Dignity,face, and honor cultures: A study of negotiation strategy and outcomes in three cultures

This study compares negotiation strategy and outcomes in countries illustrating dignity, face, and honor cultures. Hypotheses predict cultural differences in negotiators' aspirations, use of strategy, and outcomes based on the implications of differences in self‐worth and social structures in dignity, face, and honor cultures. Data were from a face‐to‐face negotiation simulation; participants were intra‐cultural samples from the USA (dignity), China (face), and Qatar (honor). The empirical results provide strong evidence for the predictions concerning the reliance on more competitive negotiation strategies in honor and face cultures relative to dignity cultures in this context of negotiating a new business relationship. The study makes two important theoretical contributions. First, it proposes how and why people in a previously understudied part of the world, that is, the Middle East, use negotiation strategy. Second, it addresses a conundrum in the East Asian literature on negotiation: the theory and research that emphasize the norms of harmony and cooperation in social interaction versus empirical evidence that negotiations in East Asia are highly competitive. Copyright © 2016 John Wiley & Sons, Ltd.     

Speciation and surface structure of inorganic arsenic in solid phases: a review

Accurate determination of individual arsenic species is critical because the toxicology, mobility, and adsorptivity of arsenic vary substantially with its chemical forms and oxidation states. Separation techniques together with techniques for chemical identification make it possible to determine the combinational forms and oxidation states of arsenic in solid phases. Selective sequential extraction is often employed to determine operationally defined fractions, but it has a poor precision and selectivity. Direct methods, based on X-ray techniques and vibrational spectroscopy, have been developed to analyze the valence, local coordination, protonation, and other properties of arsenic in solid phases. Extensive research studies in the literature have been performed to elucidate the interfacial reactions between inorganic arsenic and solid surfaces of sulfides, and Fe, Al, and Mn (hydro)oxides. Outer-sphere and inner-sphere complex (monodentate mononuclear, bidentate mononuclear, and bidentate binuclear complex) models have been proposed to interpret the sorption mechanisms. The nature of the surface complexes has been inspected by spectroscopic methods but remains controversial. This paper focuses on the recent advancement in arsenic speciation in solid phases and covers relevant methodological, analytical and modeling aspects. The identification of arsenic species in natural materials, however, is complicated by the presence of multiple species, and the applications of instrumental methods are usually limited due to their comparatively high detection limits. Development of advanced in-situ methods with high sensitivity, therefore, is required.     

Attitudes of Canadian Pig Producers Toward Animal Welfare

As part of a larger study eliciting Canadian producer and non-producer views about animal welfare, open-ended, semi-structured interviews were used to explore opinions about animal welfare of 20 Canadian pig producers, most of whom were involved in confinement-based systems. With the exception of the one organic producer, who emphasized the importance of a “natural” life, participants attached overriding importance to biological health and functioning. They saw their efforts as providing pigs with dry, thermally regulated, indoor environments where animals received abundant feed, careful monitoring and where prospective disease outbreaks could be minimized and controlled. Emphasis was also placed on low-stress handling and agreeable working conditions which were believed to promote good animal care. The fact that pigs tend to respond to such conditions with steady growth reinforced the belief that good welfare was provided. Participants supported the use of sow gestation stalls, but with some reservations, and expressed concern about welfare problems that could occur if sows were grouped. Invasive procedures (castration, tail-docking, teeth clipping) were recognized as painful but were accepted because they were seen as: (1) necessary for sales or management; (2) satisfactory trade-offs to prevent worse welfare problems such as injury or infection; or (3) sufficiently short-term to be relatively unimportant. Participants were adamantly opposed to animal neglect and some welcomed actions of animal protectionists that expose poor care. Producers also welcomed natural-science-based approaches to improving animal welfare. The findings contribute to a broader effort to identify overlapping values among different stakeholder groups as a basis for formulating mutually agreeable, farm animal care and handling polices.     

Economics of "essential use exemptions" for metered-dose inhalers under the Montreal Protocol

The Montreal Protocol on Substances that Deplete the Ozone Layer has led to rapid reductions in the use of ozone-depleting substances worldwide. However, the Protocol provides for "essential use exemptions" (EUEs) if there are no "technically and economically feasible" alternatives. An application that might qualify as an "essential use" is CFC-powered medical metered-dose inhalers (MDIs) for the treatment of asthma and chronic obstructive pulmonary disease (COPD), and the US and other nations have applied for exemptions in this case. One concern is that exemptions are necessary to ensure access to medications for low-income uninsureds. We examine the consequences of granting or withholding such exemptions, and conclude that government policies and private-sector programs are available that make it economically feasible to phase out chlorofluorocarbons (CFCs) in this application, thereby furthering the global public health objectives of the Montreal Protocol without compromising the treatment of patients who currently receive medication by means of MDIs.     

Testing isosource: stable isotope analysis of a tropical fishery with diverse organic matter sources

We sampled consumers and organic matter sources (mangrove litter, freshwater swamp-forest litter, seagrasses, seagrass epiphytes, and marine particulate organic matter [MPOM]) from four estuaries on Kosrae, Federated States of Micronesia for stable isotope (sigma13C and sigma34S) analysis. Unique mixing solutions cannot be calculated in a dual-isotope, five-endmember scenario, so we tested IsoSource, a recently developed statistical procedure that calculates ranges in source contributions (i.e., minimum and maximum possible). Relatively high minimum contributions indicate significant sources, while low maxima indicate otherwise. Litter from the two forest types was isotopically distinguishable but had low average minimum contributions (0-8% for mangrove litter and 0% for swamp-forest litter among estuaries). Minimum contribution of MPOM was also low, averaging 0-13% among estuaries. Instead, local marine sources dominated contributions to consumers. Minimum contributions of seagrasses averaged 8-47% among estuaries (range 0-88% among species). Minimum contributions of seagrass epiphytes averaged 5-27% among estuaries (range 0-69% among species). IsoSource enabled inclusion of five organic matter sources in our dual-isotope analysis, ranking trophic importance as follows: seagrasses > seagrass epiphytes > MPOM > mangrove forest > freshwater swamp-forest. IsoSource is thus a useful step toward understanding which of multiple organic matter sources support food webs; more detailed work is necessary to identify unique solutions.     

The fear of being eaten reduces energy transfer in a simple food chain

Food chain length is an important property of ecosystems, but the mechanisms maintaining it remain elusive. Classical views suggest that energetic inefficiencies (the "energy-flow hypothesis") limit food chain length, but others have argued that better explanations reside in more complex scenarios that consider the stability of food webs or the combined effects of productivity and ecosystem size. We argue that abandonment of the energy-flow hypothesis is premature. For a simple tritrophic rocky intertidal food chain, we show that the efficiency of energy transfer is strongly influenced by predation risk and consumer density. Effects tied to predation risk were particularly strong, explaining 32% of the variation in growth efficiency (compared to 15% for density effects) and reducing it by 44-76%. Hence, the stress (fear of being eaten) that predators impose on prey may be instrumental in limiting energy transfer up the food chain and thus contribute to the shortening of food chains.     

Surface-mediated formation of PBDD/Fs from the high-temperature oxidation of 2-bromophenol on a CuO/silica surface

As a model brominated hydrocarbon that may form brominated dioxins, we studied the surface-mediated, oxidative thermal degradation of 2-bromophenol on a supported copper oxide catalyst in a 1 mm i.d., fused silica flow reactor at a constant concentration of 90 ppm over a temperature range from 250 to 550 degrees C. Observed products included: dibenzo-p-dioxin (DD), 1-monobromodibenzo-p-dioxin (1-MBDD), dibromodibenzo-p-dioxin (DBDD), tribromodibenzo-p-dioxin (TrBDD), 4-monobromodibenzofuran (4-MBDF), 2,4,6-tribromophenol, 2,4- and 2,6-dibromophenol, and polybrominated benzenes. The results are compared and contrasted with previous work on surface catalyzed oxidative thermal degradation of 2-chlorophenol as well as our own work with the surface-catalyzed pyrolytic thermal degradation of 2-bromophenol. Typically 20 to 200x higher yields of PBDDs are observed for 2-bromophenol than for the analogous PCDDs for 2-chlorophenol. However the anticipated PBDF, 4,6-DBDF, was not observed and 4-MBDF was observed at very low yields. Surprisingly, the maximum yields of PBDDs were observed at higher temperatures than under pyrolytic conditions. This is attributed to regeneration of the catalytic surface due to the presence of oxygen. Higher yields of polybrominated phenols and polybrominated benzenes were also observed than for the analogous chlorinated phenols and benzenes from the oxidation of 2-chlorophenol. This can be attributed to the ease of bromination over chlorination based on the higher abundance of bromine atoms present for 2-bromophenol than chlorine atoms present for 2-chlorophenol.     

Validation of three new methods for determination of metal emissions using a modified Environmental Protection Agency Method 301

Three new methods applicable to the determination of hazardous metal concentrations in stationary source emissions were developed and evaluated for use in U.S. Environmental Protection Agency (EPA) compliance applications. Two of the three independent methods, a continuous emissions monitor-based method (Xact) and an X-ray-based filter method (XFM), are used to measure metal emissions. The third method involves a quantitative aerosol generator (QAG), which produces a reference aerosol used to evaluate the measurement methods. A modification of EPA Method 301 was used to validate the three methods for As, Cd, Cr, Pb, and Hg, representing three hazardous waste combustor Maximum Achievable Control Technology (MACT) metal categories (low volatile, semivolatile, and volatile). The modified procedure tested the methods using more stringent criteria than EPA Method 301; these criteria included accuracy, precision, and linearity. The aerosol generation method was evaluated in the laboratory by comparing actual with theoretical aerosol concentrations. The measurement methods were evaluated at a hazardous waste combustor (HWC) by comparing measured with reference aerosol concentrations. The QAG, Xact, and XFM met the modified Method 301 validation criteria. All three of the methods demonstrated precisions and accuracies on the order of 5%. In addition, correlation coefficients for each method were on the order of 0.99, confirming the methods' linear response and high precision over a wide range of concentrations. The measurement methods should be applicable to emissions from a wide range of sources, and the reference aerosol generator should be applicable to additional analytes. EPA recently approved an alternative monitoring petition for an HWC at Eli Lilly's Tippecanoe site in Lafayette, IN, in which the Xact is used for demonstrating compliance with the HWC MACT metal emissions (low volatile, semivolatile, and volatile). The QAG reference aerosol generator was approved as a method for providing a quantitative reference aerosol, which is required for certification and continuing quality assurance of the Xact.     

Polybrominated diphenyl ethers (PBDEs) in mussels from selected French coastal sites: 1981-2003

The present study focused on the retrospective analysis of PBDEs in archived blue mussel (Mytilus edulis or Mytilus galloprovincialis) samples collected over the past 22 years (1981-2003) from coastal areas of France. We have found that PBDE levels in mussels from the English Channel increased markedly from 1981 to 1991-1995, doubling approximately every 5-6 years followed by a levelling off and a possible beginning of a decrease. The rate of the decline of hexa- and hepta-BDE congeners was more rapid than the decline of tetra- and penta-BDEs in these mussel samples. The difference in the course of time of lower and higher brominated PBDE concentrations suggests that the congener profile in the mussel samples changes over time. The increase in PBDE concentrations in the mussel samples contrasts with a concomitant constant decrease of chlorobiphenyls (CBs) in the same set of samples. However, pulse inputs of both groups of organohalogen compounds were determined for the mussel samples collected at the mouth of the Seine estuary and were probably related to riverine inundations and a flushing out of the deposited sediments from the internal estuary into the bay of the River Seine, as well as considerable dredging activities taking place during same years. In France, the highest PBDE concentrations were determined in the mussels from the English Channel, more precisely in the bay of the Seine, and the regional differences in PBDE levels were mainly connected to the difference in anthropogenic urban and industrial environmental pressures. Published data comparing PBDE levels in mussels have shown significant differences in concentrations between North/South America and Europe. This observation further confirms that the PBDE levels in the North American environment are higher than in Europe. However, the data used for this comparison of mussel contamination by PBDEs is still relatively sparse.