Fugitive dust emission source profiles and assessment of selected control strategies for particulate matter at gravel processing sites in Taiwan

Particles emitted from gravel processing sites are one contributor to worsening air quality in Taiwan. Major pollution sources at gravel processing sites include gravel and sand piles, unpaved roads, material crushers, and bare ground. This study analyzed fugitive dust emission characteristics at each pollution source using several types of particle samplers, including total suspended particulates (TSP), suspended particulate (PM10), fine suspended particulate (PM2.5), particulate sizer, and dust-fall collectors. Furthermore, silt content and moisture in the gravel were measured to develop particulate emission factors. The results showed that TSP (< 100 microm) concentrations at the boundary of gravel sites ranged from 280 to 1290 microg/m3, which clearly exceeds the Taiwan hourly air quality standard of 500 microg/m3. Moreover, PM10 concentrations, ranging from 135 to 550 microg/m3, were also above the daily air quality standard of 125 microg/m3 and approximately 1.2 and 1.5 times the PM2.5 concentrations, ranging from 105 to 470 microg/m3. The size distribution analysis reveals that mass mean diameter and geometric standard deviation ranged from 3.2 to 5.7 microm and from 2.82 to 5.51, respectively. In this study, spraying surfactant was the most effective control strategy to abate windblown dust from unpaved roads, having a control efficiency of approximately 93%, which is significantly higher than using paved road strategies with a control efficiency of approximately 45%. For paved roads, wet suppression provided the best dust control efficiencies ranging from 50 to 83%. Re-vegetation of disturbed ground had dust control efficiencies ranging from 48 to 64%.     

Constructed wetlands as a component of the agricultural landscape: mitigation of herbicides in simulated runoff from upland drainage areas

Constructed wetlands are a recommended practice for buffering pollutant source areas and receiving waters. A wetland consisting of a sediment trap and two treatment cells was constructed in a Mississippi Delta lake watershed. A 3-h simulated runoff event was initiated (2003) to evaluate fate and transport of atrazine and fluometuron through the wetland. Water samples were collected during a runoff simulation and then afterward at selected intervals for 21 d, and analyzed for the herbicides. Breakthrough patterns for herbicide concentrations in water samples during the first 20 h after simulated runoff showed peak concentrations in the first 6 h, with gradual tailing as the herbicide pulse was diluted in the second, excavated (deeper) cell. Atrazine and fluometuron concentrations in the first (shallower, non-excavated) cell averaged 12- and 20-fold greater, respectively, than those in the second cell following simulated runoff, indicating entrapment in the first cell. Atrazine and fluometuron concentrations in the shallower cell decreased 32% and 22%, respectively, 9 d following simulated runoff, indicating either degradation or sorption to soil or wetland flora. In the excavated cell, concentrations were even lower, and atrazine declined more rapidly than fluometuron. Results indicate constructed wetlands can improve downstream water quality though sequestration or processing of pollutants.     

A study on dynamic volatile organic compound emission characterization of water-based paints

Volatile organic compounds (VOCs) emitted from surface coatings have caused growing public concern for air quality. Even the low-emitted VOC impact from water-based paints on indoor air quality in urban areas has caused concern. This paper presents experimental data using a mathematical model to simulate dynamic VOC emissions from water-based paints that is based on mass transfer and molecular diffusion theories. A series of field-analogous experiments were carried out to continuously measure the VOCs emitted from two typical water-based paints using a gas chromatography-flame-ionization detector monitor in an artificial wind tunnel system. In the study cases, the mass flux of VOCs emitted from the water-based paints was up to 50 microg/m2sec. It was found that the time needed to completely emit VOCs from water-based paints is just hundreds of seconds. However, the order of magnitude of the VOC emission rate from water-based paints is not lower than that from some dry building materials and solvent-based paints. The experimental data were used to produce a useful semiempirical correlation to estimate the VOC emission rates for water-based paints. This correlation is valid under appropriate conditions as suggested by this work with a statistical deviation of +/- 7.6%. With this correlation, it seems feasible to predict the dynamic emission rates for VOCs during a painting process. This correlation is applicable for assessing the hazardous air pollutant impact on indoor air quality or for environmental risk assessment. Associated with the dynamic VOC emission characterization, the air-exchange rate effect on the VOC emission rates is also discussed.     

Nitrogen fluxes through unsaturated zones in five agricultural settings across the United States

The main physical and chemical controls on nitrogen (N) fluxes between the root zone and the water table were determined for agricultural sites in California, Indiana, Maryland, Nebraska, and Washington from 2004 to 2005. Sites included irrigated and nonirrigated fields; soil textures ranging from clay to sand; crops including corn, soybeans, almonds, and pasture; and unsaturated zone thicknesses ranging from 1 to 22 m. Chemical analyses of water from lysimeters and shallow wells indicate that advective transport of nitrate is the dominant process affecting the flux of N below the root zone. Vertical profiles of (i) nitrogen species, (ii) stable isotopes of nitrogen and oxygen, and (iii) oxygen, N, and argon in unsaturated zone air and correlations between N and other agricultural chemicals indicate that reactions do not greatly affect N concentrations between the root zone and the capillary fringe. As a result, physical factors, such as N application rate, water inputs, and evapotranspiration, control the differences in concentrations among the sites. Concentrations of N in shallow lysimeters exhibit seasonal variation, whereas concentrations in lysimeters deeper than a few meters are relatively stable. Based on concentration and recharge estimates, fluxes of N through the deep unsaturated zone range from 7 to 99 kg ha(-1) yr(-1). Vertical fluxes of N in ground water are lower due to spatial and historical changes in N inputs. High N fluxes are associated with coarse sediments and high N application rates.     

Reduced mercury deposition in New Hampshire from 1996 to 2002 due to changes in local sources

Changes in deposition of gaseous divalent mercury (Hg(II)) and particulate mercury (Hg(p)) in New Hampshire due to changes in local sources from 1996 to 2002 were assessed using the Industrial Source Complex Short Term (ISCST3) model (regional and global sources and Hg atmospheric reactions were not considered). Mercury (Hg) emissions in New Hampshire and adjacent areas decreased significantly (from 1540 to 880 kg yr⁻¹) during this period, and the average annual modeled deposition of total Hg also declined from 17 to 7.0 μg m⁻² yr⁻¹ for the same period. In 2002, the maximum amount of Hg deposition was modeled to be in southern New Hampshire, while for 1996 the maximum deposition occurred farther north and east. The ISCST3 was also used to evaluate two future scenarios. The average percent difference in deposition across all cells was 5% for the 50% reduction scenario and 9% for the 90% reduction scenario.     

Removal of phenylurea herbicide monuron via riboflavin-mediated photosensitization

Photodegradation of the phenylurea herbicide monuron by using riboflavin (Rf), a sensitizer, was investigated by varying the doses of monuron and Rf in this work. An enhanced photochemical effect was observed in the process compared with the direct photolysis by using UV irradiation only. The reaction time was greatly shortened from more than 60 min (direct photolysis) to 8-30 min depending on the doses of initial concentration of monuron ([M]0) and Rf. A modified hyperbola model was found to be useful to determine the reaction kinetics and thereafter the performance on the photodegradation of monuron sensitized by Rf. Two measurable characteristic constants (initial decay rate and total removal index) were used to quantify the reaction. The maximum removal difference compared with the direct photolysis and Rf-sensitization was investigated. It was found that the improvement of the process depended on both the [M]0 and the doses of Rf.     

Assessment of PM10 Enhancement by Yellow Sand on the Air Quality of Taipei, Taiwan in 2001

The impact of long-range transport of yellow sand from Asian Continent to the Taipei Metropolitan Area (Taipei) not only deteriorates air quality but also poses health risks to all, especially the children and the elderly. As such, it is important to assess the enhancement of PM₁₀ during yellow sand periods. In order to estimate PM₁₀ enhancement, we adopted factor analysis to distinguish the yellow-sand (YS) periods from non-yellow-sand (NYS) periods based on air quality monitoring records. Eight YS events were identified using factor analysis coupling with an independent validation procedure by checking background site values, examining meteorological conditions, and modeling air mass trajectory from January 2001 to May 2001. The duration of each event varied from 11 to 132 h, which was identified from the time when the PM₁₀ level was high, and the CO and NO _x levels were low. Subsequently, we used the artificial neural network (ANN) to simulate local PM₁₀ levels from related parameters including local gas pollutants and meteorological factors during the NYS periods. The PM₁₀ enhancement during the YS periods is then calculated by subtracting the simulated PM₁₀ from the observed PM₁₀ levels. Based on our calculations, the PM₁₀ enhancement in the maximum hour of each event ranged from 51 to 82%. Moreover, in the eight events identified in 2001, it was estimated that a total amount of 7,210 tons of PM₁₀ were transported by yellow sand to Taipei. Thus, in this study, we demonstrate that an integration of factor analysis with ANN model could provide a very useful method in identifying YS periods and in determining PM₁₀ enhancement caused by yellow sand.     

Recovery of mercury-contaminated fisheries

In this paper, we synthesize available information on the links between changes in ecosystem loading of inorganic mercury (Hg) and levels of methylmercury (MeHg) in fish. Although it is widely hypothesized that increased Hg load to aquatic ecosystems leads to increases in MeHg in fish, there is limited quantitative data to test this hypothesis. Here we examine the available evidence from a range of sources: studies of ecosystems contaminated by industrial discharges, observations of fish MeHg responses to changes in atmospheric load, studies over space and environmental gradients, and experimental manipulations. A summary of the current understanding of the main processes involved in the transport and transformation from Hg load to MeHg in fish is provided. The role of Hg loading is discussed in context with other factors affecting Hg cycling and bioaccumulation in relation to timing and magnitude of response in fish MeHg. The main conclusion drawn is that changes in Hg loading (increase or decrease) will yield a response in fish MeHg but that the timing and magnitude of the response will vary depending of ecosystem-specific variables and the form of the Hg loaded.     

Assessment of influential range and characteristics of fugitive dust in limestone extraction processes

Fugitive dust emission from limestone extraction areas is a significant pollution source. The cracking operation in limestone extraction areas easily causes high total suspended particulate (TSP) concentrations in the atmosphere, occasionally exceeding the 1-hr national emission standard of Taiwan (500 microg/m3). The concentration and size distribution were measured at different distances (0.05-15 km) in the extraction areas. The highest hourly concentrations of TSP, PM10 (suspended particulate matter [PM] smaller than 10 microm), and PM2.5 (suspended PM smaller than 2.5 microm) are 1111, 825, and 236 microg/m3, respectively, during the cracking process. Measurement results obtained from the Micro-Orifice Uniform Deposit Impactor indicated that the mass median aerodynamic diameter is approximately 0.7 microm, with the geometric standard deviation exceeding 7. In addition, the emission factors are 0.143 and 0.211 kg/t for both vertical well and stair extraction operations, respectively. Experimental results demonstrate that the corresponding TSP control efficiencies for spraying water, planting grass, setting short walls, paving gravel roads, and establishing vertical well transportation are approximately 55, 50, 44, 22, and 30%, respectively. Furthermore, the PM10 control efficiencies are approximately 45, 41, 54, 35, and 30%, respectively, whereas the PM2.5 control efficiencies are roughly 23, 31, 15, 11, and 10%, individually.     

Public health assessment of hexachlorobenzene

Recently, hexachlorobenzene (HCB) was proposed for inclusion in the system of toxicity equivalency factors (TEFs) currently used for dioxin-like compounds. In this paper, we explore the practical implications of the proposition to the Agency for Toxic Substances and Disease Registry (ATSDR) programs by comparing respective health guidance values for 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) and HCB (expressed as total toxicity equivalents [TEQs]), reviewing possible interactions between HCB and dioxin-like chemicals, and by providing information on actual co-existence of HCB and dioxin-like chemicals at hazardous waste sites. We found a good correlation between the TEF-adjusted oral exposure guidance values for HCB and guidance values for TCDD. The combination of HCB and other dioxin-like compounds was not found in soil, air, or water media at hazardous waste sites. Based on this fact, it is not necessary to include HCB in the total TEQ count at hazardous waste sites at this time.