全文获取类型
收费全文 | 10053篇 |
免费 | 38篇 |
国内免费 | 935篇 |
专业分类
安全科学 | 183篇 |
废物处理 | 393篇 |
环保管理 | 907篇 |
综合类 | 3550篇 |
基础理论 | 716篇 |
污染及防治 | 3663篇 |
评价与监测 | 932篇 |
社会与环境 | 540篇 |
灾害及防治 | 142篇 |
出版年
2023年 | 27篇 |
2022年 | 38篇 |
2020年 | 29篇 |
2019年 | 25篇 |
2018年 | 29篇 |
2017年 | 52篇 |
2016年 | 40篇 |
2015年 | 94篇 |
2014年 | 42篇 |
2013年 | 41篇 |
2012年 | 796篇 |
2011年 | 1040篇 |
2010年 | 128篇 |
2009年 | 264篇 |
2008年 | 901篇 |
2007年 | 910篇 |
2006年 | 695篇 |
2005年 | 656篇 |
2004年 | 589篇 |
2003年 | 544篇 |
2002年 | 503篇 |
2001年 | 368篇 |
2000年 | 248篇 |
1999年 | 119篇 |
1998年 | 34篇 |
1997年 | 47篇 |
1996年 | 36篇 |
1995年 | 74篇 |
1994年 | 54篇 |
1993年 | 100篇 |
1992年 | 84篇 |
1991年 | 115篇 |
1990年 | 134篇 |
1989年 | 103篇 |
1988年 | 202篇 |
1987年 | 242篇 |
1986年 | 123篇 |
1985年 | 233篇 |
1984年 | 216篇 |
1983年 | 193篇 |
1982年 | 161篇 |
1981年 | 147篇 |
1980年 | 129篇 |
1979年 | 77篇 |
1978年 | 78篇 |
1977年 | 34篇 |
1976年 | 62篇 |
1975年 | 47篇 |
1974年 | 69篇 |
1973年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 781 毫秒
991.
Ecological risk assessment of open coal mine area 总被引:2,自引:0,他引:2
The coal mine areas in China have the serious conflicts between resources exploitation and ecology safety, therefore the coal mine ecological risk assessment is an important problem which relates to the sustainability of coal mines to regions and the whole country. In this study, open coal mine area serves as researching object, heavy metals, soil erosion and coast are screened out as risk resources, soil wireworm as the receiver of heavy metals risk, biotope ecosystem as the receiver of soil erosion and coast risk; ecological indexes are calculated with species background index, biological diversity index and natural degree index, ecological friability indexes are calculated with soil fertility index, plant coverage, plant species diversity index, soil wireworm index and maturity index, and the typical coal mine area assessment indexes system is established. In addition, the regional ecological risk assessment is conducted on the friable ecological system of Fuxin Haizhou open coal mine area. Examples are researched of Haizhou open coal mine, the coal mine risk distribution is established, and foundations are provided for the administrative decision-making. 相似文献
992.
Markovics R Kanduč T Szramek K Golobočanin D Milačič R Ogrinc N 《Journal of environmental monitoring : JEM》2010,12(11):2165-2176
Presented here is a study of the geochemical dynamics of the entire River Sava watershed, a major tributary of the River Danube which has not previously been investigated. The sampling was performed at 33 selected locations along the main channel of the stream and at its largest tributaries during three sampling seasons (fall 2005, spring 2006 and fall 2006), going from headwater locations to the mouth near the confluence with the Danube. Almost 80% of the solutes are derived from carbonate mineral weathering and represent over 50% of specific HCO(3)(-) flux normalized to unit basin area at the mouth of the Danube. Statistical analysis indicates that agricultural and industrial sources contribute significantly to increased Na(+), K(+), Cl(-), SO(4)(2-) and NO(3)(-) concentrations in tributary waters. Different processes control the water chemistry along the course of the Sava's drainage-the upper reaches are largely regulated by contributions from carbonate mineral weathering, the middle reaches are influenced by agricultural activity and biological processes related to eutrophication, while the lower reaches tend to have more pronounced parameters related to the industrial processing along with leakages from municipal sanitary systems of these higher population density areas. 相似文献
993.
Both the net primary productivity (NPP) and the normalized difference vegetation index (NDVI) are commonly used as indicators
to characterize vegetation vigor, and NDVI has been used as a surrogate estimator of NPP in some cases. To evaluate the reliability
of such surrogation, here we examined the quantitative difference between NPP and NDVI in their outcomes of vegetation vigor
assessment at a landscape scale. Using Landsat ETM+ data and a process model, the Boreal Ecosystem Productivity Simulator,
NPP distribution was mapped at a resolution of 90 m, and total NDVI during the growing season was calculated in Heihe River
Basin, Northwest China in 2002. The results from a comparison between the NPP and NDVI classification maps show that there
existed a substantial difference in terms of both area and spatial distribution between the assessment outcomes of these two
indicators, despite that they are strongly correlated. The degree of difference can be influenced by assessment schemes, as
well as the type of vegetation and ecozone. Overall, NDVI is not a good surrogate of NPP as the indicators of vegetation vigor
assessment in the study area. Nonetheless, NDVI could serve as a fairish surrogate indicator under the condition that the
target region has low vegetation cover and the assessment has relatively coarse classification schemes (i.e., the class number
is small). It is suggested that the use of NPP and NDVI should be carefully selected in landscape assessment. Their differences
need to be further evaluated across geographic areas and biomes. 相似文献
994.
The chemical forms and ecological risk of As were characterized in the sediment of the Daliao River System (DRS), which has
been affected by long-term intensive industrial, urban, and agricultural activities. Twenty-seven samples of surface sediment
were collected and analyzed for total As content and that of its chemical forms. The results indicated that the average total
As content in the sediment was 9.83 mg kg − 1 but that the levels ranged from 1.57 to 83.09 mg kg − 1. At the sites near cities, mining sites, and the estuary of the DRS, it is likely that adverse effects on aquatic organisms
occur, due to As levels in the sediment that are often higher than the threshold effect level and occasionally higher than
the probable effect level. A selectively sequential extraction indicated that the majority of As in the sediment was bound
to Fe oxides (62.1%), with moderate proportions of residual As (19.8%), specifically adsorbed As (17.9%), and a low proportion
of non-specifically adsorbed As (1.1%). In addition, the content of Fe in the sediment was positively and significantly correlated
with the contents of amorphous and crystalline Fe oxide-bound As, confirming the crucial role of Fe oxides in immobilizing
high amounts of As in superficial environments. The average molar ratio of As to Fe was 1.18 × 10 − 4 in the surface sediment of the DRS, similar to that of natural Fe oxides, but much lower than that of synthesized Schwertmannite.
Therefore, the release of As under reduced and low pH conditions can cause serious problems for water resources and for living
organisms. 相似文献
995.
Warren C Duzgoren-Aydin NS Weston J Willett KL 《Environmental monitoring and assessment》2012,184(2):1107-1119
Hurricanes are relatively frequent ecological disturbances that may cause potentially long-term impacts to the coastal environment.
Hurricane Katrina hit the Mississippi Gulf Coast in August 2005, and caused a storm surge with the potential to change the
trace element content of coastal surface sediments. In this study, surface estuarine and marine sediments were collected monthly
following the storm from ten sites along the Mississippi Gulf Coast (Mobile Bay, Grand Bay Bayous Heron and Cumbest, Pascagoula,
Ocean Springs, Biloxi Gulf, Back Biloxi Bay, Gulfport Gulf, Gulfport Courthouse Rd, and Gulfport Marina). Concentrations of
V, Cr, Mn, Fe, Co, Ni, Zn, As, Cd, and Pb were measured by inductively coupled plasma–mass spectrometry to evaluate their
temporal and spatial variations in the year following Hurricane Katrina. Sediments were characterized by pH, particle size
distribution and total carbon and nitrogen content. Trace element contents of the sediments were determined in both <2 mm
and <63 μm grain size fractions. Results revealed no significant temporal and spatial variability in trace element concentrations,
in either size fraction. Potential ecological risk of the sediments was assessed by using NOAA SQuiRTs’ guideline values;
most concentrations remained below probable adverse effects guidelines to marine organisms suggesting that trace elements
redistributed by Hurricane Katrina would not cause an adverse impact on resident organisms. Instead, the concentrations of
trace elements were site-dependent, with specific contaminants relating to the use of the area prior to Hurricane Katrina. 相似文献
996.
Sediment quality guidelines (SQGs) can be derived using different approaches and are commonly used in environmental management,
reclamation, and risk assessment. The screening-level concentration (SLC) approach has been used in Ontario, Canada, to derive
lowest effect levels (LELs) and severe effect levels for use as SQGs. This approach was adopted by the Canadian Nuclear Safety
Commission (CNSC) to set guidelines for metals (As, Cr, Cu, Pb, Mo, Ni, Se, U, and V) and radionuclides (Ra-226, Pb-210, and
Po-210) in sediment at northern Saskatchewan uranium mining and milling operations. The SLC approach is based on total metal
and radionuclide concentrations in sediment, and corresponding benthic community composition data for a specific sampling
site. In this study, sediment chemistry (total metals and radionuclides) and benthic community data from northern Saskatchewan
uranium operations were compiled and examined. Results indicate that the CNSC-derived SQGs had limited relationships to observed
effects, or lack thereof, on benthic invertebrate communities near uranium operations in Saskatchewan. The LELs were found
to correctly align with effects at 95% of the sites that had effects, on a general basis, but on an element-specific basis
many of the elements had concentrations at effect sites below their LELs. Furthermore, concentrations of the evaluated elements
exceeded at least one LEL at 60% of the no-effect sites. The high number of exceedences of LELs at reference and no-effect
sites (false-positives) calls to question the appropriateness of the CNSC-derived SQGs. It is suggested that alternatives
to the SLC approach be explored. 相似文献
997.
Kharroubi A Gargouri D Baati H Azri C 《Environmental monitoring and assessment》2012,184(6):4001-4014
Concentrations of selected heavy metals (Cd, Pb, Zn, Cu, Mn, and Fe) in surface sediments from 66 sites in both northern and
eastern Mediterranean Sea–Boughrara lagoon exchange areas (southeastern Tunisia) were studied in order to understand current
metal contamination due to the urbanization and economic development of nearby several coastal regions of the Gulf of Gabès.
Multiple approaches were applied for the sediment quality assessment. These approaches were based on GIS coupled with chemometric
methods (enrichment factors, geoaccumulation index, principal component analysis, and cluster analysis). Enrichment factors
and principal component analysis revealed two distinct groups of metals. The first group corresponded to Fe and Mn derived
from natural sources, and the second group contained Cd, Pb, Zn, and Cu originated from man-made sources. For these latter
metals, cluster analysis showed two distinct distributions in the selected areas. They were attributed to temporal and spatial
variations of contaminant sources input. The geoaccumulation index (I
geo) values explained that only Cd, Pb, and Cu can be considered as moderate to extreme pollutants in the studied sediments. 相似文献
998.
Sandy soil samples spiked with Bonny light crude oil were subsequently treated with Fenton's reagent at acidic, neutral, and basic pH ranges. Oil extracts from these samples including an untreated one were analyzed 1?week later with a gas chromatograph to provide evidence of hydrocarbon depletion by the oxidant. The reduction of three broad hydrocarbon groups-total petroleum hydrocarbon (TPH); benzene, toluene, ethylbenzene, and xylene (BTEX); and polycyclic aromatic hydrocarbon (PAH) were investigated at various pHs. Hydrocarbon removal was efficient, with treatment at the acidic pH giving the highest removal of about 96% for PAH, 99% for BTEX, and some TPH components experiencing complete disappearance. The four-ringed PAHs were depleted more than their three-ringed counterparts at the studied pH ranges. 相似文献
999.
Brázová T Hanzelová V Miklisová D Salgovičová D Turčeková L 《Environmental monitoring and assessment》2012,184(11):6553-6561
The distribution and concentrations of polychlorinated biphenyls (PCBs) were determined in fish species (European perch Perca fluviatilis, northern pike Esox lucius, pike perch Sander lucioperca, wels catfish Silirus glanus, common carp Cyprinus carpio, European eel Anguilla anguilla, freshwater bream Abramis brama, goldfish Carassius auratus, and roach Rutilus rutilus) in a heavily polluted water reservoir Zemplínska ?írava (Slovakia). The study performed at two different time points 5?years apart (2004 and 2009) revealed serious PCB contamination of fish muscle tissue and significant interspecies as well as tissue-specific differences in PCB uptake by fish. Total PCBs broadly correlated with the trophic position of individual fish species within a food chain (P?0.01). The concentrations were particularly high in predatory fish species, perch, pike, and pike perch (108.0, 90.1, and 113.0?mg?kg(-1) lipid wt, respectively), but comparable PCB values were also found in non-predatory detrivorous freshwater bream (128.0?mg?kg(-1) lipid wt). The lowest PCB values were surprisingly assessed in European eel (17.1?mg?kg(-1) lipid wt). Tissue analysis showed the highest storage capacity of the liver (hepatopancreas in cyprinids) with maximum concentrations recorded found in northern pike (214.0?mg?kg(-1) lipid wt) and freshwater bream (163.0?mg?kg(-1) lipid wt). Negative correlations, mostly not significant, between the total PCB concentrations and fish weight were observed (P?>?0.05). The study has shown that the kind of fish, its feeding habit, and specific conditions of the habitat are mutually interrelated factors that are responsible for significant variations in fish body burdens. A tendency to PCB biomagnification was also proved in some fish species of this water reservoir. 相似文献
1000.
Characteristic, composition, and sources of TSP investigated by HRTEM/EDS and ESEM/EDS 总被引:1,自引:0,他引:1
Zhai Y Fu Z Wang L Zeng G Li C Chen H Lan Y Lu P 《Environmental monitoring and assessment》2012,184(11):6693-6707
Total suspended particle (TSP) collected at the fifth floor of House Dust in Hunan University, China, was analyzed in terms of microscopic morphology and chemical composition. The fine particles (50?nm-2?μm) in the TSP were analyzed by a high-resolution transmission electron microscope equipped with an energy-dispersive X-ray analyzer (HRTEM/EDS). Results showed that the particles were in shapes of plate, irregular and agglomerate. Based on EDS results, these fine particulate matter was primarily composed of Fe-rich (35.82-61.29%), Ca-rich (30.18-36.77%) and Si-rich (18.95-32.28%) particles. Other elements mainly including Mg (0.47-4.97%), Al (0.45-14.57%), S (0.45-4.73%), K (1.13-2.13%) and Zn (0.67-3.85%) were also observed. The sources analysis indicated that the HRTEM particles mainly originated from coal combustion, traffic emission, vehicles exhaust emission and fugitive soil or cement particulate matter. The coarse particles (4-50?μm) were detected by environmental scanning electron microscopy coupled with energy-dispersive X-ray detector (ESEM/EDS). Based on a simple algorithm, ESEM particles were categorized into five groups: C-bearing (46.15%, 67% and 86.98%), Si + Ca-bearing (21.48?+?11.80%, 16.51?+?10.81% and 16.32?+?10.62%), Si + Al-bearing (20.06?+?12.40%, 20.16?+?11.22% and 15.31?+?11.25%), Si-bearing (34.40%, 26.92% and 27.15%) particles and aggregates, most of which exhibit obvious crystalline structure, and these ESEM particles mainly derived from vehicles exhaust emission, coal combustion, soil, and biomass burning, while the aggregates are indicative of atmospheric reaction progress. HRTEM/EDS and ESEM/EDS are mutual complementary in analyzing the characteristic and determining the sources of TSP. 相似文献