气相色谱法测定水和废水中丙烯腈

本文通过采用气相色谱法，以ＧＤＸ－５０２为固定相，ＦＩＤ为检测器测定水和废水中的丙烯腈，精密度和回收率高．方法简便易行，能满足行业废水和地面水的监队是水和废水中丙烯腈分析的较理想方法。     

缙云山银木荷(Schima argentea Pritz.ex Diels)林物种组成与多样性变化

定位研究了25a来缙云山银木荷林物种组成及多样性在自然演替过程中的动态变化。结果表明,银木荷林维管植物物种由57种(隶属于24科,46属)减少到38种(隶属于19科,26属)。林下草本和层间植物逐渐消失,胸径大于7.5cm的乔木层树总胸断面积有所减少。尽管群落物种组成以及多样性发生改变,但是银木荷依然是优势树种,处于林冠层,而林冠亚层的白毛新木姜子、四川山矾、长蕊杜鹃逐渐增多,短刺米槠逐渐减少。群落乔木层4个α多样性指数都呈下降趋势,丰富度指数由2.98下降为1.99,Shannon-Wiener指数25a间减小了0.34,Simpson指数和Pielou指数变化都很小;β多样性分析结果显示,银木荷群落的物种差异很大。研究表明,25a间群落物种差异显著。揭示缙云山银木荷林自然演替过程中的物种组成和多样性变化规律,可为缙云山保护区及长江流域中上游亚热带常绿阔叶林的银木荷群落的管理提供一定的参考价值。     

Assessment of potential dermal and inhalation exposure of workers to the insecticide imidacloprid using whole-body dosimetry in China

In China, although improvements to the pesticide registration process have beenmade in last thirty years, no occupational exposure data are required to obtain a commercial license for a pesticide product. Consequently, notably little research has been conducted to establish an exposure assessment procedure in China. The present study monitored the potential dermal operator exposure from knapsack electric sprayer wheat field application of imidacloprid in Liaocheng City, Shandong Province and in Xinxiang City, Henan Province, China, using whole-body dosimetry. The potential inhalation exposure was determined using a personal air pump and XAD-2 sample tubes. The analytical method was developed and validated, including such performance parameters as limits of detection and quantification, linear range, recovery and precision. The total potential dermal and inhalation exposures were 14.20, 16.80, 15.39 and 20.78 mL/hr, respectively, for the four operators in Liaocheng and Xinxiang, corresponding to 0.02% to 0.03% of the applied volume of spray solution. In all trials, the lower part (thigh, lower leg) of the body was the most contaminated, accounting for approximately 76% to 88% of the total exposure. The inhalation exposure was less than 1% of the total exposure. Such factors as the application pattern, crop type, spray equipment, operator experience and climatic conditions have been used to explain the exposure distribution over the different parts of the body. As indicated by the calculated Margin of Exposure, the typical wheat treatment scenarios when a backpack sprayer was used are considered to be safe in terms of imidacloprid exposure.     

A 1-dodecanethiol-based phase transfer protocol for the highly efficient extraction of noble metal ions from aqueous phase

A 1-dodecanethiol-based phase-transfer protocol is developed for the extraction of noble metal ions from aqueous solution to a hydrocarbon phase, which calls for first mixing the aqueous metal ion solution with an ethanolic solution of 1-dodecanethiol, and then extracting the coordination compounds formed between noble metal ions and 1-dodecanethiol into a non-polar organic solvent. A number of characterization techniques, including inductively coupled plasma atomic emission spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis demonstrate that this protocol could be applied to extract a wide variety of noble metal ions from water to dichloromethane with an efficiency of >96%, and has high selectivity for the separation of the noble metal ions from other transition metals. It is therefore an attractive alternative for the extraction of noble metals from water, soil, or waste printed circuit boards.     

Mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor

In this study, the mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor were investigated through thermal decomposition methods. The results show that the mercury adsorption performance of the HBr-modified fly ash was enhanced significantly. The mercury species adsorbed by unmodified fly ash were HgCl₂, HgS and HgO. The mercury adsorbed by HBr-modified fly ash, in the entrained-flow reactor, existed in two forms, HgBr₂ and HgO, and the HBr was the dominant factor promoting oxidation of elemental mercury in the entrained-flow reactor. In the current study, the concentration of HgBr₂ and HgO in ash from the fine ash vessel was 4.6 times greater than for ash from the coarse ash vessel. The fine ash had better mercury adsorption performance than coarse ash, which is most likely due to the higher specific surface area and longer residence time.     

Winter survival of microbial contaminants in soil:An in situ verification

The aim of the research was to evaluate, at site scale, the influence of freezing and freeze/thaw cycles on the survival of faecal coliforms and faecal enterococci in soil, in a climate change perspective. Before the winter period and during grazing, viable cells of faecal coliforms and faecal enterococci were detected only in the first 10 cm below ground, while,after the winter period and before the new seasonal grazing, a lower number of viable cells of both faecal indicators was detected only in some of the investigated soil profiles, and within the first 5 cm. Taking into consideration the results of specific investigations, we hypothesise that the non-uniform spatial distribution of grass roots within the studied soil can play an important role in influencing this phenomenon, while several abiotic factors do not play any significant role. Taking into account the local trend in the increase of air temperature, a different distribution of microbial pollution over time is expected in spring waters, in future climate scenarios. The progressive increase in air temperature will cause a progressive decrease in freeze/thaw cycles at higher altitudes, minimising cold shocks on microbial cells, and causing spring water pollution also during winter.     

Towards a new climate economics:research areas and prospects

International cooperation to address climate change now stands at a crossroads.With a new international regime for emissions reduction established by the Durban Platform, "New Climate Economics(NCE)" has become a research hotspot.The need for urgent action to combat climate change has prompted discussion on reforms of economic growth patterns and the energy system.The industrial civilization,therefore,now faces a transition towards a new pathway for ecological sustainability.NCE explores new economic concepts,theories,and analytical methods to design a balanced pathway for sustainable growth and emission reduction.Instead of getting trapped in discussions on allocation of emission reduction responsibilities and obligations among countries,NCE pays more attention to developing win-win multilateral cooperation mechanisms that facilitate collaborative RD and knowledge sharing.In addition,NCE studies incentives for low-carbon transition,turning carbon emission reduction into a domestic need for countries to increase their international competitiveness.To achieve the 2°C target,most countries around the world face challenges of insufficient emission allowances to cover expected emissions associated with their projected economic growth.As carbon emissions rights becomes an increasingly scarce resource,increasing the carbon productivity of the economy turns to be the critical path to address the dilemma of green or growth.NCE studies the historical evolution of carbon productivity for countries at different development stages as well as ways to enhance such carbon productivity.This type of study provides invaluable lessons for emerging economies to reach their own emission peaks without losing the momentum of growth.Replacing fossil fuels with new and renewable energy has proven to be an inevitable choice for reshaping the energy system and addressing climate change- it has already become a global trend.NCE studies incentives for new energy technology innovation and deployment provided by carbon pricing,and sheds light on the co-benefits of climate change mitigation,such as resource conservation,environmental protection,and energy security.The role of carbon pricing in promoting intemational RD cooperation and technical transfer will also be studied.The shift in consumption patterns is another key factor enabling a low-carbon transformation.Therefore,NCE also explores the theoretical work on new values of wealth,welfare and consumption,new lifestyles in the context of ecological civilization,concepts and implementation of low-carbon urban planning in developing countries,and the impacts of consumption pattern changes on social development,material production,and urban infrastructure construction.     

滁州地区覆盖层厚度对场地地震动参数的影响

以滁州地区近百个钻孔资料为原型建立土层模型,采用一维频域等效线性化波动方法进行了土层地震反应分析,重点分析了覆盖层厚度对场地地震动参数的影响。研究结果表明,随着覆盖层厚度的增加,地表峰值加速度及土层放大系数逐渐增大,当覆盖层厚度超过一定值时,地表峰值加速度及土层放大系数呈逐渐缓慢减小的趋势;而反应谱特征周期总体上随着覆盖层厚度的增加而逐渐增大。     

基于致灾因子指标体系的海冰灾害风险评估和区划方法

中国是世界上受海冰危害严重的国家之一,历史上曾发生过多次严重海冰灾害,造成重大损失。根据我国结冰海区海冰灾害风险的自然过程、社会经济状况和成灾机制,综合考虑致灾因子危险性、承灾体分类、分布及脆弱性以及防灾减灾能力等因素,对海冰灾害发生的可能性及其不确定性等进行综合分析,提出了开展海冰灾害风险评估和区划的理论依据,同时给出了利用致灾因子指标体系对海冰灾害风险进行评估和区划的具体方法。