全文获取类型
收费全文 | 96篇 |
免费 | 7篇 |
国内免费 | 46篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 7篇 |
环保管理 | 4篇 |
综合类 | 59篇 |
基础理论 | 9篇 |
污染及防治 | 42篇 |
评价与监测 | 14篇 |
社会与环境 | 2篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 9篇 |
2020年 | 2篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2015年 | 9篇 |
2014年 | 8篇 |
2013年 | 7篇 |
2012年 | 10篇 |
2011年 | 13篇 |
2010年 | 3篇 |
2009年 | 8篇 |
2008年 | 7篇 |
2007年 | 7篇 |
2006年 | 7篇 |
2005年 | 4篇 |
2004年 | 6篇 |
2003年 | 10篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1994年 | 3篇 |
1990年 | 1篇 |
排序方式: 共有149条查询结果,搜索用时 15 毫秒
81.
ZnCl2法污泥含炭吸附剂对模拟烟气中气态汞的吸附 总被引:1,自引:0,他引:1
采用改进的ZnCl2化学活化法制备污泥含炭吸附剂,利用EDS以及氮吸附等多种测试手段对所制得的污泥含炭吸附剂进行表征,并利用其处理模拟烟气汞污染物,实验结果表明,污泥含炭吸附剂对Hg0的吸附包括物理吸附作用和化学吸附作用,以物理吸附作用为主;随着Hg0入口浓度的提高,污泥含炭吸附剂的Hg0饱和吸附容量增大;随着吸附反应温度的升高污泥含炭吸附对Hg0的吸附作用减弱;在吸附反应温度125℃,Hg0入口浓度60.4 μg/m3,污泥含炭吸附剂和选定的活性炭对Hg0的吸附容量分别为81.2 μg/g和53.8 μg/g,污泥含炭吸附剂对Hg0的吸附作用好于选定的活性炭。 相似文献
82.
Shi Yin Yan-Qiu Chen Yue-Li Li Wang-Lai Cen Hua-Qiang Yin 《Frontiers of Environmental Science & Engineering》2018,12(5):12
Porous carbon material facilitates the reaction SO2 + O2 + H2O → H2SO4 in coal-burned flue gas for sulfur resources recovery at mild conditions. It draws a long-term mystery on its heterogeneous catalysis due to the complicated synergic effect between its microstructure and chemical components. To decouple the effects of geometric structure from chemical components, classical molecular dynamics method was used to investigate the static and dynamic characteristics of the reactants (H2O, SO2 and O2) in the confined space truncated by double-layer graphene (DLG). Strong adsorption of SO2 and O2 by the DLG was observed, which results in the filling of the solute molecules into the interior of the DLG and the depletion of H2O. This effect mainly results from the different affinity of the DLG to the species and can be tuned by the separation of the two graphene layers. Such dimension dependence of the static and dynamic properties like distribution profile, molecular cluster, hydrogen bond and diffusion coefficient were also studied. The conclusions drawn in this work could be helpful to the further understanding of the underlying reaction mechanism of desulfurization process in porous carbon materials and other applications of carbon-based catalysts. 相似文献
83.
Gang Xiao Baosheng Jin Mingjiang Ni Kefa Cen Yong Chi Zhongxin Tan 《Frontiers of Environmental Science & Engineering》2011,5(2):193-204
Considering high-moisture municipal solid waste (MSW) of China, a steam dried MSW gasification and melting process was proposed, the feasibility was tested, and the mass and energy balance was analyzed. Preliminary experiments were conducted using a fixed-bed drying apparatus, a 200 kg per day fluidized-bed gasifier, and a swirl melting furnace. Moisture percentage was reduced from 50% to 20% roughly when MSW was dried by slightly superheated steam of 150°C?C350°C within 40 min. When the temperature was less than 250°C, no incondensable gas was produced during the drying process. The gasifier ran at 550°C?C700°Cwith an air equivalence ratio (ER) of 0.2?C0.4. The temperature of the swirl melting furnace reached about 1240°C when the gasification ER was 0.3 and the total ER was 1.1. At these conditions, the fly ash concentration in the flue gas was 1.7 g·(Nm3)?1, which meant over 95% fly ash was trapped in the furnace and discharged as slag. 85% of Ni and Cr were bound in the slag, as well as 60% of Cu. The mass and energy balance analysis indicates that the boiler heat efficiency of an industrial MSW incineration plant reaches 86.97% when MSW is dried by steam of 200°C. The boiler heat efficiency is sensitive to three important parameters, including the temperature of preheated MSW, the moisture percentage of dried MS Wand the fly ash percentage in the total ash. 相似文献
84.
螺孢菌ZG9901的筛选及其产碱性果胶酶发酵条件研究 总被引:10,自引:0,他引:10
用筛选培养基从芦苇土壤中筛选到7株碱性果胶酶产生菌株,经初筛选和复筛得到产酶活性较高的一株菌株ZG9901,初步鉴定为螺孢菌属Spirillospora spp.最适摇瓶产酶条件是:果胶20g/L,乳糖20g/L,蛋白胨3g/L,酵母膏4g/L,KH2PO41g/L,MgSO4.7H2O0.04g/L,MgCl20.2g/L,pH9.0,32℃培养36h达到产酶高峰。 相似文献
85.
用污水处理厂脱水污泥制备含炭吸附剂 总被引:2,自引:0,他引:2
以污水处理厂脱水污泥为原料,分别采用炭化法、物理活化法和化学活化法制备了含炭吸附剂。采用化学活化法制备的含炭吸附剂性能最好,热解温度为450℃时,含炭吸附剂的碘吸附值为313.9mg/g,吸附剂收率为64.36%。采用ZnCl2为活化剂,所制备的含炭吸附剂的性能优于H2SO4,KOH,H3PO4作为活化剂。经正交实验得出的最佳实验条件为:ZnCl2浓度3mol/L,干污泥与活化剂溶液质量比1:4.0,热解温度450℃,热解时间1.5h。制备含炭吸附剂的干污泥粒径以0.6~0.9mm为宜。组合活化剂的效果好于ZnCl2溶液,最佳的组合活化剂为ZnCl2+H2SO4(体积比为3:1)。含炭吸附剂的孔径分布较宽,微孔所占比例较小,以中孔为主,比表面积较小。 相似文献
86.
草甘膦是全球范围内生产与使用量最大的除草剂。虽然草甘膦制剂被分于低毒等级,但是许多研究显示其对动物的生理、行为表达具有广泛的干扰作用。本研究将中华鳖胚胎暴露于不同浓度的草甘膦铵盐溶液以评估草甘膦除草剂对其胚胎发育及孵出幼体表型及生理表现的影响。结果显示:一定浓度范围(5~5 000 mg·L~(-1))内,草甘膦铵盐对中华鳖胚胎发育速率、孵出幼体大小、游泳能力、肝脏甘油三酯含量、超氧化物歧化酶活性、丙二醛含量以及热激蛋白70 mRNA相对表达量无显著影响。结果表明:一定浓度范围草甘膦除草剂暴露对中华鳖胚胎发育的影响较小,不改变孵出幼体的表型及其生理表现。 相似文献
87.
88.
89.
燃煤锅炉低氮氧化物燃烧特性的神经网络预报 总被引:18,自引:2,他引:18
大型燃煤电站锅炉的低NOx燃烧技术日益受到关注,但NOx的排放特性复杂,受煤种、锅炉设计结构和操作参数等多种因素影响.在对某台600MW四角切圆燃煤电站锅炉的NOx排放特性和飞灰含碳量特性进行多工况热态测试的基础上,应用人工神经网络的非线性动力学特性及自学习特性,建立了大型四角切圆燃烧锅炉NOx排放特性和燃烧经济性的神经网络模型,并对此模型进行了校验.结果表明,该模型能根据燃煤特性及各种操作参数准确预报锅炉在不同工况下的NOx排放和飞灰含碳量特性,可为大型电站锅炉通过燃烧调整降低NOx排放和提高锅炉燃烧效率提供有效手段. 相似文献
90.