Preparation of rare-earth metal complex oxide catalysts for catalytic wet air oxidation

Catalytic wet air oxidation (CWAO) is one of the most promising technologies for pollution abatement. Developing catalysts with high activity and stability is crucial for the application of the CWAO process. The Mn/Ce complex oxide catalysts for CWAO of high concentration phenol-containing wastewater were prepared by coprecipitation. The catalyst preparation conditions were optimized by using an orthogonal layout method and single-factor experimental analysis. The Mn/Ce serial catalysts were characterized by Brunauer-Emmett-Teller (BET) analysis and the metal cation leaching was measured by inductively coupled plasma torch-atomic emission spectrometry (ICP-AES). The results show that the catalysts have high catalytic activities even at a low temperature (80°C) and low oxygen partial pressure (0.5 MPa) in a batch reactor. The metallic ion leaching is comparatively low (Mn<6.577 mg/L and Ce<0.6910 mg/L, respectively) in the CWAO process. The phenol, COD_Cr, and TOC removal efficiencies in the solution exceed 98.5% using the optimal catalyst (named CSP). The new catalyst would have a promising application in CWAO treatment of high concentration organic wastewater.     

指导小儿合理用药的几点体会

文章从三个方面讨论如何指导家长给小孩合理用药,并讨论了对家庭自备药物如何保管及如何处理小孩误服药物.     

生物氧化再生脱硫液的影响因素研究

化学-生物法脱硫中使用的脱硫液一般采用生物法氧化再生.探讨了pH、初始Fe3 浓度、硫磺、硫酸钠浓度等因素对生物氧化再生Fe3 的影响.结果表明,生物氧化再生脱硫液的最适初始pH为1.8;Fe3 对细菌生长有抑制作用,初始浓度低于1.5gL-1时对细菌抑制作用较小;硫磺的存在对Fe2 的生物氧化有很大的影响,当硫磺浓度低于2gL-1时,对细菌的影响较小;硫酸钠浓度低于15gL-1时,对生物氧化Fe2 几乎没有影响,通过驯化后,细菌可以耐受更高的硫酸钠浓度.图4表3参10     

改性活性炭吸附净化黄磷尾气中的PH3

通过钢瓶配气模拟和气相色谱GC-14C测定的方法，研究了改性活性炭吸附净化黄磷尾气中PH₃的相关问题。得到了吸附反应的最佳吸附温度、氧含量、气体流量、改性液浓度、活性炭粒径和焙烧温度。再生方法可行，可通过再生液回收磷酸。热重差热分析和孔径分布初步证明吸附质为磷和磷氧化物。     

难降解废水生物处理中的共代谢作用

综述了共代谢作用的机理、特点及研究现状，展望了共代谢在废水生物处理中的应用前景。     

西安市阎良区工程场地土层地震反应分析

本文根据西安市阎良区及周围地区的地震地质环境,在地震危险性分析的基础上,采用等效线性一维波动方法进行土层地震反应分析.计算得出50年超越概率63%、10%和2%的地面水平向峰值加速度,该结果为该地区抗震设计提供了依据,具有应用价值.     

Objective and quantitative evaluation of environmental quality of the land for agriculture purpose

An objective and quantitative evaluation method on land environmental quality for agricultural purpose in a county range is studied in this paper. The method takes into account the quantity of heat, precipitation, meteorological disaster and soil fertility, which have close relationship to the potential productivity of land and can be expressed conveniently and accurately by taking Kai County as an example. Besides comprehensive grading assessment, assessment with Hilbert Space distance coefficiency and comprehensive judgement by fuzzy sets theory, the assessment factors are expanded to 18 parameters, and fuzzy dominance matrix and fuzzy clustering methods are adopted for regional comprehensive identification of agriculture-use land. Among these methods, each benefits from association with the other. In this paper, an all-round and objective new way for understanding of land environmental quality is put forward.     

汽车磷化废水的处理工艺研究

磷酸盐是污水综合排放标准(GB8978-1996)从严控制的指标.磷酸盐过度排放会导致水体富营养化,恶化水质.目前除磷方法主要有生物法、化学法、物理化学法等.文章以成都某汽车厂的废水处理工程为例,研究了磷化废水的处理工艺及原理,表明采用物化与生化相结合的工艺处理汽车磷化废水可取得良好的处理效果.经监测,其各项指标都达到国家<污水综合排放标准>(GB8978-1996)的一级排放标准.     

上海市区道路地面氮氧化物污染现场调查

为了解城市道路地面NOx污染的状况和特征，对上海典型道路路边NOx污染进行现场实测。结果表明：在交通繁忙的路段，路边NOx污染严重。调查发现：路边NOx的浓度与交通状况有关，车流量越大，车辆阻塞时间越长，NOx的浓度越高；不同类型车辆对路边NOx的贡献不同，大型车和中型车的贡献要比小型车、摩托车和助动车大得多；路边空气污染和影响因素与传统空气监测数据有较大差别。     

Enhanced photocatalytic activity of nanotube-like titania by sulfuric acid treatment

IntroductionTiO2 nanotubehaswidelydrawnmuchattentionduetoitslargesurfaceareaandhighphotocatalyticactivity ,becausetheyhavegreatpotentialforsuchapplicationsasenvironmentalpurification ,decompositionofcarbonicacidgas,andgenerationofhydrogengas .Titaniananot…