Determination of solid-liquid partition coefficients (Kd) for the herbicides isoproturon and trifluralin in five UK agricultural soils

Isoproturon and trifluralin are herbicides of contrasting chemical characters and modes of action. Standard batch sorption procedures were carried out to investigate the individual sorption behaviour of 14C-isoproturon and 14C-trifluralin in five agricultural soils (1.8-4.2% OC), and the soil solid-liquid partition coefficients (Kd values) were determined. Trifluralin exhibited strong partitioning to the soil solid phase (Kd range 106-294) and low desorption potential, thus should not pose a threat to sensitive waters via leaching, although particle erosion and preferential flow pathways may facilitate transport. For isoproturon, soil adsorption was low (Kd range 1.96-5.75) and desorption was high, suggesting a high leaching potential, consistent with isoproturon being the most frequently found pesticide in UK surface waters. Soil partitioning was directly related to soil organic carbon (OC) content. Accumulation isotherms were modelled using a dual-phase adsorption model to estimate adsorption and desorption rate coefficients. Associations between herbicides and soil humic substances were also shown using gel filtration chromatography.     

Risky, aggressive, or emotional driving: addressing the need for consistent communication in research

Problem. Researchers agree that a consistent definition for aggressive driving is lacking. Such definitional ambiguity in the literature impedes the accumulation of accurate and precise information, and prevents researchers from communicating clearly about findings and implications for future research directions. This dramatically slows progress in understanding the causes and maintenance factors of aggressive driving. Summary. This article critiques prevailing definitions of driver aggression and generates a definition that, if used consistently, can improve the utility of future research. Pertinent driving behaviors have been variably labeled in the literature as risky, aggressive, or road rage. The authors suggest that the term “road rage” be eliminated from research because it has been used inconsistently and has little probability of being clarified and applied consistently. Instead, driving behaviors that endanger or have the potential to endanger others should be considered as lying on a behavioral spectrum of dangerous driving. Three dimensions of dangerous driving are delineated: (a) intentional acts of aggression toward others, (b) negative emotions experienced while driving, and (c) risk-taking. Impact on Industry. The adoption of a standardized definition for aggressive driving should spark researchers to use more explicit operational definitions that are consistent with theoretical foundations. The use of consistent and unambiguous operational definitions will increase the precision of measurement in research and enhance authors' ability to communicate clearly about findings and conclusions. As this occurs over time, industry will reap benefits from more carefully conducted research. Such benefits may include the development of more valid and reliable means of selecting safe professional drivers, conducting accurate risk assessments, and creating preventative and remedial dangerous driving safety programs.     

IMPROVEMENT OF LEACHATE PREDICTION THROUGH MUNICIPAL SOLID WASTE LAYERS1

ABSTRACT: Existing leachate prediction models over- or underestimate leachate generation by up to three orders of magnitude. Practical experiments show that channeled flow in waste leads to rapid discharge of large leachate volumes and heterogeneous moisture distributions. In order to more accurately predict leachate generation, leachate models must be improved. To predict moisture movement through waste, the one-domain water balance model HELP, and two-domain PREFLO, are tested. Experimental waste and leachate flow values are compared with model predictions. When calibrated with experimental parameters, the HELP model yields reasonable predictions of cumulative leachate flow and PREFLO provides estimates of breakthrough time. In the short term, field capacity has to be reduced to 0.12 and effective storage and hydraulic conductivity of the waste must be increased to 0.2 and 2.2 cm/s respectively. In the long term, a new modeling approach must be developed to adequately describe the moisture movement mechanisms.     

Sustainable environmental careers and industries in the reengineering/EMS era

Environmental business and environmental professionals within industry will face unprecedented challenges in the late 1990s. The strategies of Business Process Reengineering (BPR) and Environmental Management Systems (EMSs) will require integrating environmental processes into mainstream business systems and reducing the role for “pure” environmental processes. This article describes some of the new skills that employees and consultants will need to learn in order to provide value to the customer's core business.     

A prototype expert system for fishway design

The design of structures for fish passage in rivers and streams provides an opportunity to apply expert system concepts to a design problem. Fishways contribute to the sustainable development of water resources projects by providing a path that allows fish migrations to be maintained. A prototype expert system (FDES) has been developed to recommend the most suitable fishway type for given design conditions. A recommendation is provided on the basis of fishway hydraulics, fish passage performance, and cost requirements. Fishway design demands expertise in various scientific disciplines such as hydrology, hydraulics, and fish biology. Expert system technology may be used to reduce design time requirements and to serve as a teaching aid to inexperienced engineers by organizing and accessing the cumulative knowledge of the most experienced designers. The rule-based expert system development tool, VP-Expert, supplies the backward chaining control structure for accessing the knowledge within the prototype.     

Application of a Sediment Quality Index to the Lower Laurentian Great Lakes

A sediment quality index (SQI) was developed using an equation incorporating three elements; scope--the % of variables that did not meet guidelines; area frequency--the % of failed tests divided by the total number of tests in a group of sites; and amplitude - the magnitude by which failed variables exceeded guidelines. The SQI calculation produces a numerical score with a maximum value of 100 representing the highest sediment quality. A modified SQI was also developed using only the scope and amplitude elements, which computed a score per site with no grouping. The SQI was applied to assessment of sediment quality in Lakes Erie and Ontario using Canadian Federal and Ontario Provincial guidelines for 34 compounds, Spatial trends in sediment quality in both lakes reflected overall trends for most individual contaminant classes, including mercury and polychlorinated biphenyls. In Lake Erie, there was a trend toward lower SQI values from the eastern basin to the western basin, and from the northern area to the southern area of the central basin. Sediment quality in the eastern basin and the northern area of the central basin was classified as excellent (>95); sediments in other areas of Lake Erie ranged from fair to good. In Lake Ontario, the poorest sediment quality was associated with the three major depositional basins; sediment quality among the three basins was quite consistent. The SQI values based on all three elements (scope, frequency and amplitude) for the Niagara basin. Mississauga Basin and Rochester Basin were 67 (fair), 65 (fair) and 70 (fair), respectively. Comparison of SQI values for all lower lake basins showed generally poorer sediment quality in Lake Ontario, compared to Lake Erie.     

Saturated and Unsaturated Water Flow in Inclined Porous Media

This paper considers the two-dimensional saturated and unsaturated flow of water through inclined porous media, namely a waste dump or hill slope. Since the partial differential equation governing this water flow transforms from being parabolic to elliptic as the water flow varies from unsaturated to saturated, an iterative, finite differencing scheme is used to develop a numerical solution. The model can be used to investigate the effects that hill slope angle, depth of soil cover and hilltop width have on water accumulation in the dump and the time required for saturation to occur at different areas in the dump domain. The accuracy and reliability of the computer based solution is tested for two different boundary conditions – (1) no flow on all boundaries (i.e., the internal redistribution of soil moisture to steady state) and (2) a constant rainfall flux on the dump surface. Numerical studies then show the effects of changing the hill slope angle, depth of layer, and dump geometry on the flow characteristics in the dump.     

Book reviews

The Economics of Art and Culture: An American Perspective

James Heilbrun & Charles M. Gray

New York, Cambridge University Press, 1993, 378 pp., £14.95 pb

Building Cities that Work

Edmund Fowler

Montreal & Kingston, McGill‐Queen's University Press, 1992, 315 pp.

Interactive Decision Making: The Graph Model for Conflict Resolution

Liping Fang, Keith W. Hipel & D. Marc Kilgour

New York, Wiley, 1993, 221 pp., £49.50

The Politics of Nature: Explorations in Green Political Theory

Andrew Dobson & Paul Lucardie (Eds)

London, Routledge, 1993, 240 pp. + xv, £37.50

Urban Transport in Asia: An Operational Agenda for the 1990s, World Bank

Technical Paper No. 224

Peter Midgley

Washington, DC, The World Bank, 1994, 98 pp.

Landscape Ecology: Theory and Application, 2nd edition

Zev Naveh & Arthur Lieberman

New York, Springer‐Verlag, £34.50     

Retrieval And Monitoring of Atmospheric Trace Gas Concentrations in Nadir and Limb Geometry Using the Space-Borne Sciamachy Instrument

The Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) onboard the European Envisat spacecraft performs continuous spectral observations of reflected, scattered and transmitted sunlight in various observation geometries. A unique feature of SCIAMACHY is the capability of probing the atmosphere in three different observation geometries:The nadir, limb, and occultation measurement modes. In nadir mode, column densities of trace gases are retrieved with a spatial resolution of typically 30× 60 km using the Differential Optical Absorption Spectroscopy (DOAS) technique (Platt and Perner, 1983). Alternating with the nadir measurement, vertical profiles of absorber concentration in the stratosphere are derived in limb and occultation. In this paper we present an overview over some applications of SCIAMACHY data in space-based monitoring of atmospheric pollution. The DOAS algorithms for the retrieval of total column amounts from nadir spectra are briefly described and case studies of pollution events are presented. We also illustrate the technique used to derive stratospheric concentration profiles from limb observations and show comparisons with other remote sensing systems. Special emphasis will be given to techniques, which take advantage of SCIAMACHY's different viewing geometries. In particular, we will discuss the potential and limits of strategies to infer tropospheric abundances of O₃and NO₂.