Anaerobic degradation of diethyl phthalate, di-n-butyl phthalate, and di-(2-ethylhexyl) phthalate from river sediment in Taiwan

We investigated anaerobic degradation rates for three phthalate esters (PAEs), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), and di-(2-ethylhexyl) phthalate (DEHP), from river sediment in Taiwan. The respective anaerobic degradation rate constants for DEP, DBP, and DEHP were observed as 0.045, 0.074, and 0.027 1/day, with respective half-lives of 15.4, 9.4, and 25.7 days under optimal conditions of 30 °C and pH 7.0. Anaerobic degradation rates were enhanced by the addition of the surfactants brij 35 and triton N101 at a concentration of 1 critical micelle concentration (CMC), and by the addition of yeast extract. Degradation rates were inhibited by the addition of acetate, pyruvate, lactate, FeCl₃, MnO₂, NaCl, heavy metals, and nonylphenol. Our results indicate that methanogen, sulfate-reducing bacteria, and eubacteria are involved in the degradation of PAEs.     

Surface Consolidation of Pentelic Marble: Criteria for the selection of methods and materials - The Acropolis case (6 pp)

Goal and Scope In order to realize surface consolidation of Pentelic marble on the Acropolis monuments, we have collected the criteria that have to be fulfilled by the methods and materials without side effects on the marbles (and other stones). When the existing methods and materials did not satisfy the requirements (criteria), we invented new ones.Methods The criteria were collected from the literature, by thermodynamic and kinetic viewpoints, by laboratory experiments and in situ observations on monuments, both in Greece and in several countries in which the various methods and materials were applied. Concerning our method of ‘Inversion of sulfation’, performed by spraying a K2CO3 solution, its concentration and its temperature were controlled in order to have a total inversion (certified by liquid crystals) of gypsum back to CaCO3. For the new material of ours, ‘Reinforced Lime’, in order to eliminate the disadvantages of plain lime (low carbonation rate, low mechanical properties of CaCO3 formed, lack of carbonation in the bulk of lime), measurements of the rate of carbonation were performed in plain lime and in lime with a different CaCO3 concentration beforehand as well as in a different CO2 environments, using DTG and XRD to measure the rate of carbonation. The detachment (kg/cm2) of marble specimens stuck by lime in each case was also measured. A microscope was also used to measure the dimensions of the grain in each case as well as ammonium citrate and thymolphthalein to certify the depth of carbonation in each case. Part of the work was communicated in an international congress.Results A table with the criteria of the selection of the methods and materials for the consolidation of Pentelic marble surfaces (and other stones) was established. None of the employed methods and materials fulfilled the criteria. Only the ‘Inversion of gypsum ‘ and the ‘Reinforced Lime’ were adopted and applied to the Acropolis monuments and to other monuments in Greece and in several other countries.Recommendation and Outlook All criteria must be used for the selection of methods and materials for the consolidation of the monument surfaces. This is why we have already studied with the same procedures, methods and materials for restoration, surface cleaning and protection.     

Idiosyncratic deals in contemporary organizations: A qualitative and meta‐analytical review

Idiosyncratic deals (i‐deals) research focuses on the emergence of customized work arrangements employees negotiate with their employers. This article provides a critical review and synthesis of i‐deals research, combining a qualitative review of i‐deals theory and research with a supplementary meta‐analysis of 23 empirical studies (k = 27 samples, N = 8110 individuals). The qualitative review examines the conceptualization and measurement of i‐deals and identifies patterns and gaps in i‐deals research, while the quantitative meta‐analysis tests the moderating effect of societal cultures on the predictors and consequences of ideals investigated to date. In each section, attention is given to strengths and weaknesses of current approaches to i‐deals theory and research. Future research directions are identified with particular emphasis on the largely unexamined role of i‐deals from a multilevel perspective. Copyright © 2014 John Wiley & Sons, Ltd.     

Trends in environmental education for biodiversity conservation in Costa Rica

Costa Rica is internationally recognized for its abundant biodiversity and being a leader in the promotion of education strategies for biodiversity conservation. We interviewed staff from 16 institutions developing key environmental communication, education, and participation projects for biodiversity conservation in the country. Through content analysis, hierarchical cluster analysis and Chi-square tests, we examined the characteristics of the projects carried out by these institutions and developed a typology of four categories derived from six variables: primary audience, content, project purpose, location, scale, and facility. Then, we designed a conceptual model describing the integration of conservation and economic development in the educational projects. We found two key approaches related to this integration: vision of nature protection which aims to inform audiences of ecological concepts and focuses on schoolchildren and vision of sustainability which engages adult audiences and is management-oriented. Education for community-based environmental management may serve as a good example of educational projects which integrate conservation and economic development, implementing a vision of sustainability.     

Effectiveness of EMS in Tunisian companies: framework and implementation process based on ISO 14001 standard

This paper reports environmental analysis results of food and tannery Tunisian companies to identify the features of environmental management system (EMS) that is implemented recently. EMS via ISO 14001 has become one of the principal tools used by companies to handle environmental aspects and impacts through their various complex activities interacted with environment. While several companies have implemented and maintained a formal EMS, it has related mainly to their benefits in short term without responding to the sustainable development recommendations and practices. This study focuses on the strong linkage between the EMS effectiveness of food–tannery Tunisian companies and sustainability. A proactive environmental management approach is proposed and adopts a qualitative and quantitative assessment for factor analysis. It provides a strategic EMS framework and principles for sustainability to evolve the future enterprises’ benefits that has a clear influence on environmental performance in long term.     

The methylic versus the ethylic route: considerations about the sustainability of Brazilian biodiesel production

Brazil is considered one of the world’s leading producers of biofuels given the predominance of ethanol fuel in its energy matrix. However, despite the prominence of Brazil in ethanol production, the vast majority of biodiesel production plants in Brazil use methanol instead of ethanol as the alcohol for transesterification reaction, as is generally the case in the rest of the world. The aim of this paper is therefore to examine the transesterification process in the Brazilian biodiesel production in terms of sustainability. In this regard, it was necessary to evaluate the way in which the industrial process is currently carried out, the role of government incentives or subsidies for the use of ethanol to produce biodiesel, and the investments of companies in technology development for the same purpose. This study presents indications that the development of the biodiesel market in Brazil is still oriented toward a production model which is inconsistent with the environmental and social aspects of sustainability.     

Factors influencing farmers’ decisions on nitrogen fertilizer application in the Liangzihu Lake basin,Central China

Overuse of nitrogen (N) fertilizers in agriculture activities has caused severe water pollution in China. The lack of data at producer level hampers decision makers in the development and implementation of efficient policies to curb excessive N-fertilizer use. In a survey of 300 farm households in the Liangzihu Lake basin, we identified factors associated with farmers’ decisions on N-fertilizer use and application rate. Household survey and multiple linear regression models indicate that the average application rate in the study region is 229 kg N ha^?1, which exceeds the recommended rate for maximum profit for cereal crops (maize, wheat, and rice) in China of 150–180 kg N ha^?1. High N-application rates are associated with low farmland productivity (coefficient = ?15.66, p = 0.02), a high share of off-farm income (coefficient = 27.14, p = 0.003), and a low education level of the household head (coefficient = ?10.83, p = 0.039). Neither physical infrastructure nor access to input markets appears to be related to N-application rates. It may be concluded that excessive use of N in agriculture of Central China is mainly a problem of insufficient awareness and high share of off-farm income.     

Design,measurement and evaluation of photovoltaic pumping system for rural areas in Oman

In the present paper, the optimum design of a PV system used to operate a water pumping system was determined for Oman. The system design focused on the environmental conditions of Sohar city. The implementation and measurement of the designed system are presented to prove the effectiveness of the proposed system. The results show that the system can provide the required power at peak hours, leading to a substantial reduction in the sizing of the PV system. Consequently, the investment capital costs 2400 USD, and the cost of energy is equal to 0.309 USD/kWh. Furthermore, the results indicate that the system annual yield factor is 2024.66 kWh/kWp and that the capacity factor is 23.05 %, which is encouraging since the latter is typically 21 %. The system capital cost and the cost of energy are worth comparing to a diesel generator. A comparison is made between the proposed system and several others in the literature. The comparison indicated that the system cost of energy is promising.     

2014, The “year without a summer” in Italy: news media coverage and implications for the climate change debate

In 2014, there was virtually no summer in northern and central-southern Italy. Storm after storm battered the peninsula, triggering floods and landslides from Veneto to Puglia. We studied the coverage of “the year without a summer” in Italy by analyzing the content of 171 news articles from two influential online newspapers. Our software-based analysis enabled us to observe that the two newspapers hardly ever mentioned climate change in their coverage of the weather anomaly that affected Italy in the summer of 2014. This type of coverage is in line with climate science, according to which there is no evidence of a climate change-related influence on summer precipitation patterns in Southern Europe—whereas such influence has been documented for northern Europe. We compared our results with a recent paper, which documented that the same online dailies chose to represent the particularly hot summer of 2012 in Italy as a direct consequence of climate change. We corroborated this comparison also on the basis of a preliminary analysis we performed on the media coverage of the exceptionally hot and arid summer of 2015 in Italy.     

Investigating soils retention ratios and modelling geochemical factors affecting heavy metals retention in soils in a tropical urban watershed

This study aimed at investigating the retention of Pb and Cd in soils and the geochemical factors influencing the adsorption of these pollutants. Soil samples were air-dried and ground to pass through a 2-mm sieve, and different soil extracts were prepared for chemical analysis (organic matter, cation exchange capacity and pH). Total Pb and Cd were extracted with diacid using digestion method and determined by atomic adsorption spectrophotometer (AAS) after filtration. Results revealed that the heavy metals retention ratio (RR) of the Rhodic ferralsol, Xanthic ferralsol and Mollic gleysol (2) were very high for Cd (>80 %) and was relatively low (generally < 60 %) for Pb. In contrast, RRs for the Plinthic gleysol and the Mollic gleysol (1) were relatively low (<60 %), regardless of the heavy metal concerned. Multiple regression equations indicated for Pb and Cd concentrations different linear relationships over simple linear regression, when pH, organic matter, clay percentage and cation exchange capacity (CEC) were used as independent variables. Results indicate that organic matter exerts major influences on the retention of Pb and Cd in soils, while CEC, clay content and pH have a minor influence in this process in the Ntem watershed. From these observations, the application of soil organic matter could be a solution in protecting shallow aquifers from heavy metal pollution and thus insuring that they are not a hazard to public health.