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211.
Acute toxicity of benzene derivatives to the tadpoles (Rana japonica) and QSAR analyses 总被引:2,自引:0,他引:2
Acute lethal toxicity (the negative logarithm of molar concentrations of 12 h acute median lethal, expressed as 12 h-log1/LC50) of 46 benzene derivatives to Rana japonica tadpoles was determined. 1-octanol/water partition coefficient (logKow)-dependent models were developed to study the toxicity of different categories chemicals. In an effort to model all chemicals, response surface analyses and stepwise multiple regression analyses were performed and successful models were obtained. A general and robust QSAR model was achieved with the combined application of variables reflecting hydrophobicity, electric property, and molecular size respectively (12h-log1/LC50 = 0.393logKow - 0.428Elumo + 0.0110Vol. + 1.362 n = 51, r2 = 0.834) using stepwise multiple regression analyses. Because of strong dissociation of carboxyl group greatly decreasing their observed toxicity, using logDow in instead of logKow the quality of the models is greatly improved. The conventional r2 and cross-validation r2(CV) were 0.914 and 0.785, respectively, indicating that QSAR was both internally consistent and highly predictive. 相似文献
212.
生活水污泥油化试验研究 总被引:10,自引:0,他引:10
用碳酸钠与污泥混合,在压力4 ̄5kgf/cm^2、温度300 ̄450℃获得燃料油16%左右,气体各C1 ̄C3烃类占体积的约19%,臭气物质主要10种。 相似文献
213.
玉米秸秆生物炭固化细菌对镉砷吸附 总被引:4,自引:2,他引:2
为了确保细菌对镉砷复合污染土壤的修复效果,对细菌进行固定化处理.本研究将细菌悬液(Delftia sp. B9, B9)、玉米秸秆生物炭(corn stalks biochar,CSB)以及玉米秸秆生物炭-细菌复合体(corn stalks biochar-bacteria complex,B-CSB)作为3种吸附材料,探究3种材料对镉和砷的吸附特性及pH对3种材料去除水中镉砷离子性能的影响,进行了等温吸附模型拟合,并采用扫描电镜(SEM)、傅里叶红外变换光谱(FT-IR)和X射线光电子能谱分析(XPS)对3种材料进行表征分析,同时探究添加B9、 CSB和B-CSB对土壤中镉和砷形态变化的影响.结果表明, 3种材料对Cd~(2+)的饱和吸附量分别为49.43、 82.68和75.38 mg·g~(-1);对As的饱和吸附量分别为24.67、 42.92和34.03 mg·g~(-1).添加B-CSB可使土壤中的弱酸可溶态Cd显著下降,残渣态Cd显著增加;铁型砷含量显著减少,残渣态砷含量增加.B-CSB是一种更有效地修复镉砷复合污染的材料. 相似文献
214.
Thomas JE Allen LH McCormack LA Vu JC Dickson DW Ou LT 《Journal of environmental science and health. Part. B》2004,39(5-6):709-723
The fumigant 1,3-dichloropropene (1,3-D) is considered to be a potential replacement for methyl bromide when methyl bromide is phased out in 2005. This study on surface emissions and subsurface diffusion of 1,3-D in a Florida sandy soil was conducted in field beds with or without plastic covers. After injection of the commercial fumigant Telone II by conventional chisels to field beds at 30cm depth which were covered with polyethylene film (PE), virtually impermeable film, or no cover (bare), (Z)- and (E)-1,3-D rapidly diffused upward. Twenty hours after injection, majority of (Z)- and (E)-1,3-D had moved upward from 30 cm depth to the layer of 5-20 cm depth. Downward movement of the two isomers in the beds with or without a plastic cover was not significant. (Z)-1,3-D diffused more rapidly than (E)-1,3-D. Virtually impermeable films (VIF) had a good capacity to retain (Z)- and (E)-1,3-D in soil pore air space. Vapor concentrations of the two isomers in the shallow subsurface of the field bed covered with VIF were greater than that in the two beds covered with polyethylene film (PE) or no cover (bare). In addition, VIF cover provided more uniform distribution of (Z)- and (E)-1,3-D in shallow subsurface than PE cover or no cover. Virtually impermeable film also had a better capability to retard surface emissions of the two isomers from soil in field beds than PE cover or no cover. 相似文献
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216.
Sediments are increasingly recognized as both carrier and potential source of contaminants in aquatic environments. This study investigated the characteristics and spatial distribution of total chlordane and its three most abundant compounds, including alpha-chlordane, gamma-chlordane, and trans-nonachlor, in sediments from the Cedar and Ortega rivers, Florida, USA, using geographic information system (GIS)-based kriging analyses and field measurements. Kriging analysis showed that two areas, one from the Cedar River area and the other from the northern end of the Ortega River area, were contaminated. The maximum concentrations of total chlordane, gamma-chlordane, alpha-chlordane, and trans-nonachlor in the sediments were, respectively, 101.8, 20.1, 26.3, and 19.2 microg/kg. A plot of total organic carbon (TOC)-normalized chlordane concentrations showed that effects of grain size on sediment chlordane contamination were negligible. A principal axis analysis further revealed that a linear correlation existed between alpha-chlordane and total chlordane as well as between gamma-chlordane and total chlordane, whereas no correlation existed between trans-nonachlor and total chlordane. Comparison of total chlordane concentration with Florida Sediment Assessment Guidelines showed that the Cedar River and the northern end of the Ortega River had total chlordane concentrations above the probable effect level (4.79 microg/kg), which could pose a potential risk to aquatic life. 相似文献
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219.
本文以文献中提出的结构体系可靠度分析的最弱失效模式法为基础,充分考虑结构体系的造价和结构的损失期望与结构体系可靠度的关系,以及结构构件的可靠度约束,提出了结构体系目标可靠度的优化决策方法;基于优化决策的结果,提出了结构体系的最优设计准则;最后,依所提出的最优设计准则,实现了高层建筑基于构件和结构可靠度约束的结构优化设计。 相似文献
220.
丹江口库区及上游生态系统土壤保持效益价值评估 总被引:1,自引:0,他引:1
以RUSLE为模型的基本框架,以GIS、RS软件为技术平台,利用GIS强大的空间数据组织分析运算能力,将项目规划区各土壤侵蚀影响因子的遥感数据与非遥感数据网格化,通过网格数据的空间分析和模型运算,实现生态系统土壤保持量的区域性宏观定位定量评价。估算结果表明:研究区土壤保持总量林地最高,草地次之,水域等其它类型土壤保持量都非常少,这与植被覆盖度和植被净第一性生产力的分布是一致的,说明高植被覆盖类型分布区的植被能有效防止和控制土壤流失。1987、2000和2008年不同土地利用/覆被类型土壤保持价值分别为355.21亿元3、41.37亿元和367.41亿元。其中林地和灌木林地生态系统的土壤保持价值占到近60%,草地生态系统占到近30%,林、灌、草共占到服务总价值的近90%,林、灌、草在土壤保持生态系统服务中具有决定性的作用。 相似文献