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71.
Carolina Molero Antonio de Lucas Fernando Romero Juan F. Rodríguez 《Journal of Material Cycles and Waste Management》2009,11(2):130-132
Flexible polyurethane foam wastes can be advantageously treated by two-phase glycolysis to recover the polyols with an improved
quality compared to single-phase processes. This reaction has been traditionally catalyzed by alkanolamines, titanium compounds,
or acetates. Recently, the employment of new catalysts based on potassium and calcium octoates has opened up a new way to
catalyze the glycolysis of polyurethanes. In this work, the use of stannous octoate, which has never before been applied in
the glycolysis reactions of polyurethanes, is proposed. The catalytic activity of stannous octoate in such a process was studied.
The decomposition rate and the purity of polyol obtained were greater than those obtained using other catalysts previously
employed for this application. 相似文献
72.
Carlos F. Mena Francisco Laso Patricia Martinez Carolina Sampedro 《Journal of Land Use Science》2017,12(6):477-492
In the Ecuadorian Amazon roads play the major role in transforming land cover. Since the beginning of the oil development in this region, oil exploration and road building have been linked. The objectives of this paper are twofold: First, to present a scenario of future deforestation as result of expanding the oil frontier in the Ecuadorian Amazon until the year 2030. Second, to produce an analysis of possible carbon emission scenarios as results of the deforestation produced. This paper tries to shed light into how the development of new oil concessions impact land associated environmental services. The paper uses spatial explicit simulations, that are based on parameters built using past land transitions from areas that experimented oil development, and that explain possible outcomes in the year 2030 using current and predicted road network. Simulations indicate that under current transition probabilities and a conservative scenario road construction, more than 2 million hectares will be affected, which is 35% of the area covered by concessions, which would release 51 to 148 MT of carbon to the atmosphere. This paper illustrates the strong links between road building and deforestation, where even small amount of road construction can have large effects on land cover. 相似文献
73.
Carolina Millan Simone Silva Borges Daniela Rodrigues Gilson Rudinei Pires Moreira 《Die Naturwissenschaften》2013,100(10):901-911
Interspecific competition in herbivorous insects remains a controversial issue. To date, many studied systems have not met assumptions of the traditional competition theory, and a new paradigm has been emerging. We examined the behavioral and life-history consequences of common host plant use of Heliconius erato and Dryas iulia (Nymphalidae) in relation to Passiflora suberosa (Passifloraceae). Larvae of the former use the apical portion of this host; the latter is presumably able to explore all plant parts. We assessed host use pattern in relation to leaf age, when reared either alone (D. iulia) or together (D. iulia and H. erato). Larval feeding choice tests with respect to leaf age were performed, and performance was recorded. Observations were made to assess antagonistic behavior of H. erato and D. iulia towards each other, if any. Similarly to H. erato, D. iulia fed on the young leaves significantly more than the mature ones; larvae were not induced to prefer mature leaves. First instars of H. erato used only the apical parts of P. suberosa and displayed aggressive behavior towards D. iulia, which moved to the lower shoot portions. Larval mortality and development time of both species significantly increased when reared together; such performance costs were more pronounced in D. iulia than H. erato. Our study gathers evidences that use of P. suberosa by these heliconian butterflies represent a case of competitive exclusion resulting in niche differentiation, where costs are higher for D. iulia than H. erato. 相似文献
74.
The COVID-19 pandemic has escalated into one of the largest crises of the 21st Century. The new SARS-CoV-2 coronavirus, responsible for COVID-19, has spread rapidly all around the world. The Spanish Government was forced to declare a nationwide lockdown in view of the rapidly spreading virus and high mortality rate in the nation. This study investigated the impact of short-term lockdown during the period from March 15th to April 12th 2020 on the atmospheric levels of CO, SO2, PM10, O3, and NO2 over 11 representative Spanish cities. The possible influence of several meteorological factors (temperature, precipitation, wind, sunlight hours, minimum and maximum pressure) on the pollutants' levels were also considered. The results obtained show that the 4-week lockdown had significant impact on reducing the atmospheric levels of NO2 in all cities except for the small city of Santander as well as CO, SO2, and PM10 in some cities, but resulted in increase of O3 level. 相似文献
75.
de Araujo Helder F. P. Machado Célia C. C. Alves Ana Carolina Flores da Costa Lima Mônica da Silva José Maria Cardoso 《Mitigation and Adaptation Strategies for Global Change》2022,27(8):1-18
Mitigation and Adaptation Strategies for Global Change - All Clean Development Mechanism (CDM) projects are designed to contribute to the sustainable development of the host country. Livelihood is... 相似文献
76.
Iglesias A Nebot C Miranda JM Vázquez BI Cepeda A 《Environmental science and pollution research international》2012,19(8):3235-3249
Introduction
The use of veterinary drugs in food production focuses on the control and improvement of animal health. The disadvantage of this practice is that pharmaceuticals and their metabolites are released into the environment, finding their way to natural water systems and becoming a potential risk to non-target organism.Methods
This paper reports the development and validation of a quantitative method, based on high-performance liquid chromatography coupled to tandem mass spectrometry, for the simultaneous analysis of 21 veterinary drugs, antimicrobials, corticosteroids, coccidiostats and antifungal agents, in surface water.Results
The precision of the method was established by calculating the mean recoveries, which were in the range of 94?C101%. The developed method was employed to conduct the first monitoring study on the presence of veterinary drugs in the Galicia region, Northwest of Spain and was applied to 235 surface water samples. Eleven veterinary drugs were detected at concentrations from below the limit of quantification to 2,978.6?ng?L?1. Limits of detection and quantification were in the range of 6.2 (betamethasone, cortisone, decoquinate, dexamethasone, maduramycin, monensin, narasin, salinomycin, sulfachloropyridazine, sulfamethoxypyridazine and trimethoprim) to 12.5?ng?L?1 (for the rest of the selected drugs) and 12.5 (betamethasone, cortisone, decoquinate, dexamethasone, maduramycin, monensin, narasin, salinomycin, sulfachloropyridazine, sulfamethoxypyridazine and trimethoprim) to 25.0?ng?L?1 (for the remaining pharmaceuticals), respectively.Conclusion
Sulfonamides were the group most frequently found, which are widely used in veterinary medicine. 相似文献77.
78.
Lastre-Acosta Arlen Mabel Rocha Carolina Mendes Mendes Maria Anita Teixeira Antonio Carlos Silva Costa do Nascimento Claudio Augusto Oller 《Environmental science and pollution research international》2022,29(28):42231-42241
Environmental Science and Pollution Research - Polychlorinated biphenyls (PCBs) are a family of highly toxic, resistant, and persistent organic pollutants, among which 2-chlorobiphenyl (PCB-1) is... 相似文献
79.
Delgado-Alvarez Carolina Guadalupe Ruelas-Inzunza Jorge Osuna-Martínez Carmen Cristina Bergés-Tiznado Magdalena Elizabeth Escobar-Sánchez Ofelia Ocampo-Rodríguez Pedro Octavio Soto-Romero Karen Lizbeth Garzón-Raygoza Nancy Lorena Aguilar-Júarez Marisela Osuna-López José Isidro Frías-Espericueta Martín 《Environmental science and pollution research international》2021,28(9):10909-10917
Environmental Science and Pollution Research - Mercury and selenium concentrations and Se:Hg molar ratio in edible muscle and hepatopancreas of the crab Callinectes arcuatus from coastal lagoons of... 相似文献
80.
Bernardo Alves de Lima Pedro Paulo Rocha de Castro Alexandre Boscaro França Eduardo Prado Baston Renata Carolina Zanetti Lofrano Gisella Rossana Lamas Samanamud Carla Cristina Almeida Loures Luzia Lima Rezende Naves Fabiano Luiz Naves 《Environmental monitoring and assessment》2018,190(9):560
Ozone and a Fe2+/TiO2-based catalyst were examined in the degradation of a synthetic solution of benzene toluene and xylene (BTX) in an advanced oxidation process (AOP). The catalyst beads were made from the slurry waste of aluminum production process, by inserting the TiO2 content and subsequent calcination. The reduction of the BTX concentration load was monitored by the reduction of chemical oxygen demand (COD) and BTX concentration. Different levels were used on factors: pH, time of treatment, initial concentration of BTX, and percentage of TiO2. The process was conducted in a bubble column reactor with the insertion of catalyst beads. A response surface methodology technique (CCD) was used to build a model based on COD reduction results. The model was optimized using the normal-boundary intersection (NBI) algorithm to maximize COD reduction and minimize the variance attributed to the process. Optimization led to COD reductions of 80% in 2 h of experiment. Correlation analysis of coefficient models from experimental data R2adj was 0.9966, showing a good fit of model data. In the optimized conditions, the possible increase of the biodegradability ratio of the BTX solution, through the biochemical oxygen demand (BOD) and COD, was also analyzed. Under pre-treatment conditions, the BOD/COD ratio was 0.13. After the treatment, it increased to 0.56. 相似文献