水动力学法预测三峡工程对洞庭湖洲滩的影响

用水动力学方法，根据三峡建库前后不同的时空边界条件，模拟长江水情要素，并建立长江水位与洞庭湖水位的回归方程，从而预测三峡工程对洞庭湖区洲滩面积的影响。     

Characteristics of the PAH emissions from the incineration of livestock wastes with/without APCD

This study was conducted on two batch-type livestock waste incinerators, including the one with an air-pollution control device (APCD)-one wet scrubber (WSB) and the other without APCD for the disposal of livestock wastes. The concentration and composition of 21 individual polycyclic aromatic hydrocarbons (PAHs) in the stack flue gas (gas and particle phases), bottom ash, and effluent of WSB were determined. Stack flue gas samples were collected by a PAH stack-sampling system. Twenty-one individual PAHs were analyzed by a gas chromatography/mass spectrometer (GC/MS). Due to the low combustion temperature, a remarkable and significant increase in the total-PAH concentration of emission from the stack with APCD was observed when compared with the case without APCD. Measured total-PAH emission factors were 285 and 2.86 mg/kg waste for the incineration with and without APCD, respectively, while BaP (the most carcinogenic PAH) emission factors were 0.79 and 0.12 mg/kg waste for the incineration with and without APCD. The total-PAH output/input mass ratios averaged 0.011 and 0.004 with and without APCD, respectively. The result reveals that the PAH content in the auxiliary fuel during the incinerating process could affect the emission of PAH.     

陕北子长县阎家沟黄土滑坡特征及其变形机制

野外调查和钻探资料显示,阎家沟滑坡属大型黄土滑坡,滑坡体为中、晚更新世黄土.在滑坡前缘流水侵蚀坡脚和滑坡体上修建窑洞、梯田、排放生活用水等人类工程活动影响下以及在2002年7月4日连续强降雨的激发下,目前处于不稳定状态,若遇强降雨失稳概率很大.填埋滑坡体裂隙和孔洞、加强地表排水、在滑坡体前缘沟谷修建淤地坝是提高陕北此类滑坡稳定性最为经济有效的措施.     

废纸造纸废水处理工程应用

报道了自制混凝剂产品处理废纸造纸废水的工程应用情况。经过 1年多的运行结果表明 ,当进水CODCr、悬浮物浓度分别为 972mg/L、82 5mg/L以及色度为 3 0 0倍时 ,采用该工艺处理后 ,CODCr去除率平均为 95 .7% ,SS去除率平均为 98.9% ,色度去除率平均为 99.3 % ,出水水质远低于国家一级排放标准 (GB3 5 44 - 92 ) ,并且工厂实践表明 ,对生产有显著的效益 ,从而证明该方法对于废纸造纸废水的处理是可行的。该处理工艺设备简单 ,系统运行稳定 ,操作方便 ,成本低     

制备方法对MgAl水滑石衍生氧化物负载钯催化剂丙烷完全氧化活性的影响

以沉积沉淀法(DP)、浸渍法(IM)和共沉淀法(CP)制备MgAl水滑石衍生氧化物负载钯催化剂,用ICP、XRD、SEM、TEM、EDS、TPR以及比表面测定等手段对催化剂进行了表征.ICP和XRD数据表明用上述3种方法均可成功制备水滑石为前体载钯催化剂.SEM、TEM、EDS数据表明不同方法制备的样品具有不同的形貌以及钯在其中的分散度.综合各类表征数据可知Pd在催化剂中暴露的活性位是影响其活性的主要因素.     

Shellac-coated iron oxide nanoparticles for removal of cadmium(II) ions from aqueous solution

This study describes a new effective adsorbent for cadmium removal from aqueous solution synthesized by coating a shellac layer, a natural biodegradable and renewable resin with abundant hydroxyl and carboxylic groups, on the surface of iron oxide magnetic nanoparticles. Transmission Electron Microscopy (TEM) imaging showed shellac-coated magnetic nanoparticle (SCMN) adsorbents had a core-shell structure with a core of 20 nm and shell of 5 nm. Fourier Transform Infrared Spectroscopic analysis suggested the occurrence of reaction between carboxyl groups on the SCMN adsorbent surface and cadmium ions in aqueous solution. Kinetic data were well described by pseudo second-order model and adsorption isotherms were fitted with both Langmuir and Freundlich models with maximum adsorption capacity of 18.80 mg/g. SCMN adsorbents provided a favorable adsorption capacity under high salinity conditions, and cadmium could easily be desorbed using mild organic acid solutions at low concentration.     

The impact of urban planning on land use and land cover in Pudong of Shanghai,China

Functional zones in cities constitute the most conspicuous components of newly developed urban areas,and have been a hot spot for domestic and foreign investors in China,which not only show the expanse of urban space accompanied by the shifts both in landscape(from rural to urban)and land use(from less extensive to extensive),but also display the transformation of regional ecological functions.By using the theories and methods of landscape ecology,the structure of landscapes and landscape ecological planning can be analyzed and evaluated for studying the urban functional zones‘layout.In 1990,the Central Govermment of China declared to develop and open up Pudong New Area so as to promote economic development in Shanghai.Benefited from the advantages of Shanghai‘s location and economy,the government of Pudong New Area has successively built up 7 different functional zones over the past decade according to their functions and strategic goals.Based on the multi-spectral satellite imageries taken in 1990,1997and 2000,a landscape ecolgy analysis was carried out for Pudong New Area of Sanghai ,supported by GIS technology.Green space(including croplands )and built-up areas are the major factors considered in developing urban landscape.This paper was mainly concerned with the different spatial patterns and dynamics of green space,built-up areas and new buildings in different functional zones,as influenced by different spatial patterns and dynamics of green space,built-up areas and new buildings in different functional zones,as influenced by different functional layouts and development strategies.The rapid urbanization in Pudong New Area resulted in a more homogeneous landscape.Agricultural landscape and suburban landscape were gradually replaced by urban landscape as the degree of urbanization increased.As a consequence of urbanization in Pudong,not only built-up patches,but also newly-built patches and green patches merged into one large patch,which should be attributed to the construction policy of extensive green space as the urban development process in Pudong New Area.The shape of green area of 7 functional zones became more and more regular because of the horticultural needs in Shanghai urban planning.Some suggestions were finally made for the study of future urban planning and layout.     

Biosorption mechanisms involved in immobilization of soil Pb by Bacillus subtilis DBM in a multimetal-contaminated soil

Mechanisms of soil Pb immobilization by Bacillus subtilis DBM, a bacterial strain isolated from a heavy-metal-contaminated soil, were investigated. Adsorption and desorption experiments with living bacterial cells as well as dead cells revealed that both extracellular adsorption and intracellular accumulation were involved in the Pb2＋removal from the liquid phase. Of the sequestered Pb（II）, 8.5% was held by physical entrapment within the cell wall, 43.3% was held by ion-exchange, 9.7% was complexed with cell surface functional groups or precipitated on the cell surface, and 38.5% was intracellularly accumulated.Complexation of Pb2＋with carboxyl, hydroxyl, carbonyl, amido, and phosphate groups was demonstrated by Fourier transform infrared spectroscopic analysis. Precipitates of Pb5（PO4）3OH, Pb5（PO4）3Cl and Pb10（PO4）6（OH）2that formed on the cell surface during the biosorption process were identified by X-ray diffraction analysis. Transmission electron microscopy–energy dispersive spectroscopic analysis confirmed the presence of the Pb（II）precipitates and that Pb（II） could be sequestered both extracellularly and intracellularly.Incubation with B. subtilis DBM significantly decreased the amount of the weak-acid-soluble Pb fraction in a heavy-metal-contaminated soil, resulting in a reduction in Pb bioavailability, but increased the amount of its organic-matter-bound fraction by 71%. The ability of B.subtilis DBM to reduce the bioavailability of soil Pb makes it potentially useful for bacteria-assisted phytostabilization of multi-heavy-metal-contaminated soil.     

Deodorization of dimethyl sulfide using a discharge approach at room temperature

The traditional technologies for odor removal of thiol usually create either secondary pollution for scrubbing, adsorption, and absorption processes, or sulfur (S) poisoning for catalytic incineration. This study applied a laboratory-scale radio-frequency plasma reactor to destructive percentage-grade concentrations of odorous dimethyl sulfide (CH3SCH3, or DMS). Odor was diminished effectively via reforming DMS into mainly carbon disulfide (CS2) or sulfur dioxide (SO2). The removal efficiencies of DMS elevated significantly with a lower feeding concentration of DMS or a higher applied rf power. A greater inlet oxygen (O2)/DMS molar ratio slightly improved the removal efficiency. In an O2-free environment, DMS was converted primarily to CS2, methane (CH4), acetylene (C2H2), ethylene (C2H4), and hydrogen (H2), with traces of hydrogen sulfide (H2S), methyl mercaptan (CH3SH), and dimethyl disulfide. In an O2-containing environment, the species detected were SO2, CS2, carbonyl sulfide, carbon dioxide (CO2), CH4, C2H4, C2H2, H2, formaldehyde, and methanol. Differences in yield of products were functions of the amounts of added O2 and the applied power. This study provided useful information for gaining insight into the reaction pathways for the DMS dissociation and the formation of products in the plasmolysis and conversion processes.     

Dechlorination and organohalide-respiring bacteria dynamics in sediment samples of the Yangtze Three Gorges Reservoir

Several groups of bacteria such as Dehalococcoides spp., Dehalobacter spp., Desulfomonile spp., Desulfuromonas spp., or Desulfitobacterium spp. are able to dehalogenate chlorinated pollutants such as chloroethenes, chlorobenzenes, or polychlorinated biphenyls under anaerobic conditions. In order to assess the dechlorination potential in Yangtze sediment samples, the presence and activity of the reductively dechlorinating bacteria were studied in anaerobic batch tests. Eighteen sediment samples were taken in the Three Gorges Reservoir catchment area of the Yangtze River, including the tributaries Jialing River, Daning River, and Xiangxi River. Polymerase chain reaction analysis indicated the presence of dechlorinating bacteria in most samples, with varying dechlorinating microbial community compositions at different sampling locations. Subsequently, anaerobic reductive dechlorination of tetrachloroethene (PCE) was tested after the addition of electron donors. Most cultures dechlorinated PCE completely to ethene via cis-dichloroethene (cis-DCE) or trans-dichloroethene. Dehalogenating activity corresponded to increasing numbers of Dehalobacter spp., Desulfomonile spp., Desulfitobacterium spp., or Dehalococcoides spp. If no bacteria of the genus Dehalococcoides spp. were present in the sediment, reductive dechlorination stopped at cis-DCE. Our results demonstrate the presence of viable dechlorinating bacteria in Yangtze samples, indicating their relevance for pollutant turnover.