Gradient ion chromatography of environmentally relevant anions in scrubbers of waste incinerators

Improved separations of a wide range of anions of environmental importance in scrubbers of waste incinerators were achieved by applying a Na₂B₄O₇/NaOH composition gradient of low electrical conductivity in combination with suppressed ion chromatography. Fluoride, Acetate, Formiate and 16 other ions including Iodide could be separated within the same run in less than 20 minutes. The selective detection of small amounts of several anions in presence of excessive amounts of Chloride and Sulfate is discussed. Furtheron various adsorbents were tested for the removal of Phenol as a potential trouble shooting source in 5 ion chromatography. Depending on the analytical task and circumstances several adsorbents reveiled promising properties.     

Large-scale green synthesis of Cu nanoparticles

This article reports a novel, eco-friendly herbal method to synthesize Cu nanoparticles in large scales. Cu nanoparticles are an alternative to Ag and Au nanoparticles and have potential applications in many industrial areas. Many synthetic routes have been documented for the preparation of copper nanoparticles, but very few routes are eco-friendly and large-scale. We report here the preparation of Cu nanoparticles from aqueous CuSO₄ using non-toxic and inexpensive materials like curd, milk, and herbal extracts such as tamarind and lemon juice as capping agents. X-ray diffraction and transmission electron microscopy show that produced particles are nanocrystalline copper 20–50 nm in size with a face-centered cubic structure. Fourier-transformed infrared spectroscopy evidences the role of organic acids in the capping process. The novelty of this work is the synthesis of Cu nanoparticles from CuSO₄ without electricity and using non-toxic, cheap capping agents.     

Controlling urban air pollution caused by households: uncertainty, prices, and income

We examine the control of air pollution caused by households burning wood for heating and cooking in the developing world. Since the problem is one of controlling emissions from nonpoint sources, regulations are likely to be directed at household choices of wood consumption and combustion technologies. Moreover, these choices are subtractions from, or contributions to, the pure public good of air quality. Consequently, the efficient policy design is not independent of the distribution of household income. Since it is unrealistic to assume that environmental authorities can make lump sum income transfers part of control policies, efficient control of air pollution caused by wood consumption entails a higher tax on wood consumption and a higher subsidy for more efficient combustion technologies for higher income households. Among other difficulties, implementing a policy to promote the adoption of cleaner combustion technologies must overcome the seemingly paradoxical result that efficient control calls for higher technology subsidies for higher income households.     

Histological changes in the reproductive system of male rats exposed to cigarette smoke or electronic cigarette vapor

Abstract

The use of electronic cigarettes increases as a supposedly healthier form of nicotine consumption, but safety of vaping remains uncertain. In this study, we assessed whether the use of electronic cigarettes increases the risk of infertility in male rats. Malformations of sperm morphology were more frequent in nicotine-exposed groups than in the control group. Vacuolization of seminiferous epithelium, reduction of spermatogenesis, increased apoptosis of spermatogonia and spermatocytes, and acceleration of degeneration of testes were observed. The male reproductive organs are slightly less affected by vaping than by smoking. Nevertheless, in consequence both may lead to the reduction of fertility.     

A simplified clean-up procedure for the rapid determination of PCDDs and PCDFs based on retention on activated carbon AX-21

Different 2,3,7,8-substituted polychlorinated dibenzodioxins (PCDDs) and dibenzofurans (PCDFs) were investigated for their retention behaviour on a disposable minicolumn containing activated carbon AX-21. Elution behaviour and recovery were examined, using native and radiolabelled PCDD and PCDF isomers.

A comparison of the total mass chromatograms of PCDDs and PCDFs in an extract from animal adipose tissue, before and after activated carbon treatment, demonstrates the efficiency of this cleanup step with respect to the elimination of interfering compounds.