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941.
Effect of SiO2 addition on NH4HSO4 decomposition and SO2 poisoning over V2O5–MoO3/TiO2–CeO2 catalyst
The deposition of NH4HSO4 and the poisoning effect of SO2 on SCR catalyst are the main obstacles that restrict the industrial application of CeO2-doped SCR catalysts. In this work, deposited NH4HSO4 decomposition behavior and SO2 poisoning over V2O5–MoO3/TiO2 catalysts modified with CeO2 and SiO2 were investigated. By the means of characterization analysis, it was found that the addition of SiO2 into VMo/Ti–Ce had an impact on the interaction existed between catalyst surface atoms and NH4HSO4. Temperature-programmed methods and in situ diffused reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments indicated that the doping of SiO2 promoted the decomposition of deposited NH4HSO4 on VMo/Ti–Ce catalyst surface by reducing the thermal stability of NH4HSO4 and enhancing the NH4HSO4 reactivity with NO in low temperature. And this improvement may be the reason for the better catalytic activity than VMo/Ti–Ce in the case of NH4HSO4 deposition. Accompanied with cerium sulfate species generated over catalyst surface, the conversion of SO2 to SO3 was inhibited in SiCe mixed catalyst. The addition of SiO2 could promote the decomposition of cerium sulfate, which may be a potential strategy to enhance the resistance of SO2 poisoning over CeO2-modifed catalysts. 相似文献
942.
943.
在分析城市步行街及其周边存在人车混行、人员密度高、通行效率低、潜在的危险大的基础上,笔者用计算机模拟方法研究了沈阳市中街步行街的一个人车混行的交叉路口,实际勘察了十字路口道路格局、车流、人流状况,测量、估计通过路口的人数、流量,根据获得的数据,对不设置交通信号灯、设置信号灯、建设过街天桥或地下通道等几种情况进行模拟,得到各种情况下的通行效率,并对不同的过街方案的优缺点进行比较。最终选择过街方案需要综合考虑影响安全和效率的多种因素,包括地域、人流量、路口宽度、周边交通等因素,用较小的经济投入取得最大的通行效率。文中的模拟采用EXODUS软件。 相似文献
944.
高风险社会及其对策研究 总被引:3,自引:8,他引:3
经济和技术不断发展的过程中伴随的副作用使人类社会逐渐处于“风险社会”乃至“高风险社会”之中。当前我国正处于结构调整和社会转型中,存在着自然灾害、事故灾难、公共卫生事件和社会安全事件等各种各样的风险。在对现代社会风险的特点进行归纳后,对其量化方法也进行了初步探讨,并结合我国实际情况从影响风险大小的各因素入手,拟定了若干风险管理对策,对如何面对“风险社会”和提高风险承受能力可起到积极的参考作用。 相似文献
945.
职业安全培训效果定量评估方法应用研究 总被引:2,自引:1,他引:2
职业安全培训是企业安全管理的重要内容,是提高员工安全意识和事故风险管理技能的主要手段。但是职业安全培训效果如何,目前尚无有效的定量评估方法。针对安全培训这个复杂的多因素、多变量、多层次系统,通过对影响培训效果的各因素以及因素之间的相互联系进行系统深入的分析,建立起科学、全面和客观的评价指标体系;通过运用层次分析法(AHP)法,合理准确地确定各评价因素的权重,在此基础上运用模糊数学基本理论构建职业安全培训效果定量评估模型;并通过案例加以应用,表明该模型的评价结果能较好地反映实际情况,对于提高和改善培训质量,降低事故风险,具有重要的应用价值。 相似文献
946.
Chitosan is a natural high molecular polymer made from crab, shrimp and lobster shells. When used as coagulant in water treatment, not like aluminum and synthetic polymers, chitosan has no harmful effect on human health, and the disposal of waste from seafood processing industry can also be solved. In this study the wastewater from the system of cleaning in place (CIP) containing high content of fat and protein was coagulated using chitosan, and the fat and the protein can be recycled. Chitosan is a natural material, the sludge cake from the coagulation after dehydrated could be used directly as feed supplement, therefore not only saving the spent on waste disposal but also recycling useful material. The result shows that the optimal result was reached under the condition of pH 7 with the coagulant dosage of 25 mg/l. The analysis of cost-effective shows that no extra cost to use chitosan as coagulant in the wastewater treatment, and it is an expanded application for chitosan. 相似文献
947.
948.
服务期的法律定性和法律后果 总被引:2,自引:0,他引:2
案例
张某自2000年进入某公司工作,任公司技术开发部副主任,劳动合同每年签订一次.2001年,张某参与了公司的技术开发工作,9月12日与公司签订《技术保密协议》.约定:保密产品主要为公司已在生产和开发成功的各类浸渍手套. 相似文献
949.
Ming-Song Tsai Fa-Kung Lee Chih-Chien Cheng Kuo-Yuan Hwa Mei-Leng Cheong Bo-Quing She 《黑龙江环境通报》2002,22(9):747-751
Increased fetal nuchal translucency (NT) in the first trimester is associated with adverse pregnancy outcomes. Whether the increased NT is also associated with an increased frequency of pregnancy-associated hypertension (PAH) is not known. Seven hundred and seventy-nine pregnant women who received NT-based Down syndrome screening and delivered their babies at our hospital by September 2000 were enrolled into this study. Among these women, there are 46 cases of preeclampsia, 68 cases of gestational hypertension (GH); 665 women without any adverse pregnancy outcomes served as controls. Correlation analysis demonstrated that NT MoM (multiples of median) level had a positive association with maternal diastolic blood pressure at the time of admission for delivery (r = 0.104; p < 0.01). The severity of PAH was concordant with the stepwise increase of mean NT MoM level, which was 0.88 in control, 1.07 in gestational hypertension, and 1.13 in preeclampsia (p < 0.001). Using the 95th (1.52 MoM) and 90th (1.31 MoM) percentiles of NT thickness as cut-offs, the sensitivities and odds ratios of the women at risk for developing GH after 20 weeks of gestation were 8.8%, 19.1% and 1.98, 2.15 respectively, while for preeclampsia were 10.9%, 28.3% and 2.49, 3.58 respectively. It is concluded that the pathological changes in the placenta responsible for the development of PAH may also influence the physiological decrease of NT thickness in late first trimester. However, the sensitivity of fetal NT measurement in first trimester is not sufficient as a single marker for predicting the pregnant women at risk for subsequent PAH. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
950.