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41.
Most studies on contaminant interactions with the subsurface environment focus on contaminant transport, retention and persistence, and on potential remediation of polluted soils, vadose zones and aquifers. Changes in the soil-vadose-aquifer zone (SVAZ) matrix and properties, caused by human activities, are thus usually considered to be deviations from a normal geochemical environment, which will disappear by natural processes or by specific remediation procedures. However, contaminants may also cause, under specific conditions, irreversible changes in SVAZ properties. In this critical overview, we discuss a different aspect of contaminant-SVAZ interactions: irreversible changes in natural SVAZ properties as a result of anthropogenically-induced chemical contamination. We survey selected research results that illustrate various aspects of such phenomena, in soils, aquifers and the vadose zone. Grouping contaminants according to major and trace elements, we observe that major elements can irreversibly affect water transmission and other physical and chemical properties of the SVAZ, mainly in the liquid phase, while trace elements affect mostly the solid phase matrix. 相似文献
42.
This article sets out to analyse how and to what degree land use is linked to the physical characteristics of the territory
itself, and the way in which changes in land use are determined by agricultural and socio-demographic dynamics. The study
was conducted within the territorial boundaries of five municipalities surrounding Lake Trasimeno and refers to the periods
1977–2000 for land use and 1971–2001 for socio-demography data. The use of environmental, social, economic and agricultural
indicators demonstrates how a mix of various indicators are useful for monitoring the changes which took place. It also shows
the powerful influence that socio-demographic factors exert upon land use and landscape change. 相似文献
43.
de Figueiredo DR Ferreira RV Cerqueira M de Melo TC Pereira MJ Castro BB Correia A 《Environmental monitoring and assessment》2012,184(1):471-485
The information on bacterial community composition (BCC) in Portuguese water bodies is very scarce. Cértima River (central
western Portugal) is known to have high levels of pollution, namely organic. In the present work, the BCC from a set of 16
water samples collected from Cértima River Basin and its main tributaries was characterized using 16S rDNA–denaturing gradient
gel electrophoresis, a culture-independent molecular approach. Molecular data were related to environmental parameters through
multivariate analysis to investigate potential impact of water pollution along the river. Principal component analysis using
environmental data showed a water quality gradient from more pristine waters (at the mountain tributaries) to waters with
increasingly eutrophic potential (such as Fermentelos Lake). This gradient was mainly defined by factors such as organic and
inorganic nutrient sources, electrical conductivity, hydrogen carbonate concentration, and pH. Molecular results showed variations
in BCC along Cértima River Basin but in the main river section, a Bacteroidetes phylotype (Flavobacterium sp.) proved to be dominant throughout the river course. Multivariate analysis suggests that spatial variation of BCC along
the Cértima River Basin depended mainly on parameters such as Chl a, total suspended solid (TSS), total organic carbon, electrical conductivity, and HCO
_boxclose^-_{3}^{-} levels. Bacteroidetes phylotypes were all related to higher electrical conductivity and HCO3-_{3}^{-} levels although some of these were also correlated with high SO42-_{4}^{2-} and others with high soluble reactive phosphorus, nitrate, TN, and Kjeld-N levels. The Gammaproteobacteria occurrence was correlated with high SO42-_{4}^{2-} levels. One of the Betaproteobacteria phylotypes showed to correlate with low redox potential (Eh) and high temperature, pH, TSS, and Chl a levels while another one showed a negative correlation with Chl a values. 相似文献
44.
45.
Manuela Carneiro Bruno Colaço Ricardo Brandão Carla Ferreira Nuno Santos Vanessa Soeiro Aura Colaço Maria João Pires Paula A. Oliveira Santiago Lavín 《Environmental monitoring and assessment》2014,186(11):7011-7021
The accumulation of heavy metals in the environment may have a wide range of health effects on animals and humans. Thus, in this study, the concentrations of arsenic (As), cadmium (Cd), lead (Pb), and mercury (Hg) in the blood and tissues (liver and kidney) of Portuguese common buzzards (Buteo buteo) were determined by inductively coupled plasma-mass spectrometer (ICP-MS) in order to monitor environmental pollution to these elements. In general, Hg and As were the elements which appeared in the highest and lowest concentrations, respectively. A highest percentage of non-detected concentration was found for blood Cd (94.6 %) but, in turn, it was the only metal that was detected in all kidney samples. The kidney was the analyzed sample which showed the highest concentrations of each element evaluated. Statistically, significant differences among blood, liver, and kidney samples were observed for As and Cd (P?0.05). Cd concentrations in kidney and liver varied significantly with age: Adults showed higher hepatic and renal Cd concentrations than juveniles. Blood Pb concentration seems to show an association with the hunting season. Although raptors are at the top of the food chain and are thus potentially exposed to any biomagnification processes that may occur in a food web, the individuals evaluated in this study generally had low levels of heavy metals in blood and tissues. However, chronic exposure to these metals was verified. The results presented here lend weight to arguments in favor of continuous biomonitoring of metals and metalloids, since heavy metals may accumulate to levels that will pose a risk to both human health and the environment. 相似文献
46.
Emmanuel C. Gentil Anders Damgaard Michael Hauschild Göran Finnveden Ola Eriksson Susan Thorneloe Pervin Ozge Kaplan Morton Barlaz Olivier Muller Yasuhiro Matsui Ryota Ii Thomas H. Christensen 《Waste management (New York, N.Y.)》2010,30(12):2636-2648
A number of waste life cycle assessment (LCA) models have been gradually developed since the early 1990s, in a number of countries, usually independently from each other. Large discrepancies in results have been observed among different waste LCA models, although it has also been shown that results from different LCA studies can be consistent. This paper is an attempt to identify, review and analyse methodologies and technical assumptions used in various parts of selected waste LCA models. Several criteria were identified, which could have significant impacts on the results, such as the functional unit, system boundaries, waste composition and energy modelling. The modelling assumptions of waste management processes, ranging from collection, transportation, intermediate facilities, recycling, thermal treatment, biological treatment, and landfilling, are obviously critical when comparing waste LCA models.This review infers that some of the differences in waste LCA models are inherent to the time they were developed. It is expected that models developed later, benefit from past modelling assumptions and knowledge and issues. Models developed in different countries furthermore rely on geographic specificities that have an impact on the results of waste LCA models. The review concludes that more effort should be employed to harmonise and validate non-geographic assumptions to strengthen waste LCA modelling. 相似文献
47.
Bruno Nunes Ana Raquel Barbosa Sara C. Antunes Fernando Gonçalves 《Environmental science and pollution research international》2014,21(9):6258-6262
The simultaneous presence of distinct compounds in the aquatic environment can be causative of various toxicological interactions. This scenario challenges ecotoxicologists, since the assessment of toxicological effects caused by the simultaneous presence of multiple substances is by far more complicated. An illustrative example can be given by mentioning the anticholinesterasic compounds: by studying the level of cholinesterase impairment of an exposed organism, it is possible to ascertain the level of exposure to all anticholinesterasics (despite their chemical classes and natures) that the organism was subjected to. In this work, we describe the effects of three chemically different, albeit mechanistically, and toxicologically similar compounds (copper, chlorfenvinphos, and pyridostigmine) on cholinesterases of the fish Gambusia holbrooki. The results showed that the combinatorial effects may be of considerable extent, even for levels of exposure that are close to the ones already reported in the wild, for each isolated compound. 相似文献
48.
Terukazu Kumazawa Kouji Kozaki Takanori Matsui Osamu Saito Mamoru Ohta Keishiro Hara Michinori Uwasu Michinori Kimura Riichiro Mizoguchi 《Sustainability Science》2014,9(2):173-192
Implementation of the sustainability science (SS) approach is often difficult because of poor communication between experts from different academic fields. We focused on ontology engineering as a method of knowledge structuring that supports the co-deliberation process. However, SS is too broad for a few experts to construct an ontology because SS targets and covers almost all existing research fields from the viewpoint of problem-solving. The N-iteration process is required for completing an SS ontology. In the present paper, we discuss the initial design process for constructing an ontology on SS from the aspect of a knowledge-sharing tool to support co-deliberation. First, we identified the SS ontology by referring to the existing literature. Second, we traced the structuring process of the SS ontology, which is independent of the existing research domain. Third, we compared the SS ontology with existing ontologies or concept structures on SS. Fourth, we assessed the SS ontology produced in the initial process in terms of relevance and coverage and addressed areas for improvement in order to facilitate co-deliberation among researchers from different domains. As a result of developing the SS ontology and applying it to the mapping tool that we developed based on the ontology, we found the following three points: the SS ontology enables us to define concepts relevant to SS without overlapping by distinguishing part-of and attribute-of relationships at the upper level of the ontology; the SS-based mapping tool successfully represents the potential countermeasures required by the targeted problem for all scientific fields except experimental engineering; however, the SS ontology requires further improvement in order to represent the conceptual linkage arising from compound and secondary problems and the fulfillment of classes at the lower hierarchy of Shortage problem, and requires slots for the entire hierarchy. In addition, based on the discussion of the areas for improvement, we found that missing slots and classes should be added in the process in which we use or improve tools corresponding to a variety of requirements for supporting co-deliberation. In this way, we are able to propose an incremental process for constructing the SS ontology from the aspect of a knowledge-sharing tool to support co-deliberation. 相似文献
49.
Bruno Nunes Fátima Brandão Tânia Sérgio Sara Rodrigues Fernando Gonçalves Alberto Teodorico Correia 《Environmental science and pollution research international》2014,21(12):7501-7511
Flatfish species, such as the turbot (Scophthalmus maximus), are common targets for toxic effects, since they are exposed through the food chain (ingestion of contaminated preys) and are in direct contact with the waterborne contaminant and sediments. Furthermore, these fish species live in close proximity to interstitial water that frequently dissolves high amounts of contaminants, including metals. Despite this significant set of characteristics, the present knowledge concerning flatfish contamination and toxicity by metals is still scarce. To attain the objective of assessing the effects of metals on a flatfish species, S. maximus specimens were chronically exposed to lead, copper and zinc, at ecologically relevant concentrations, and biochemical (oxidative stress: catalase and glutathione S-transferases activities, and lipid peroxidation; neurotoxicity: cholinesterase activity) parameters were assessed on selected tissues (gills and liver). Copper had no significant effects on all tested parameters; lead was causative of significant increases in liver GSTs activities and also in lipoperoxidation of gill tissue; exposure to zinc caused a significant increase in catalase activity of gill tissue. None of the tested metals elicited noteworthy effects in terms of neurotoxicity. The obtained results showed that only the metal lead is of some environmental importance, since it was able to cause deleterious modifications of oxidative nature at relevant concentrations. 相似文献
50.
Predictive value of cardiovascular parameters in stages 1 and 2 of twin-to-twin transfusion syndrome