PRELIMINARY OBSERVATIONS ON WATER QUALITY OF STORM RUNOFF FROM FOUR SELECTED RESIDENTIAL ROOFS1

ABSTRACT: Storm runoff from four characteristic types of residential roofs and incident rainwater were monitored for 47 storm events over a six-month period at Nacogdoches, Texas, to study water quality conditions for 20 element and four chemical variables. The total element concentration in storm runoff from each roof type was greater than that of rainwater in the open. Differences in element concentrations in storm runoff among the four roof types were statistically significant (α≤ 0.05) with the differences for the wood shingle roof being the greatest and that for terra cotta clay roof being the least. The median concentrations of four element variables exceeded the Texas surface water quality standards, while 12 variables exceeded the standards at least one time in all samples collected. Zinc concentrations violated the Standard ranging from 85.7 percent of the samples for the wood shingle roof to 66.0 percent for the composite shingle, the greatest exceedances of all 24 variables studied. Storm characteristics and gutter maintenance level had some effects on these water quality conditions. The study suggested that roof types can be important to water pollution management programs. More detailed studies on roof water quality in major municipalities are required.     

THROUGHFALL IN PLANTED STANDS OF FOUR SOUTHERN PINE SPECIES IN EAST TEXAS1

Throughfall was measured during 1978–79 beneath the canopies of adjacent stands of four major southern pine species, all on identical soil type and topography in the Stephen F. Austin Experimental Forest. Observations from 44 storms in a randomized network of 15, 5.08 cm PVC gages in a 0.4 ha plot of each species showed that throughfall expressed as percent of storm precipitation, is greatest under longleaf pine and least under loblolly pine; throughfall under shortleaf and slash pine did not differ significantly. Generally, through-fall decreased with storm size and intensity, with distance from the nearest tree stem, and is greater during summer half-year (May–October). Canopy drips, apparently accounting for the greater throughfall for the gage position closer to the stems, were more numerous than reported elsewhere. The 5.08 cm PVC gages proved to be acceptable substitutes for standard nonrecording gages in measuring throughfall. A network of 15 such gages was sufficient to sample throughfall data with 90 percent accuracy in each of the four southern pine plantations.     

AN EVALUATION OF PRECIPITATION GAGE DENSITY IN A MOUNTAINOUS TERRAIN1

ABSTRACT: Inter-station analysis was employed to evaluate the adequacy of the precipitation network in topographically complex West Virginia. A 25-year period was determined as the minimum lingth of record needed for relatively stable and fairly accurate estimates of long-term (50-year) precipitation and in frequency analysis. Data from the 83 National Weather Service stations with 25-year records were adjusted for consistency and evaluated separately by zones east (31 stations) and west (52 stations) of the Appalachian divide. Correlation coefficients (r) and average standard errors of estimate were computed for all station pairs within 50 miles distance and 1000 feet elevation difference of each other. The third polynomial equation of inter-station distance eliminated using elevation and land slope as the criteria in network design in this mountainous terrain. A network with (r) = 0.9 estimates annual precipitation with accuracy as great as 5 percent, but requires about 250 additional gages (i.e., about 200 percent of the present density).     

Quantifying the human health benefits of curbing air pollution in Shanghai

Urban development in the mega-cities of Asia has caused detrimental effects on the human health of its inhabitants through air pollution. However, averting these health damages by investing in clean energy and industrial technologies and measures can be expensive. Many cities do not have the capital to make such investments or may prefer to invest that capital elsewhere. In this article, we examine the city of Shanghai, China, and perform an illustrative cost/benefit analysis of air pollution control. Between 1995 and 2020 we expect that Shanghai will continue to grow rapidly. Increased demands for energy will cause increased use of fossil fuels and increased emissions of air pollutants. In this work, we examine emissions of particles smaller than 10 microm in diameter (PM10), which have been associated with inhalation health effects. We hypothesize the establishment of a new technology strategy for coal-fired power generation after 2010 and a new industrial coal-use policy. The health benefits of pollution reduction are compared with the investment costs for the new strategies. The study shows that the benefit-to-cost ratio is in the range of 1-5 for the power-sector initiative and 2-15 for the industrial-sector initiative. Thus, there appear to be considerable net benefits for these strategies, which could be very large depending on the valuation of health effects in China today and in the future. This study therefore provides economic grounds for supporting investments in air pollution control in developing cities like Shanghai.     

Biological treatment process of air loaded with an ammonia and hydrogen sulfide mixture

The physico-chemical characteristics of granulated sludge lead us to develop its use as a packing material in air biofiltration. Then, the aim of this study is to investigate the potential of unit systems packed with this support in terms of ammonia and hydrogen sulfide emissions treatment. Two laboratory scale pilot biofilters were used. A volumetric load of 680 g H2S m(-3) empty bed day(-1) and 85 g NH3 m(-3) empty bed day(-1) was applied for eight weeks to a unit called BGSn (column packed with granulated sludge and mainly supplied with hydrogen sulfide); a volumetric load of 170 g H2S m(-3) empty bed day(-1) and 340 g NH3 m(-3) empty bed day(-1) was applied for eight weeks to the other called BGNs (column packed with granulated sludge and mainly supplied with ammonia). Ammonia and hydrogen sulfide elimination occur in the biofilters simultaneously. The hydrogen sulphide and ammonia removal efficiencies reached are very high: 100% and 80% for BGSn; 100% and 80% for BGNs respectively. Hydrogen sulfide is oxidized into sulphate and sulfur. The ammonia oxidation products are nitrite and nitrate. The nitrogen error mass balance is high for BGSn (60%) and BGNs (36%). This result could be explained by the denitrification process which would have occurred in anaerobic zones. High percentages of ammonia or hydrogen sulfide are oxidized on the first half of the column. The oxidation of high amounts of hydrogen sulfide would involve some environmental stress on nitrifying bacterial growth and activity.     

A COMPARISON OF METHODS OF ESTIMATING MEAN WATERSHED SLOPE1

ABSTRACT: Ten topographic analysis methods were employed to estimate watershed mean slopes for 13 small forested watersheds (32 to 131 mi²) in East Texas. Of the ten methods employed, the mean slope curve is the most accurate but also the most tedious and laborious one. The method can be simplified by measuring only the lengths of five contours and the areas between these contours within the watershed with little loss of its accuracy. Watershed slopes estimated by the contour length method, the grid contour method, the systematic slope sampling method, and the simplified contour length method are satisfactory for general purposes and relatively simple. The watershed circumference-stream length method, the length-width axis method, the Justin method, and the regression plane method are not suitable for estimating watershed slopes in East Texas without modification.     

FORESTS AND OTHER FACTORS ASSOCIATED WITH STREAMFLOWS IN EAST TEXAS1

Effects of proportion of watersheds in forest and watershed physiographic factors on mean annual streamflow (1965-76), median flow, and 12 flood flow characteristics were regionally analyzed for 19 unregulated streams in East Texas. Annual streamflow increased with decreasing proportion of forest area. Differences in annual streamflow between full forest cover and bare watersheds could be as much as 200 mm. Other things being equal, the minimum watershed area required to generate 0.142 cm (5 cfs), a criterion used by the U.S. Corps of Engineering in regulating dredge and fill activity for water pollution abatement in East Texas streams, is 70 km² (27 mi²). Of the 31 physio-climatic parameters analyzed, watershed area, percent forest area, shape index, spring precipitation, and annual temperature were the most significant in affecting streamflow characteristics in East Texas. Using 2-3 of these five variables, all of the 14 streamflow characteristics can be estimated with accuracy ranging from acceptable to excellent levels.     

Automatic continuous river monitoring of nitrate using a novel ion-selective electrode

On-site continuous measurement of nitrate in the River Taw situated in Devon (UK) was performed automatically for two months using a recently developed ion-selective electrode (ISE). A non-submersible electrode support system was developed and a field instrument was constructed comprising the nitrate-ISEs, a reference electrode and a temperature probe connected through a pre-amplifier to a data-logger and battery supply. The nitrate-ISE was constructed using a commercially available electrode body with a membrane incorporated into the tip. This rubbery membrane contained the sensor molecule (N,N,N-triallylleucine betaine chloride, 6.5% m/m) covalently bound to polystyrene-block-polybutadiene-block-polystyrene, SBS, (43.5% m/m), with 2-nitrophenyloctyl ether (2-NPOE) as mediator (40% m/m). The Nernstian slope was -59.1 mV per decade over a linear range of 1400-0.07 mg L(-1) nitrate-N. The limit of detection was 0.007 mg L(-1) nitrate-N with a selectivity coefficient for nitrate against chloride (k(pot)NO3-, Cl-) of 3.4 x 10(-3). The speed of response was less than a minute over the linear Nernstian range. The lifetime in the laboratory exceeded 5 months with no potentiometric drift over the linear Nernstian range. A temperature correction algorithm was also used to accomodate the temperature changes encountered in the river. The river nitrate results obtained with the ISEs at hourly intervals compared very favourably (R2 = 0.9) with those obtained with laboratory automated chemical determinations made on contemporaneous river samples over a concentration range 0.55-2.00 mg L(-1) nitrate-N. The ISEs did not require re-calibration and no deterioration in performance or fouling of the membrane surface was observed during 40 days.     

Biflagellated Unicellular Algae as Detectors of Pesticide Contamination in Water

The flagellae of the unicellular marine algae Dunaliella bioculata and the freshwater Chlamydomonas resemble very much the cilia lining the bronchial tubes in human lungs. Lindane the commercial product containing 99% of the isomer of hexachlorocyclohexane was tested at various concentrations on the two algae.The concentrations of Lindane tested (5ppm - 30ppm) proved to be cytotoxic and also had a remarkable effect on the motility of both Dunaliella bioculata and Chlamydomonas. The , and isomers of lindane showed similar efects on Dunaliella bioculata.Cytoxicity was measured by growth curves and motility was quantified by microcinematography and Doppler laser velocimetry methods.At low concentrations of all the isomers (5-10 ppm), there was an acceleration of movement which lasted for 5 minutes followed by rapid deceleration of movement.Dunaliella was tested with the ionophore (mobile ion carrier) A23187 for calcium at concentration of (10-5M). The results were compared with that of Dunaliella with lindane at 15ppm and a combination of lindane (15ppm) and Ionophore A23187 (10-5M).The results show that the ionophore A23187 (10-5M) enhances the effect of lindane on the motility of Dunaliella. This could suggest that lindane induced effects may be due to interferences with the intracellular calcium flux.     

Assessment of Human Health Risk of Dioxin in Korea

This study assessed the daily exposure to dioxin using comparable approach methods in order to predict the human health risks of dioxin on the general adult population and incinerator workers in Korea. The health risk assessment of dioxin involved four scenarios (General-Direct, General-Breast Milk, General-Blood, and Worker-Blood). The risks were described in terms of the excess cancer risk and the MOEs (Margin-Of-Exposure) for cancer, reproductive dysfunctions, endometriosis, and neurobehavioral effects. The adult daily intake (General-Direct) of dioxin was estimated to be 0.50 pg-TEQ/kg-day based on the dioxin concentrations in the environmental media and foods in Korea. The average dioxin concentrations in General-Breast Milk, General-Blood, and Worker-Blood were 15.13 pg-TEQ/g fat, 14.57 pg-TEQ/g lipid, and 22.90 pg-TEQ/g lipid, respectively. The lifetime average daily doses (LADDs) of dioxin for General-Breast Milk, General-Blood, and Worker-Blood were estimated to be 1.35 pg-TEQ/kg day, 0.99 pg-TEQ/kg day, and 1.15 pg-TEQ/kg day, respectively. Although the estimated risks of cancer and reproductive dysfunctions were not unusually high in any of the four scenarios, the MOE values for the neurobehavioral effects on infants were not sufficiently high to guarantee the safety against this endpoint.