Ozone and forests in South-Western Europe

The paper provides basic information about background, objectives and structure of O3SWE (Ozone at the permanent monitoring plots in South-Western Europe), an international co-operative project aimed at evaluating O3 concentrations, cumulative exposure, uptake and effects on forest vegetation in four countries of South-Western Europe (France, Italy, Luxenbourg, Spain and Switzerland). The project covers a total of 83 permanent plots of the EU and UN/ECE intensive forest monitoring programme and span over three years of investigation (2000-2002). The O3SWE project aims to demonstrate how, using data collected routinely in an intensive forest monitoring network, O3 exposure, flux and effects can be assessed and exceedances critically evaluated.     

Ozone and forests in South-Western Europe--What have we learned?

Monitoring of forest condition and ozone (O3) at 83 sites in France, Italy, Luxenbourg, Spain and Switzerland resulted in a number of findings in relation to the knowledge of O3 exposure (concentration and cumulative AOT40), feasibility of the assessment of stomatal O3 flux and relationships between O3 and crown defoliation of beech and visible symptoms on native vegetation. However, the project provides evidence of issues to be addressed within the current monitoring system (data quality, validation sites and response indicators) and indications as to how the monitoring of O3 risk in the context of an effect-oriented monitoring program can be improved.     

Metals in sediments and mangrove oysters (Crassostrea rhizophorae) from the Caroni Swamp,Trinidad

Metals can have significant impacts on inhabitants of mangrove swamps as well as consumers of mangrove-associated fauna. Yet, for several Caribbean islands, assessments regarding the impact of metals on such ecosystems are particularly sparse. The present study investigated the distribution and potential impact of Cd, Cr, Cu, Ni, Pb and Zn in the Caroni Swamp, Trinidad and Tobago’s largest mangrove ecosystem. Surface sediments and mangrove oysters (Crassostrea rhizophorae) from 10 sites in the swamp were analysed for the 6 identified metals. The concentration ranges (in μg/g dry wt.) of metals in sediments from Caroni Swamp were: Zn (113.4–264.6), Cr (27–69.7), Ni (10.7–41.1) and Cu (11–40.7). Based on Canadian Sediment Quality Guidelines (CSQGs), metals in sediments posed a low to medium risk to aquatic life. The concentration ranges (in μg/g wet wt.) for metals in Crassostrea rhizophorae tissues were: Zn (123.2–660), Cu (4.2–12.3), Ni (0.1–5.5), Pb (0.1–0.9), Cr (0.2–0.3) and Cd (0.1–0.2). Multiple evaluations indicated that zinc posed a potential threat to the health of oyster consumers. Information from this study is vital for managing the Caroni Swamp, safeguarding the health of consumers of shellfish on this Caribbean island and serving as a useful baseline for future local and regional risk assessments.     

A new typology for Portuguese beaches: An exploratory study

Beaches are now the most popular tourist destination and increased demand in the past 40 years has led not only to beach congestion but also to a differentiation between urban (resorts, overcrowded and under huge pressure), to natural (less crowded beaches). This diversity needs to be further explored not only to characterize individual beaches in a precise way, but also to understand the distinctive characteristics responsible for options made by beach users. Some attempts have been made to create a universal beach typology but sparse research has been undertaken. The topic is of extreme importance for beach management, as most studies only take into consideration beach usage type and few consider the surrounding environment (landscape). This paper presents an exploratory work for Portuguese beaches which creates a new classification, according to usage and surrounding environment, based on several variables, measured and weighted. The results scale between zero and five and assess how a beach can be classified along an urban (0) to natural (5) spectrum. Variables studied include population density, number of hotels urban density, car park distance to the beach, etc. A pilot study applied to 100 beaches in the Lisbon Metropolitan Area, found that a densely populated region, can also contain beaches with natural characteristics.     

Two and three-dimensional shoreline behaviour at a MESO-MACROTIDAL barred beach

The present work investigates cross-shore shoreline migration as well as its alongshore variability (with deformation) on timescales of days to years using 6 years of time-averaged video images. The variability of the shoreline is estimated through empirical statistical methods with comprehensive reference to three scales of variability. At the meso-to macro-tidal barred Biscarrosse beach, shoreline responds in decreasing order at seasonal (winter/summer cycles, 52%), event (storms, 28%) and inter-annual scales. Whereas seasonal evolution is dominated by wave climate modulation, short-term evolution is influenced by tidal range and surf-zone sandbar characteristics. The influence of tide range and sandbars increases when timescale decreases. This is even more the case for the alongshore deformation of the shoreline which is dominated by short-term evolution. An EOF analysis reveals that the first mode of shoreline change time series is associated with cross-shore migration and explains 58% of the shoreline variability. The rest of the modes are associated to deformation which explain 42% of shoreline variability.     

Environmentally friendly system for the degradation of multipesticide residues in aqueous media by the Fenton’s reaction

A Fenton oxidation system employing zero-valent iron (whose source was swarf, a residue of metallurgical industries, in powder form) and hydrogen peroxide for the treatment of an aqueous solution with six pesticides was developed, and the effect of the iron metal content, pH, and hydrogen peroxide concentration was evaluated. The characterization of the aqueous solution resulted in: pH 5.6, 105 mg L^?1 of dissolved organic carbon, and 44.6 NTU turbidity. In addition, the characterization of the swarf by FAAS and ICP-MS showed 98.43?±?7.40 % of zero-valent iron. The removal was strongly affected by the content of iron metal, pH, and hydrogen peroxide concentration. The best degradation conditions were 2.0 g swarf, pH 2.0, and 5 mmol L^?1 H₂O₂. At the end of the treatment, the pesticide degradation ranged from 60 to 100 %, leading to 55 % mineralization. Besides, all hydrogen peroxide was consumed and the determination of total dissolved iron resulted in 2 mg L^?1. Thus, the advantages of this system are rapid degradation (up to 20 min), high-degradation rates, simple handling, and low cost.

Degradation and mineralization of sulcotrione and mesotrione in aqueous medium by the electro-Fenton process: a kinetic study

Introduction

The degradation and mineralization of two triketone (TRK) herbicides, including sulcotrione and mesotrione, by the electro-Fenton process (electro-Fenton using Pt anode (EF-Pt), electro-Fenton with BDD anode (EF-BDD) and anodic oxidation with BDD anode) were investigated in acidic aqueous medium.

Methods

The reactivity of both herbicides toward hydroxyl radicals was found to depend on the electron-withdrawing effect of the aromatic chlorine or nitro substituents. The degradation of sulcotrione and mesotrione obeyed apparent first-order reaction kinetics, and their absolute rate constants with hydroxyl radicals at pH?3.0 were determined by the competitive kinetics method.

Results and discussion

The hydroxylation absolute rate constant (k _abs) values of both TRK herbicides ranged from 8.20?×?10⁸ (sulcotrione) to 1.01?×?10⁹ (mesotrione) L?mol^?1?s^?1, whereas those of the TRK main cyclic or aromatic by-products, namely cyclohexane 1,3-dione , (2-chloro-4-methylsulphonyl) benzoic acid and 4-(methylsulphonyl)-2-nitrobenzoic acid, comprised between 5.90?×?10⁸ and 3.29?×?10⁹?L?mol^?1?s^?1. The efficiency of mineralization of aqueous solutions of both TRK herbicides was evaluated in terms of total organic carbon removal. Mineralization yields of about 97?C98% were reached in optimal conditions for a 6-h electro-Fenton treatment time.

Conclusions

The mineralization process steps involved the oxidative opening of the aromatic or cyclic TRK by-products, leading to the formation of short-chain carboxylic acids, and, then, of carbon dioxide and inorganic ions.     

Towards a renewed research agenda in ecotoxicology

New concerns about biodiversity, ecosystem services and human health triggered several new regulations increasing the need for sound ecotoxicological risk assessment. The PEER network aims to share its view on the research issues that this challenges. PEER scientists call for an improved biologically relevant exposure assessment. They promote comprehensive effect assessment at several biological levels. Biological traits should be used for Environmental risk assessment (ERA) as promising tools to better understand relationships between structure and functioning of ecosystems. The use of modern high throughput methods could also enhance the amount of data for a better risk assessment. Improved models coping with multiple stressors or biological levels are necessary to answer for a more scientifically based risk assessment. Those methods must be embedded within life cycle analysis or economical models for efficient regulations. Joint research programmes involving humanities with ecological sciences should be developed for a sound risk management.     

Of Catholicism,Forest and Management: An Analysis of Imaginaries in the Discussion of the Native Forest Law in Chile

The relationship between media and the construction of environmental policy has been studied acutely in the Global North. However, less attention has been paid to deeper cultural symbols displayed in public policy discussions in the Global South. Through qualitative examination of 100 letters to the editor (LTE) of the Chilean newspaper, El Mercurio, this study examined the imaginaries in the public discussion of the Native Forest Policy in Chile. Although such a discussion was often framed as a technical debate, the letters to El Mercurio were embedded within Catholic imaginaries, condensed into two main sets. The first one constructed forests as endangered due to human action and called for immediate protection, contending that humans shall not destroy God's creation. The second set depicted a degraded forest in need of rational management to satisfy the needs of God's children. This study suggests that, in a mediated public discussion, religion might play an important role in communicating environmental issues. This work contributes to our understanding of environmental imaginaries and discourses in the context of environmental controversies, to the understanding of the functions of the LTE, and to the social construction of forest policy in recent post-autocratic regimes.