Assessment of Groundwater Quality and Contamination from Uranium-Bearing Black Shale in Goesan–Boeun Areas, Korea

This study was initiated to identify the impact of metals and uranium enriched soil and black shale in groundwater quality and contamination. From a Piper diagram, groundwater was classified into four types as (Ca+Mg)–HCO₃ type, (Ca+Mg)–SO₄ type, the mixed type of these two and Na–HCO₃ type, reflecting the complicated nature of geology of the study area. Silicate weathering appeared to be the major water–rock interaction. In groundwater, metals including Cr, Pb, Cu and V, previously identified as being enriched in soils and black shale, were much lower in concentrations than Korean and US EPA drinking water guidelines. Instead, Fe and Mn caused major water-quality problems. In the artesian groundwater from an abandoned uranium mine, the uranium concentration was 21.3 µg L^–1, slightly higher than EPA guidelines of 20 µg L^–1. Heavy metals in groundwater appeared to be controlled mostly by sorptions on to Fe- and Mn-oxyhydroxides. They could be remobilised in groundwater with changes of pH and Eh conditions due to acid mine drainage from black shale or the recharge of fresh water. Uranium would be associated with carbonate and sulphate complexes in groundwater. Because of the remaining water-quality problems in the study area, we suggested containment of identified mine wastes, considering remedial measures for local problems with Fe and Mn, continuous monitoring of groundwater and developing groundwater from deep aquifers.     

WATER MANAGEMENT AND N,P LOSSES FROM PADDY FIELDS IN SOUTHERN KOREA1

ABSTRACT: Assessment and control of nutrient losses from paddy fields is important to protect water quality of lakes and streams in Korea. A four‐year field study was carried out to investigate water management practices and losses of nitrogen (N) and phosphorus (P) in rice paddy irrigation fields in southern Korea. The amount and water quality of rainfall, irrigation, surface drainage, and infiltration were measured and analyzed to estimate inputs and losses of N and P. The observed irrigation amount surpassed consumptive use, and approximately 52 to 69 percent of inflow (precipitation plus irrigation) was lost to surface drainage. Field data showed that significant amounts of irrigation water and rainfall were not effectively used for rice paddy culture. Water quality data indicated that drainage from paddy fields could degrade the recipient water environment. The nutrient balance indicated that significant amounts of nutrients (29.5 percent of total N and 8.6 percent of total P compared to input) were lost through surface drainage. Furthermore, up to half the nutrient losses occurred during nonstorm periods. The study results indicate that inadequate water management influences N and P losses during both storm and nonstorm periods. Proper water management is required to reduce nutrient losses through surface drainage from paddy fields; this includes such measures as minimum irrigation, effective use of rainfall, adoption of proper drainage outlet structures, and minimized forced surface drainage.     

Conflict,justice, and inequality: Why perceptions of leader–member exchange differentiation hurt performance in teams

To better understand why leader–member exchange (LMX) differentiation in teams may be detrimental to individual and team performance, we propose that team members' perception of LMX differentiation (PLMXD) is more important than statistical measures of LMX differentiation. Specifically, we hypothesize a multilevel model in which relationship conflict and procedural justice (climate) mediate the relationships of individual and collective PLMXDs with individual and team performance, respectively. Using a sample of 235 individuals in 53 teams, we found that individual PLMXD was negatively related to individual performance through relationship conflict perceptions, controlling for LMX. At the team level, collective PLMXD was negatively related to team performance through procedural justice climate and relationship conflict, controlling for a statistical measure of LMXD. Theoretical implications and directions for future research are explored.     

Submerged arc plasma system combined with ozone oxidation for the treatment of wastewater containing non-degradable organic compounds

• Submerged arc plasma was introduced in terms of wastewater treatment. • Ozone oxidation was coupled with submerged arc plasma system. • Ozone was converted into O and O₂ by submerged arc plasma. • Decomposition rate was accelerated by submerged arc plasma. • Introduction of ozone led to significant increase in mineralization. Submerged arc plasma technology was assessed for the removal of phenols from wastewater. The OH radicals generated from the boundary between the plasma and waste solution were considered as a significant factor on the degradation reaction. In this study, the effects of highly energetic electrons released from the submerged arc plasma were mainly studied. The highly energetic electrons directly broke the strong chemical bond and locally increased the reaction temperatures in solution. The effects of the submerged-arc plasma on the decomposition of phenol are discussed in terms of the input energy and initial concentration. The single use of submerged arc plasma easily decomposed the phenol but did not increase the mineralization efficiency. Therefore, the submerged arc plasma, coupled with the ozone injection, was investigated. The submerged arc plasma combined with ozone injection had a synergic effect, which led to significant improvements in mineralization with only a small increase in input energy. The decomposition mechanism of phenol by the submerged arc plasma with the ozone was analyzed.     

Rewards and employee creative performance: Moderating effects of creative self‐efficacy,reward importance,and locus of control

The effects of extrinsic rewards on creative performance have been controversial, and scholars have called for the examination of the boundary conditions of such effects. Drawing upon expectancy theory, we attend to both reinforcement and self‐determination pathways that reveal the informational and controlling functions of creativity‐related extrinsic rewards. We further identify the individual dispositions that moderate these two pathways. Specifically, we propose that extrinsic rewards for creativity positively predict creative performance only when employees have high creative self‐efficacy and regard such rewards as important. We likewise propose that extrinsic rewards positively affect the intrinsic motivation of employees with an internal locus of control, thus enhancing their creative performance. Results based on a sample of 181 employee–supervisor dyads largely supported these expectations. The current analysis enriches the creativity literature by combining different perspectives in a coherent framework, by demonstrating the positive effects of extrinsic rewards on intrinsic motivation, and by demonstrating that the rewards–creativity relationship varies across employees depending on their individual differences. Copyright © 2014 John Wiley & Sons, Ltd.     

Self‐efficacy changes in groups: effects of diversity,leadership, and group climate

Self‐efficacy belief is a significant predictor of behavioral choices in terms of goal setting, the amount of effort devoted to a particular task, and actual performance. This study conceives of formation and change of self‐efficacy as a social and context‐dependent process. We hypothesized that different group factors (discretionary and ambient group stimuli) influence changes in members' self‐efficacy through differing routes (individual‐level and cross‐level processes). We tested our hypotheses using data from individuals in 169 training groups who attended a 5‐day workshop designed to increase participants' job‐search skills and efficacy. Specifically, we examined the degree of change in participants' job‐search efficacy before and after the workshop. The results showed that (a) membership diversity in education was positively related to increases in job‐search efficacy, (b) supportive leadership contributed to job‐search efficacy at the individual level of analysis with no cross‐level effects, and (c) open group climate contributed to job‐search efficacy through both individual‐level and cross‐level processes. Limitations and directions for future research are discussed. Copyright © 2003 John Wiley & Sons, Ltd.     

Transfer of 90Sr to rice plants after its acute deposition onto flooded paddy soils

The transfer of 90Sr to rice plants following its acute ground deposition was examined experimentally in a greenhouse. Lysimeters were flooded after being filled with the soil monoliths from 12 paddy fields. A solution of 90Sr was applied to the standing water in the flooded lysimeters at the pre-transplanting stage or booting stage. Applied 90Sr was mixed with the topsoil only after the pre-transplanting application (PTA). The transfer was quantified with the areal transfer factor (TF(a), m2 kg(-1)-dry) defined as the ratio of the plant concentration to the initial ground deposition. In the PTA, the first-year TF(a) values in the 12 soils were in the range of 8.2 x 10(-3) -2.1 x 10(-2) and 1.7 x 10(-4) -3.6 x 10(-4) for the straws and hulled seeds, respectively. The TF(a) values from the booting-stage application (BSA) were higher than those from the PTA by a factor of up to four. The ratios of the seed TF(a) to the straw TF(a) were, on the whole, higher in the BSA. The 90Sr TF(a) in the PTA was negatively correlated with the soil pH and, to a lesser degree, the exchangeable Ca content. In the second year, the TF(a) in the PTA reduced to 53-90% of that in the first year. A more significant reduction, in general, occurred in a sandier soil. Based on the four consecutive years' transfer data, an overall half-time of the 90Sr TF(a) was estimated to be 2.2 years.     

Cytotoxicity, genotoxicity and ecotoxicity assay using human cell and environmental species for the screening of the risk from pollutant exposure

For the screening of the risk from environmental contamination, the cytotoxic/genotoxic effects of various model pollutants were determined using an in vivo system comprised of human HeLa cells; the ecotoxicity was also determined using the acute and genotoxicity tests on two aquatic sentinel species widely used in biomonitoring, namely, freshwater crustacean, Daphnia magna and larva of aquatic midge, Chironomus tentans. Nonylphenol (NP), bisphenol A (BPA), bis(2-ethylhexyl) phthalate (DEPH) and paraquat dichloride (PQ) were used as the model pollutants. The results showed that exposure of HeLa cells to NP, BPA and DEHP was sufficient for the expression of noticeable genotoxic and cytotoxic effects. Ecotoxicity results showed that, as expected, D. magna was more sensitive than C. tentans to chemical exposure. BPA may exert a genotoxic effect on D. magna and C. tentans, given that DNA strand breaks increased in both species exposed to this compound, whereas NP-induced DNA damage occurred only in C. tentans. In vivo genotoxic data obtained in aquatic sentinel species could provide valuable information for freshwater quality monitoring. From the results of the present study, the use of cytotoxic, genotoxic and ecotoxic tests using human cell system, as well as, biomonitoring species, seems to be relevant for preliminary evaluation of the human health and ecological effects of pollutants and thus, a promising screening tool for environmental monitoring and risk assessment.     

Uptake of radionuclides and stable elements from paddy soil to rice: a review

The critical paths for radionuclides and the critical foods in Asian countries differ from those in Western countries because agricultural products and diets are different. Consequently, safety assessments for Asian countries must consider rice as a critical food. As most rice is produced under flooded conditions, the uptake of radionuclides by rice is affected by soil conditions. In this report, we summarize radionuclide and stable element soil-to-plant transfer factors (TFs) for rice. Field observation results for fallout ¹³⁷Cs and stable Cs TFs indicated that while fallout ¹³⁷Cs had higher TF than stable Cs over several decades, the GM (geometric mean) values were similar with the GM of TF value for ¹³⁷Cs being 3.6 × 10⁻³ and that for stable Cs being 2.5 × 10⁻³. Although there are some limitations to the use of TF for stable elements under some circumstances, these values can be used to evaluate long-term transfer of long-lived radionuclides in the environment. The compiled data showed that TF values were higher in brown rice than in white rice because distribution patterns for elements were different in the bran and white parts of rice grains.     

Full-scale experience for nitrogen removal from piggery waste.

The nitrogen-removal performances of three full-scale piggery wastewater treatment plants, with different organic and nitrogen loads, at the capacity ranges of 95 to 130 m3/d, were compared in this study. Plants 1 and 2 can be characterized as the modification of anoxic-aerobic operating systems, while an anaerobic and anoxic-aerobic system was used in plant 3. The influent piggery wastewater concentration for plant 1 was relatively lower, but with higher organic and nitrogen loads, resulting in higher chemical oxygen demand (COD) and ammonium-nitrogen in effluent. Plant 2 was operated with strong piggery wastewater, resulting in a higher operating temperature. The high temperature could inhibit the nitrifying activity in plant 2. Although plant 3 was operated with a higher influent total COD-to-total Kjeldahl nitrogen ratio (TCOD:TKN), an additional external carbon source was required to polish the final effluent to remove nitrogen. Influent COD in plant 3 was used in the anaerobic-anoxic reactor for both methane (CH4) production and denitrification. Based on various mass balances, including caloric, COD, and alkalinity, the key elements for the successful nitrogen removal from the piggery waste were reactor temperature (less than 35degrees C), influent TCOD:TKN (greater than 6), and alkalinity-to-TKN ratio (greater than 3).