复合型CoO/TiO2光催化剂降解亚甲基蓝动力学研究

以钛酸四丁酯为前驱体,采用溶胶凝胶法,制备了CoO掺杂的TiO2光催化剂。利用X射线衍射（XRD）、扫描电镜（SEM）、透射电镜（TEM）、紫外可见漫反射（UV-vis DRS）对催化剂进行了分析、表征。以中压汞灯为光源,研究了亚甲基蓝（MB）在CoO/TiO₂微粒水悬浮液中的降解动力学。结果表明：所制备的催化剂活性组分主要是锐钛矿型的二氧化钛和CoO固溶体,粒径为25～30 nm,分布均匀。亚甲基蓝的光催化降解动力学满足一级动力学,在一定的浓度范围内,反应速率常数随初始浓度增大而减少,适当的掺钴量可以有效地提高TiO₂光催化活性,其最佳掺杂量重量百分比为0.25%。     

Bioconversion of dairy manure by black soldier fly (Diptera: Stratiomyidae) for biodiesel and sugar production

Modern dairies cause the accumulation of considerable quantity of dairy manure which is a potential hazard to the environment. Dairy manure can also act as a principal larval resource for many insects such as the black soldier fly, Hermetia illucens. The black soldier fly larvae (BSFL) are considered as a new biotechnology to convert dairy manure into biodiesel and sugar. BSFL are a common colonizer of large variety of decomposing organic material in temperate and tropical areas. Adults do not need to be fed, except to take water, and acquired enough nutrition during larval development for reproduction. Dairy manure treated by BSFL is an economical way in animal facilities. Grease could be extracted from BSFL by petroleum ether, and then be treated with a two-step method to produce biodiesel. The digested dairy manure was hydrolyzed into sugar. In this study, approximately 1248.6 g fresh dairy manure was converted into 273.4 g dry residue by 1200 BSFL in 21 days. Approximately 15.8 g of biodiesel was gained from 70.8 g dry BSFL, and 96.2 g sugar was obtained from the digested dairy manure. The residual dry BSFL after grease extraction can be used as protein feedstuff.     

Reprint of: Concentrations, distribution, and bioaccumulation of synthetic musks in the Haihe River of China

Seven typical synthetic musks (SMs) in the samples from the surface water, sediment and fish of the Haihe River were measured. The SM concentrations in the sediment and surface water of the Haihe River were significantly lower than those in the Dagu Drainage River and Chentaizi Drainage River (p < 0.05). Along the flow direction, the SM concentrations in surface water and sediment tended to increase from the upstream to the downstream of Dagu Drainage River. The Bioaccumulation factors (BAFs) of galaxolide (HHCB) and tonalide (AHTN) were calculated at high levels in the muscles of crucian carp, common carp, and silver carp. Most of the biota-sediment accumulation factors (BSAFs) for HHCB and AHTN were higher than 1.7, suggesting magnification possibly exist in the musk bioaccumulations of the three fishes in the Haihe River. No significant differences in HHCB/AHTN ratios were observed among the water, fish, and sediment samples (p > 0.05). However, the HHCB/AHTN values in the Haihe River were much lower than those in the Dagu Drainage River and Chentaizi Drainage River (p < 0.05). Compared with several typical persistent organic pollutants (POPs), the musk concentrations were higher or comparable in the Haihe River.     

巢湖低温高效聚磷菌的筛选及其特性

采用低温富集培养及混合平板分离技术,从巢湖底泥中分离筛选得到2株在低温下仍具有较高效能的菌株D3、D6,经过厌氧/好氧交替培养,2种菌株在低温下(8℃)的除磷率均达到80%以上。在低温下,研究了p H、微量元素对2株菌株生长及除磷率的影响,实验结果表明,2株菌都具有广泛的温度适应性,适宜其生长和除磷的p H为中性偏碱,微量元素的缺乏对2株菌株的生长和除磷效果有不同程度的不良影响。染色观察显示,厌氧培养时菌体内聚羟基丁酸(PHB)颗粒明显增多,转为好氧培养后异染颗粒增多,为典型的聚磷菌特征。经鉴定,2株菌均属假单胞菌属。     

一种新型铋基光催化剂的合成及其可见光催化性能

采用水热法合成铋基光催化剂Bi4VO8Br,通过X-射线粉末衍射、扫描电镜等手段对其进行表征.选择甲基橙为目标降解物来评价不同条件下合成的Bi4VO8Br在可见光下的光催化活性,发现pH 3、反应时间15 h、反应温度160℃为材料水热合成的最佳条件.考察了Bi4VO8Br在可见光及紫外光下对几种农药和增塑剂的光催化降解性能,显示了Bi4VO8Br对不易光解的含苯环有机物的可见光高活性.五氯酚的光催化过程影响因素优化结果表明,可见光和紫外光分别照射120 min和20 min,其降解率分别达到97％和99％,Bi4VO8Br表面上活性基团的捕获即空穴的氧化作用是主要反应原理.     

EGSB出水回流对EGSB—SBR工艺处理果汁废水的影响

采用EGSB—SBR工艺处理实际果汁废水(COD 2 608~6 500 mg/L,p H 5.0~7.0)。在EGSB反应器成功启动及驯化完成的情况下,连续运行49 d。实验结果表明:第25天起,控制EGSB回流比为3.00∶1,EGSB反应器可在无须添加Na HCO3的条件下稳定运行,从而降低了废水处理成本;第25天起,平均进水COD,BOD5,SS分别为5 968,2 130,1 020 mg/L,平均出水COD,BOD5,SS分别降至131,11,50 mg/L,平均COD,BOD5,SS去除率分别为98%,99%,95%;组合工艺对该实际果汁废水具有良好的处理效果。     

喀纳斯自然保护区生态系统服务价值变化研究

生态系统可持续发展是随着全球范围内可持续发展研究的深入和人们对环境破坏和资源利用认识的不断加深而逐渐形成的.人类社会的可持续发展从根本上取决于生态系统及其服务的可持续性,本文应用喀纳斯自然保护区1980、2005年两期Landsat TM影像解译数据,参照谢高地等制定的中国生态系统单位面积生态服务当量因子和新疆布尔津县单位面积农田生态系统提供的食物生产服务的经济价值,确定喀纳斯自然保护区生态系统单位面积生态服务价值系数,对保护区生态系统服务价值及其变化进行了估算和比较.结果表明,林地和草地是喀纳斯自然保护区主要的土地利用类型,25年间土地利用总体上发生了明显变化,林地面积在减少,革地、水域、建设用地面积略有增加;保护区生态系统服务价值由1980年的37.289亿元减少至2005年的36.351亿元,有林地和离覆盖度草地的减少是服务价值降低的主要原因;主要由林地、草地和水域提供的维持生物多样性、水文调节、气候调节、保持土壤等单项功能服务价值均呈现不同程度地减少,说明保护区生态系统结构和功能已受到影响,保护区生态环境质量不断趋向退化.     

贵州喀斯特土石山区水土保持生态经济型植被恢复模式

以贵州省喀斯特土石山区为例,通过总结前人的研究成果和中国科学院亚热带农业生态研究所喀斯特生态实验站的部分试验数据,从全局性、紧迫性、高效性、层次性、可持续性、创新性与多样性的角度提出了在贵州喀斯特土石山区的急坡地、陡坡地、缓陡坡地其水土保持生态经济型植被恢复模式分别采用3种典型模式,即:灌草模式,乔灌草模式与林果模式,以期促进该区域的生态、经济与社会的全面协调与可持续发展。     

完善我国医疗废物集中处置收费政策的思考和建议

医疗废物处置收费政策是医疗废物处置产业化发展的重要前提和保障。当前,医疗废物处置收费政策执行难,欠费、漏费等问题非常突出,医疗废物集中收集十分困难。在对我国医疗废物处置收费政策进行全面分析和评估的基础上,对当前收费政策存在的主要问题和产生的原因进行了分析。以加快完善医疗废物处置收费政策为目标,从完善政策体系、加强监管执法、提高标准合理性、综合确定费用承担方、制定鼓励性的经济政策、提高宣传和缴费意识等方面,提出医疗废物处置收费政策改革完善的若干建议。     

Investigation of PM2.5 pollution during COVID-19 pandemic in Guangzhou, China

The COVID-19 pandemic has raised awareness about various environmental issues,including PM_2.5 pollution.Here,PM_2.5 pollution during the COVID-19 lockdown was traced and analyzed to clarify the sources and factors influencing PM_2.5 in Guangzhou,with an emphasis on heavy pollution.The lockdown led to large reductions in industrial and traffic emissions,which significantly reduced PM_2.5 concentrations in Guangzhou.Interestingly,the trend of PM_2.5