A New Ozonated Cassava Film with the Addition of Cellulose Nanofibres: Production and Characterization of Mechanical,Barrier and Functional Properties

Journal of Polymers and the Environment - In this study cassava starch modified by ozone technology and cellulose nanofibres were used to produce films. These nanocomposites were produced by...     

A power-efficiency trade-off in resource use alters epidemiological relationships

Trade-offs play pivotal roles in the ecology and evolution of natural populations. However, trade-offs are probably not static, invariant relationships. Instead, ecological factors can shift, alter, or reverse the relationships underlying trade-offs and create critical genotype x environment (G x E) interactions. But which ecological factors alter trade-offs or create G x E interactions, and why (mechanistically) do they do this? We tackle these questions using resource quality as the central ecological factor and a case study of disease in the plankton. We show that clonal genotypes of a zooplankton host (Daphnia dentifera) exhibit a "power-efficiency" trade-off in resource use, where powerful (fast-feeding) host clones perform well on richer algal resources, but more efficient (slow-feeding) clones perform relatively well on poorer resources. This resource-based trade-off then influences epidemiological relationships due to fundamental connections between resources and fecundity, transmission rate (an index of resistance), and replication of a virulent fungal parasite (Metschnikowia bicuspidata) within hosts. For instance, using experiments and dynamic energy budget models, we show that the power-efficiency trade-off overturned a previously detected trade-off between fecundity and transmission risk of hosts to this parasite. When poorer resources were eaten, transmission risk and fecundity were negatively, not positively, correlated. Additionally, poor resource quality changed positive relationships between yield of infectious stages (spores) and host fecundity: those fecundity-spore relationships with poor food became negative or nonsignificant. Finally, the power-efficiency trade-off set up an interaction between host clone and resource quality for yield of fungal spores: powerful clones yielded relatively more spores on the better resource, while efficient clones yielded relatively more on the poorer resource. Thus, the physiological ecology of resource use can offer potent, mechanistic insight linking environmental factors to epidemiological relationships.     

Ni-MH spent batteries: a raw material to produce Ni-Co alloys

Ni-MH spent batteries are heterogeneous and complex materials, so any kind of metallurgical recovery process needs a mechanical pre-treatment at least to separate irony materials and recyclable plastic materials (like ABS) respectively, in order to get additional profit from this saleable scrap, as well as minimize waste arising from the braking separation process. Pyrometallurgical processing is not suitable to treat Ni-MH batteries mainly because of Rare Earths losses in the slag. On the other hand, the hydrometallurgical method, that offers better opportunities in terms of recovery yield and higher purity of Ni, Co, and RE, requires several process steps as shown in technical literature. The main problems during leach liquor purification are the removal of elements such as Mn, Zn, Cd, dissolved during the leaching step, and the separation of Ni from Co. In the present work, the latter problem is overcome by co-deposition of a Ni-35/40%w Co alloy of good quality. The experiments carried out in a laboratory scale pilot-plant show that a current efficiency higher than 91% can be reached in long duration electrowinning tests performed at 50 degrees C and 4.3 catholyte pH.     

Duplication of 9 p11.2-p13.1: a benign cytogenetic variant

The detection of very rare variants in prenatal diagnosis often causes counseling difficulties and anxiety in parents. We describe a duplication of the proximal region of chromosome 9 short arm in two cases of prenatal diagnosis and in one young woman, with evidence that such rearrangement is an uncommon variant. The duplication was investigated using Fluorescence in situ hybridization (FISH). Although the cytogenetic findings were indicative of a ‘duplication 9p syndrome’ associated with mental and developmental retardation, we were able to demonstrate that the rearrangement was a heteromorphism with no phenotypic consequence. We also determined the breakpoint regions of the rearrangement and identified the BAC probes that precisely define the duplicated region devoid of risk of phenotypic effects. Copyright © 2004 John Wiley & Sons, Ltd.     

Genetic structure and different color morphotypes suggest the occurrence and bathymetric segregation of two incipient species of Sebastes off Argentina

Rockfishes of the genus Sebastes are extensively distributed in the Pacific and Atlantic oceans. Although the occurrence of two morphologically similar species in the Southern Hemisphere, Sebastes oculatus and Sebastes capensis, is now clearly established, the taxonomic status and phylogeographic patterns for the genus in the region have not yet been completely resolved. In this study, we provide new insights into the taxonomy and evolutionary relationships of rockfishes inhabiting the Southwestern Atlantic Ocean, off the coast of mainland Argentina, by combining mitochondrial DNA (mtDNA) control region sequences, microsatellite data, and color pattern analyses. Differences in coloration (“dark” and “light” fish) together with bathymetric segregation between color morphotypes were evident from fish collection and literature review. In addition, the mtDNA phylogenetic analysis and Bayesian clustering analysis using microsatellite data separated the fish into two distinct groups (F _ST?=?0.041), most likely representing incipient species. Our results suggest that speciation-by-depth in the absence of physical barriers could be a widespread mechanism of speciation in Sebastes from both the Northern and Southern Hemispheres. Nevertheless, the degree of genetic differentiation found, added to the large number of individuals displaying high levels of admixture, points to the occurrence of incomplete reproductive barriers between color morphotypes. Beyond the taxonomic and phylogeographic implications of our findings, the occurrence of distinct groups of Sebastes off the coast of Argentina being targeted by different fisheries (angling and trawling) has consequences for the design and implementation of appropriate fishery regulations to avoid overharvest of either group.     

Influence of flooding and vegetation on carbon, nitrogen, and phosphorus dynamics in the pore water of a Spartina alterniflora salt marsh

Four sites were selected in a salt marsh in the Bah′?a Blanca Estuary (Argentina): (1) low marsh (flooded by the tide twice daily) vegetated by S. alterniflora; (2) non-vegetated low marsh; (3) high marsh (flooded only in spring tides) vegetated by S. alterniflora; (4) non-vegetated high marsh. The pH and Eh were measured in sediments, while dissolved nutrients (ammonium, nitrate, nitrite and phosphate) and particulate organic matter (POM) were determined in pore water. pH (6.2–8.7) was only a ected by vegetation in low areas. Eh (from –300 to 250 mV) was lower at low sites than at high ones; in the latter, the values were higher in the non-vegetated sediments. The POM concentration was greater in the high marsh than in the low marsh, with no e ect of vegetation. Ammonium was the most abundant nitrogen nutrient species in pore water, except in the non-vegetated high marsh where nitrate concentration was higher. All nitrogen nutrients were a ected by both flooding and vegetation. Phosphate was always present in pore water at all sites throughout the year and its concentration varied within narrow limits, with no e ect of flooding and greater values always at non-vegetated sites. Our results showed that the variability of the pore water composition within the marsh is greater than the temporal variation, meaning that both tidal flooding and vegetation are important in the dynamics of nutrients and organic matter in the sediment pore water.     

Fast Preparation of Flexible Wet-Resistant and Biodegradable Films From a Stable Suspension of Xylan/Chitosan Polyelectrolyte Complexes

Journal of Polymers and the Environment - Novel hemicellulose-based films from polyelectrolyte complexes (PECs) of chitosan and xylan from sugar cane bagasse were prepared and characterized. PEC...     

Potentially harmful elements in house dust from Estarreja,Portugal: characterization and genotoxicity of the bioaccessible fraction

Due to their behavioral characteristics, young children are vulnerable to the ingestion of indoor dust, often contaminated with chemicals that are potentially harmful. Exposure to potentially harmful elements (PHEs) is currently exacerbated by their widespread use in several industrial, agricultural, domestic and technological applications. PHEs cause adverse health effects on immune and nervous systems and can lead to cancer development via genotoxic mechanisms. The present study is an integrated approach that aims at assessing the genotoxicity of bioaccessible PHEs following ingestion of contaminated house dust. A multidisciplinary methodology associating chemical characterization of five house dust samples, extraction of the bioaccessible PHEs in gastric extracts by the unified BARGE method, determination of the bioaccessible fraction and in vitro genotoxicity of gastric extracts in adenocarcinoma gastric human (AGS) cells was developed. The five gastric extracts induced dose-dependent genotoxicity in AGS cells. Copper (bioaccessible concentration up to 111 mg/kg) was probably the prevalent PHE inducing primary DNA damage (up to 5.1-fold increase in tail DNA at 0.53 g/l of gastric extract). Lead (bioaccessible concentration up to 245 mg/kg) was the most prevalent PHE inducing chromosome-damaging effects (r = 0.55; p < 0.001 for micronucleated cells induction). The association of principal component analysis and Spearman’s correlations was decisive to understand the chromosome-damaging properties of the bioaccessible PHEs in AGS cells. This methodology could be used on a larger-scale study to provide useful information for science-based decision-making in regulatory policies, and a better estimation of human exposure and associated health risks.     

Current status and future restoration of coastal dune systems on the Catalan shoreline (Spain,NW Mediterranean Sea)

Coastal dunes are an essential part of beach-dune systems. Dunes systems have their own intrinsic values and provide a range of goods and services, including the protection of tangible goods located on the shoreline affected by waves, storms, and sea erosion. Dunes also act as repositories of biodiversity that have their exclusive habitat in dune communities, and the aesthetic value of dune landscapes derived from unique plant communities and landforms is also of great importance. Nevertheless, dune systems on developed coasts suffered a drastic decline in geomorphological and ecological quality throughout the last century. Catalonia (Spain, NW Mediterranean Sea) is no exception, and the coastal dune systems which were present in the early 20th century have now disappeared due to urbanization. The regeneration of dune systems is of crucial importance in this context. The aim of this study is to assess the current status of dune systems in Catalonia in order to determine their future prospects based on beach characteristics, those beaches likely to host dunes being determined according to their width and sediment type. The results of our study show that nowadays most dune systems in Catalonia are not developed due to human pressure on the beaches. Only those beaches located in the natural protected areas in Roses Bay, Baix Ter Bay, the Llobregat Delta, and especially the Ebro Delta, have the right characteristics to host well-developed dune systems. That said, 30% of sandy beaches in Catalonia have a width of over 35 metres; wide enough to host well-developed dune systems if appropriate integrated beach management is applied. The methodology used in this research also provide a tool to assess which are the beaches that can host dunes on other developed shores in the Mediterranean area.     

The Potential of Cleaner Fermentation Processes for Bioplastic Production: A Narrative Review of Polyhydroxyalkanoates (PHA) and Polylactic Acid (PLA)

Journal of Polymers and the Environment - Synthetic plastics generate major problems in landfills after their consumption for occupying high volumes and difficult the decomposition of other organic...