沉淀物和生物中U,Th和226Ra的联合测定

用放射化学法对U,Th,~(226)Ra等核素进行联合测定,国外已有不少报道,只是所用的分离方法和所测的介质不同而已。我国学者也做过一些这方面的工作。本工作建立了用三正辛胺-二甲苯萃取分离法对沉积物和生物样中U,Th和~(226)Ra的联合测定方法。 二、主要仪器与试剂     

Study of prediction for groundwater contamination in wastewater land treatment system

This paper uses a prediction model of groundwater pollution based on the experiments in the laboratory and in field .The model, which was tested and calibrated by the field observated data ,satisfactorily simulated the field conditions in land treatment system of wastewater . Particularly , the model can provide the reliable pollution prediction of heavy metals , organisms and nitrogen . The model was used to predict the groundwater pollution caused by the land treatment system in the region of North China . The calibration of the model showed that correlation coefficients between the tested and predictive data of Cr6+. As3+, organism and NH4+ could reach 0.990, which proved that the model possessed the realistic instructive significance for design and use of wastewater land treatment systems .     

不同生物接触氧化方法对藻类的去除效果比较及其途径分析

比较了3种生物接触氧化法对富营养化水源水中藻类的去除效果，探讨其去除藻类的途径。试验结果表明：淹没式曝气生物陶粒滤池（I型）在4-6m/h过滤速度条件下，对藻类总数的去除效率稳定，平均为70%左右；采用YDT弹性立体填料的中心导流筒曝气生物接触氧化法（Ⅱ型）与直接微孔曝气生物接触氧化法（Ⅲ型），在试验初期对藻类总数的去除率较低，平均去除率分别为60.2%、51.6%。但随着生物膜厚度的增加，试验后期对藻类的去除效果逐步得到提高，平均达70%以上。生物膜对藻类的生物絮凝、吸附、生物膜的脱落沉降等是生物接触氧化法去除藻类的主要途径。     

锦纶生产废水的深度处理研究

采用曝气生物滤池对锦纶生产废水进行深度处理,试验结果表明,该工艺可有效去除CODCr和NH3-N,并在不同运行条件下的运行特性进行了考察,确定试验的最佳气水比。     

碎砖骨料再生混凝土配合比研究

用正交法试验分析了碎砖骨料混凝土的配合比，提出水灰比和碎砖骨料掺量分别是影响混凝土强度和流动性的主要因素。倡导用碎砖做混凝土骨料，保护生态环境。     

Combined effect of tributyltin and benzo[a] pyrene on the levels of sex hormone and vitellogenin in female Sebastiscus marmoratus

Tributyltin（TBT）, an organometal used as an antifouling biocide, has been reported to induce masculinization of fish. Benzo [a]pyrene （BaP）, a widespread carcinogenic polycyclic aromatic hydrocarbon, has been reported that its microsomal metabolites can produce an estrogenic response when tested in vitro. This study was therefore designed to examine the potential in vivo influence of TBT, BaP and their mixture on sex hormone levels in serum of Sebastiscus marmoratus, which were given 2 separate intraperitoneally （ip） injections（a single injection every 7 d） of TBT（0.5, 1, 5 and 10 mg/kg）, BaP（0.5, 1, 5 and 10 mg/kg）, or both in combination（0.5, 1, 5 and 10 mg/kg）; control fish received olive oil vehicle only. Six days after the 2nd injection, serum samples were collected and analyzed for sex hormone levels and alkali labile protein phosphorus （ALPP）, which is related to the yolk precursor protein vitellogenin. The pollutants at all doses significantly reduced serum testosterone, estradiol and ALPP content after 2 injections compared with the corresponding controls. The reduction of the estradiol levels should be response for the decrease of the vitellogenin levels. The results in the present study suggested that aromatase seems not the major target acted by TBT and BaP in fish. This study demonstrated that TBT or BaP exposure both inhibit the reproductive potential in female Sebastiscus marmoratus. Combined effect of TBT and BaP on the serum testosterone, estradiol and ALPP was not antagonism from the anticipation.     

水稻烤田期间N2O排放及其影响因素

水稻田间实验研究了烤田期间的土壤温度、Eh、含水量和裂缝基本性质,矿质态氮以及与氮有关的酶活性的演变规律,及其对N2O排放的影响.试验表明,在水稻分蘖期间烤田,N2O有一个排放高峰,其最高值可达75.6μg·m-2·h-1.在排放高峰后,即使继续烤田,N2O的排放值也将降低.N2O排放与尿素氮肥的施用量没有明显关系.裂缝的生成,改变了N2O的日排放规律.随着烤田时间的延长,脲酶和羟胺还原酶活性呈波动变化,硝酸还原酶活性递减,亚硝酸还原酶活性极低.硝酸还原酶活性与N2O排放之间没有显著相关性.土壤中的脲酶活性与N2O日排放通量呈显著的线性正相关.在烤田期间,NO-3含量呈增加趋势.土壤中的硝态氮含量与N2O排放通量之间呈显著正线性关系.土壤中的铵态氮含量与N2O排放通量之间呈显著负线性相关.     

浅谈原子吸收分光光度计在环境监测中的应用

本文介绍了原子吸收分光光度计在环境监测中的应用情况和重要性。分析了原子吸收光度法（包括石墨炉法）与ICP-AES（电感偶合等离子体发射光谱法），原子荧光法，极谱法在分析元素时各自的优缺点，又从目前环境监测的角度阐述了应用原子吸收分光度计的重要性与现实性。分析了原子吸收分光广度计在使用中的常见问题及原子吸收分光广度法分析中常出现的问题（从仪器、方法角度分别讲述）。并提出了原子吸收分光度计要进一步应适应环境监测的需求。     

地理变异系数法和Fisher最优分割法在环境空气监测优化布点中的应用

在环境空气监测点位优化中,为反映优化后点位的整体代表性,需要在允许的测定误差内以最少的测点反映区域内较长时期的整体污染水平、污染分布状况和污染趋势.本文以博山城区为例,利用地理变异系数法和Fisher最优分割法对所布设点位进行数理统计.该方法使用简便,分级自然,避免了诸多人为因素的影响,同时,优选结果具有较强的整体代表性.     

景观水治理中存在问题及优化方案

有些景观水域(人工湖、河)采用宏观粗放的生态法治理取得了较好的效果,但也有一些景观水由于简单地套用宏观生态法进行水质维持,反而使亲水区域减少、蚊蝇滋生、水生植物生长失控、水体混白、清塘困难等不利影响.为此,建议采用造流复氧强化、微观生态系统功能,可以取得较好的效果.