Mechanism of Microbial Degradation of Slow-Release Fertilizers

Methyleneureas are condensation products of urea and formaldehyde of different molecular mass and solubility; they are used in large amounts both as resins, binders, and insulating materials for industrial applications, as well as a slow-release nitrogen fertilizer for greens, lawns, or in bioremediation processes. In the present study, the microbial breakdown of these products was investigated. The nitrogen was released as ammonia and urea, and the formaldehyde released immediately oxidized via formiate to carbon dioxide. The enzymatic mechanism of metabolization of methyleneureas was studied in microorganisms isolated from soil, which were able to use these compounds as the sole source of nitrogen for growth. A strain of the Gram-negative bacterium Ralstonia paucula (formerly Alcaligenes sp. CDC group IVc-2) completely degraded methylenediurea and dimethylenetriurea to urea, ammonia, formaldehyde, and carbon dioxide. The enzyme initiating this degradation (methylenediurease) was purified and turned out to be different from the previously described enzyme from Ochrobactrum anthropi with regard to its regulation of expression and physicobiochemical properties. Fungal degradation of methyleneureas may occur via the formation of organic acids, thus leading to a nonenzymatic degradation of methyleneureas, which are unstable under acidic conditions.     

Salinity as a Limiting Factor for Biological Condition in Mining‐Influenced Central Appalachian Headwater Streams

Recent studies have found that Appalachian coal mining causes increased surface water salinity, and that benthic macroinvertebrate communities in salinized mining‐influenced streams differ from communities in streams draining unmined areas. Understanding the role of salinity in shaping these communities is challenging because such streams are often influenced by a variety of stressors in addition to salinity. We characterized associations of salinity with biotic condition while isolating salinity from other stressors through rigorous site selection. We used a multimetric index of biotic condition to characterize benthic macroinvertebrate communities in headwater streams in the Central Appalachian Ecoregion of Virginia across a gradient of sulfate‐dominated salinity. We found strong negative seasonal correlations between biotic condition and three salinity measures (specific conductance, total dissolved solids, and SO₄^2? concentration). We found no evidence to suggest stressors other than salinity as significant influences on biotic condition in these streams. Our results confirm negative associations of salinity with benthic macroinvertebrate community condition, as observed in other studies. Thus, our findings demonstrate that elevated salinity is an important limiting factor for biological condition in Central Appalachian headwater streams.     

Air pollution and mortality rates: A note on Lave and Seskin's pooling of cross-section and time-series data

In “Air Pollution and Human Health” (Johns Hopkins University Press, Baltimore, 1977) Lester Lave and Eugene Seskin report the results of regressions which suggest a strong association between air pollution and mortality rates. This note questions assumptions made by Lave and Seskin which underlie their -estimation of a single-equation model using pooled cross-section and time-series data. If, in fact, these assumptions cannot be made, the association between air pollution and mortality rates appears considerably weakened, but it still appears to be significant.     

Representation of tourist interest in the Opal Coast by local populations, English and Belgian Dutch-speaking populations

The purpose of the exploratory study is to describe the perception of the “Opal Coast (North of France)” among French native populations or remaining population for tourist reasons. A discussion (a) based on quantitative and qualitative equivalences and differences on perceiving the characteristics and love of the area according to nationality is proposed (b) confronting the perceptions measured of the national stereotypes is evoked, (c) considering the tourist communication in the area as a self confirmation of the identity of the tourist visiting is outlined.     

An LCA model for waste incineration enhanced with new technologies for metal recovery and application to the case of Switzerland

A process model of municipal solid waste incinerators (MSWIs) and new technologies for metal recovery from combustion residues was developed. The environmental impact is modeled as a function of waste composition as well as waste treatment and material recovery technologies. The model includes combustion with a grate incinerator, several flue gas treatment technologies, electricity and steam production from waste heat recovery, metal recovery from slag and fly ash, and landfilling of residues and can be tailored to specific plants and sites (software tools can be downloaded free of charge). Application of the model to Switzerland shows that the treatment of one tonne of municipal solid waste results on average in 425 kg CO₂-eq. generated in the incineration process, and 54 kg CO₂-eq. accrue in upstream processes such as waste transport and the production of operating materials. Downstream processes, i.e. residue disposal, generates 5 kg CO₂-eq. Savings from energy recovery are in the range of 67 to 752 kg CO₂-eq. depending on the assumptions regarding the substituted energy production, while the recovery of metals from slag and fly ash currently results in a net saving of approximately 35 kg CO₂-eq. A similar impact pattern is observed when assessing the MSWI model for aggregated environmental impacts (ReCiPe) and for non-renewable resource consumption (cumulative exergy demand), except that direct emissions have less and no relevance, respectively, on the total score. The study illustrates that MSWI plants can be an important element of industrial ecology as they provide waste disposal services and can help to close material and energetic cycles.