能量流评价——一种污水处理系统能耗评价的新方法研究

将污染物所含热值定义为污水的能量势,并根据能量势的变化与污水厂能耗的比值,定义了一种全新的污水厂能耗评价指标——能量流(Energy Flow,EF).能量流没有量纲,表示污水厂能耗作用于污染物处理效果上的能源利用效率.通过能量流和比能耗这2种方法对交互式反应器中试系统在改良A2O工艺下运行情况分别进行能耗评价发现:单位污染物比能耗与能量流呈很强的负相关性;处理水量是EF的主要影响因素之一,EF将随处理水量的增加而提高;能量流是一个从能量角度进行评价的的综合指标,其意义相当于一个由多个比能耗(各类去除物质)组成的评价指标体系.因此EF评价可以更清晰地反映污水厂能量利用效率,应替代比能耗作为污水厂运营的辅助参考依据.目前,能量流评价尚不完善,在其内涵中纳入反硝化过程以及除磷等相关生化反应将成为下一步的研究重点.     

Pollution level and human health risk assessment of some pesticides and polychlorinated biphenyls in Nantong of Southeast China

Food consumption is one of the key exposure routes of humans to contaminants. This article evaluated the residue levels of 51 pesticides and 16 polychlorinated biphenyls (PCBs) in selected fish and food items which were commonly consumed in the Nantong area of Jiangsu Province, Southeast China. The 51 pesticides and 16 PCBs were analyzed by highly sensitive gas chromatography-tandem mass spectrometry (GC-MS/MS). The results showed that organochlorine pesticides such as dichlorodiphenyltrichloroethanes (DDTs), hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB) and mirex and other pesticides including chlorpyrifos, pyrethroid pesticides, metolachlor, pyridaben and trifluralin were frequently detected in the samples, which was consistent with the accumulation level and characteristics of these toxic chemicals in human adipose tissue of people living in Nantong. Meanwhile, correlation of the residue level of toxic chemicals with their physical chemical properties and historic use pattern in Nantong area was observed. Combined with dietary survey results at the same sampling locations, human health risk assessment of ingestion through the dietary route was performed. The results suggested that the non-cancer risks of the chemicals investigated can be considered negligible in the Nantong area, however, the cancer risks from lifetime dietary exposure to DDTs and HCB have exceeded the acceptable levels.     

成都地区水质调查与富营养化评价

为了解成都地区各类水体的水质情况,以便为以后的水资源保护及水环境修复工作提供参考依据。特对成都地区的城市景观水体、住宅区景观水体、湖泊、河流以及农业养殖用水的水质情况进行调查,并采用综合营养状态指数法对各类水体的富营养化状态进行评价。结果表明:成都地区水质污染情况严重,河流和养殖水体均达到重度富营养水平,而城市水体也已接近中度富营养水平。     

Low SO2 emission from CFB co-firing MSW and bituminous

Influence of co-firing rate on SO2 emission from co-firing municipal solid waste(MSW) and bituminous containing high amount of sulfur(1.79%) was studied in a 0.15 MWt circulating fluidized bed (CFB). The temperature selected is 1123 K, typical for MSW incineration using CFB. The particle concentration in the dilution zone of the furnace, the alkali metal concentration and sulfate concentration in the recirculating ash and fly ash, and flue gas composition were determined. The results showed that the addition of MSW leads to a significant decrease in SO2 emission. Concentration of SO2 in flue gas decreased to 0 with the co-firing rate greater than 51%. This reduction in SO2 emission is attributed both to the high particle concentration in the dilution zone of the furnace, the high content of alkali metals in the bed material, and to the comparatively high concentration of HCI in flue gas during co-firing of MSW and bituminous.     

水和土壤中磺胺和激素类药物的同时分析方法

建立了一种水和土壤中磺胺嘧啶、磺胺甲嘧啶、磺胺噻唑、磺胺二甲嘧啶、磺胺二甲氧嘧啶、磺胺甲(噁)唑6种磺胺类药物和17α-雌二醇、17β-雌二醇、雌酮、雌三醇、炔雌醇、乙烷雌酚6种激素类药物同时分析的方法.具体步骤:水样过滤后使用Oasis HLB固相萃取小柱进行净化富集;土壤样品经加速溶剂提取(ASE)之后过Oasis HLB小柱净化富集;采用超高效液相色谱-串联质谱(UPLC-MS/MS)进行检测,分别以乙腈和1mL·L-1甲酸溶液、乙腈和1 mL· L-1氨水溶液作为流动相.磺胺在水和土壤中的回收率分别为87.4％～ 103.6％和58.2％～80.0％,激素在水和土壤中的回收率分别为84.8％～ 101.8％和62.8％～79.3％,相对标准偏差均小于10.3％.水和土壤中磺胺的检测限分别为0.11～0.24ng·L-1和0.01～0.02ng·g-1,激素的检测限分别为0.31 ～2.14 ng·L-1和0.03～0.21ng·g-1.用上述方法检测宿迁某典型养殖场周边的地表水和土壤,结果表明采用该方法检测环境样品中的磺胺和激素类药物是可行的.     

TiO_2光催化氧化处理废水存在的问题和改进方案

结合TiO2光催化氧化技术的基本原理,讨论了该技术在废水处理过程中存在的主要问题以及改进的方案。可以预见TiO2光催化氧化将是一种非常有效的处理技术,为彻底解决废水处理问题提供了新的手段,在环境污染治理方面具有广阔的应用前景。     

高速公路交通应急救援资源的配置

针对交通事故与救援资源存在随机性的特点,建立了交通救援资源配置的随机模型。根据高速公路特有的道路条件与交通机理,确定了模型中救援服务水平、事故概率的权重,配置点至事故点的权值以及随机资源等参数值。将所建立的模型与参数用于河南省高速公路的救援资源配置,研究表明,新的配置方案较好满足了交通事故高概率区域的救援需求,并且合理减少了救援需求区域的资源配置数量,为目前高速公路交通应急资源的科学配置提供了重要的参考依据。     

城市埋地天然气管道系统的脆弱性评价模型及其实例应用

脆弱性评价是系统风险评估的新方法,具有理论成熟、指标全面,结果贴合等优点。在对天然气管道风险研究基础上,建立起适合城市天然气管道系统的脆弱性评估指标体系。结合城市天然气管道脆弱性指标的取值特点,选择模糊综合评判方法,建立城市天然气管道系统的脆弱性评估数学模型,实现系统脆弱度计算和脆弱等级确定。并对北京市某段次高压天然气管道的指标进行调研取值,带入模型进行该管道的脆弱性评价,实现模型的实例应用和效果检验。     

辽宁沿海经济带开发战略下的水资源承载力研究

采用压力-状态-响应(Pressure-State-Response,PSR)模型构建了辽宁沿海经济带水资源承载力评价指标体系,通过层次分析法(AHP)确定评价指标权重,运用可变模糊识别模型评价水资源承载力.结果表明,辽宁沿海经济带水资源承载力状态在时间上总体呈波动上升的趋势,在空间上与区域产业结构调整、用水技术进步及经济发展水平有重要关系.在加强配置工程建设的同时,应进一步优化产业用水结构,重点加强海水利用及水质保护力度,从而缓解水资源开发利用与社会经济快速发展之间的矛盾.     

硫化氢浓度测定方法的比较和建议

本文研究了过滤式防毒面具滤毒罐防护硫化氢性能试验中,采用用碘量法和紫外光度法对硫化氢浓度测定的对比。通过试验证明了,碘量法测得的硫化氢的浓度均偏低。结果表明:紫外光度法具有良好的准确度和精确度,适用于长时间测定硫化氢混合气体浓度。