution is suitably restored. The by-product obtained, zeolite A, proved to be a high-grade material with performance as a cation exchanger and physical sorbent that is certainly comparable to that reported in literature (e.g., cation exchange capacity equal to 5.14 meq g(-1) vs. 5.48 meq g(-1) and water vapour adsorption capacity of 26.5% vs. 27.6% at 16 torr and 298 K). The economics of the process, although not examined yet, would appear generally favourable, considering that zeolite A is a valuable by-product which widely covers the costs for the recovery of the spent solutions. There are, therefore, significant prospects for the use of zeolite A, particularly as a builder in detergent formulation. 相似文献
62.
Pienkoß Fabian Abis Marco Bruno Martina Grönholm Raul Hoppe Michel Kuchta Kerstin Fiore Silvia Simon Franz-Georg 《Journal of Material Cycles and Waste Management》2022,24(1):364-377
Journal of Material Cycles and Waste Management - This work is aimed at exploring the recovery of heavy metals from the fine fraction of solid waste incineration bottom ash. For this study,... 相似文献
63.
Soares Jéssica Maria Alexandre da Silva Júnior Elenildo Dário Oliveira de Veras Bruno Yara Ricardo de Albuquerque Priscilla Barbosa Sales de Souza Marthyna Pessoa 《Journal of Polymers and the Environment》2022,30(1):217-231
Journal of Polymers and the Environment - Bioactive biodegradable films are emerging biomaterials in the food packaging field. This study aims to investigate the effect of different Cenostigma... 相似文献
64.
Battisti Sabrina Scaramozzino Paola Boselli Carlo Busico Fabio Berretta Sesto Sala Marcello Neri Bruno 《Environmental science and pollution research international》2022,29(46):69424-69438
Environmental Science and Pollution Research - This study reports the data of polychlorinated dibenzo-p-dioxins (PCDDs), -furans (PCDFs), and polychlorinated biphenyls dioxin-like (dl PCBs)... 相似文献
65.
Heiko Schmaljohann Felix Liechti Bruno Bruderer 《Behavioral ecology and sociobiology》2009,63(11):1609-1619
Meteorological conditions influence strongly the energy and water budget of birds. By adjusting their flights spatially and
temporally with respect to these conditions, birds can reduce their energy expenditure and water loss considerably. By radar,
we quantified songbird migration across the western Sahara in spring and autumn. There autumn migrants face the trade-off
between (a) favorable winds combined with hot and dry air at low altitudes and (b) unfavorable winds combined with humid and
cold air higher up. Thus, it can be tested whether birds may chose altitudes to minimize water loss instead of energy expenditure.
We predicted optimal flight altitudes with respect to water loss and energy expenditure based on a physiological flight model
when crossing the western Sahara and compared these model predictions spatially and temporally with measured songbird densities.
The model aiming for minimal water consumption predicted a mean flight altitude of 3,400 m under autumn conditions. However,
64% of the nocturnal songbird migration flew at altitudes below 1,000 m above ground level profiting from tailwind. This preference
for tailwind in autumn, despite the hot and dry air, emphasizes the importance of energy savings and diminishes the significance
of possible water stress for the selection of flight altitude. Nevertheless, during daytime, high energy expenditure due to
air turbulences and water loss due to warmer air and direct solar radiation prevent songbirds from prolonging their nocturnal
flights regularly into the day. Birds crossing the Sahara save water by nocturnal flights and diurnal rests. 相似文献
66.
67.
Improvements on Flood Alleviation in Germany: Lessons Learned from the Elbe Flood in August 2002 总被引:1,自引:0,他引:1
The increase in damage due to natural disasters is directly related to the number of people who live and work in hazardous
areas and continuously accumulate assets. Therefore, land use planning authorities have to manage effectively the establishment
and development of settlements in flood-prone areas in order to avoid the further increase of vulnerable assets. Germany faced
major destruction during the flood in August 2002 in the Elbe and Danube catchments, and many changes have been suggested
in the existing German water and planning regulations. This article presents some findings of a “Lessons Learned” study that
was carried out in the aftermath of the flood and discusses the following topics: 1) the establishment of comprehensive hazard
maps and flood protection concepts, 2) the harmonization of regulations of flood protection at the federal level, 3) the communication
of the flood hazard and awareness strategies, and 4) how damage potential can be minimized through measures of area precaution
such as resettlement and risk-adapted land use. Although attempts towards a coordinated and harmonized creation of flood hazard
maps and concepts have been made, there is still no uniform strategy at all planning levels and for all states (Lae
nder) of the Federal Republic of Germany. The development and communication of possible mitigation strategies for “unthinkable
extreme events” beyond the common safety level of a 100-year flood are needed. In order to establish a sustainable and integrated
flood risk management, interdisciplinary and catchment-based approaches are needed. 相似文献
68.
Karimoun M. Illyassou Rabani Adamou Bruno Schiffers 《Journal of environmental science and health. Part. B》2019,54(3):176-186
The use of pesticides in horticultural sector in Niger has become an integral part of modern agriculture. Nevertheless, their inappropriate use can generate negative health effects to operators. A study was carried out among Kongou farmers in order to assess their potential dermal exposure (PDE). The UK-POEM model was used to quantify the PDE during mixing/loading and application according to the local practices. In order to determine which parts of the operator body are subject to most contamination during spraying and to validate the theoretical model used, a patch method was used with a tartrazine dye. The deposits of the tartrazine on patches were measured by colorimetry thanks to the absorbance value determined after their extraction in water and a calibration curve. A total of ten spraying trials (five trials with the hand-held sprayer and five others with the backpack sprayer) were performed by different producers at 0.5 and 1 m height for each trial. The survey shows that 92% of the farmers are illiterate and the most common active substances identified are organophosphate or pyrethroids insecticides. Seventy percent of operators do not use any personal protective equipment (PPE) during mixing/loading or spraying. The predictive systemic exposure levels vary from 0.0027?mg kg?1 bw per day to 0.7692?mg kg?1 bw per day for backpack sprayer and from 0.0261?mg kg?1 bw per day to 0.9788?mg kg?1 bw per day for hand-held sprayer, several times higher the Acceptable Operator Exposure Level (AOEL) for some actives substances. Theoretical modeling indicates more exposure of operator by a hand-held sprayer than a backpack sprayer. The patch method results show that the deposits of dye increase when the position of sprayer nozzle increases from 0.5 to 1 m for the two sprayers. All parts of the operator body are contaminated but lower body parts and chest are the most exposed. The patch method results also show that hand spraying contaminates operator more than backpack spraying, confirming the results of the theoretical model. 相似文献
69.
Ana L. De Toffoli Bruno H. Fumes 《Journal of environmental science and health. Part. B》2018,53(7):434-440
On-line in-tube solid phase microextraction (in-tube SPME) coupled to high performance liquid chromatography and tandem mass spectrometry (HPLC-MS/MS) was successfully applied to the determination of selected triazines in water samples. The method based on the employment of a packed column containing graphene oxide (GO) supported on aminopropyl silica (Si) showed that the extraction phase has a high potential for triazines extraction aiming to its physical-chemical properties including ultrahigh specific surface area, good mechanical and thermal stability and high fracture strength. Injection volume and loading time were both investigated and optimized. The method validation using Si-GO to extract and concentrate the analytes showed satisfactory results, good sensitivity, good linearity (0.2–4.0 µg L?1) and low detection limits (1.1–2.9 ng L?1). The high extraction efficiency was determined with enrichment factors ranging from 1.2–2.9 for the lowest level, 1.3–4.9 intermediate level and 1.2–3.0 highest level (n = 3). Although the analytes were not detected in the real samples evaluated, the method has demonstrated to be efficient through its application in the analysis of spiked triazines in ground and mineral water samples. 相似文献
70.
Md. Badiuzzaman Khan Mauro Masiol Caterina Bruno Alberto Pasqualetto Gian Maria Formenton Claudio Agostinelli Bruno Pavoni 《Environmental science and pollution research international》2018,25(32):31987-32000
A yearlong sampling campaign (2012–2013) was conducted in six major cities of the Veneto region to investigate the spatial-temporal trends and the factors affecting the polycyclic aromatic hydrocarbon (PAHs) variations and identify the local sources. Sixty samples per city were collected for analyses in every alternate month (April, June, August, October, December, and February): 10 samples per sampling site in 10 consecutive days of the months selected. Samples were ultrasonically extracted with acetonitrile and processed through high-performance liquid chromatography. Total Σ-PAH concentrations ranged from 0.19 to 70.4 ng m?3 with a mean concentration of 11.5 ng m?3. The mean benzo[a]pyrene (BaP) concentration reached 2.0 ng m?3, which is two-times higher than the limit set by the European Union. BaP contributed for 17.4% to the total concentration of PAHs, which showed the same pattern across the region with maxima during cold months and minima in the warm period. In this study, PAHs showed an inverse relationship with temperature, solar radiation, wind speed, and ozone. According to this study, biomass burning for household heating and cooking, followed by gaseous PAHs absorption on particles due to low atmospheric temperature, were the main reasons for increasing PAHs concentration in winter. Health risk, evaluated as lifetime lung cancer risk (LCR), showed a potential carcinogenic risk from the airborne BaPTEQ six-fold higher in the cold season than in the warm one. Diagnostic ratios and conditional probability functions were used to locate the sources, and results confirmed that local emission, overall domestic heating, and road transport exhausts were responsible for higher concentration rates of PAHs as well as of PM2.5. 相似文献