Chronic exposure of arsenic via drinking water and its adverse health impacts on humans

Worldwide chronic arsenic (As) toxicity has become a human health threat. Arsenic exposure to humans mainly occurs from the ingestion of As contaminated water and food. This communication presents a review of current research conducted on the adverse health effects on humans exposed to As-contaminated water. Chronic exposure of As via drinking water causes various types of skin lesions such as melanosis, leucomelanosis, and keratosis. Other manifestations include neurological effects, obstetric problems, high blood pressure, diabetes mellitus, diseases of the respiratory system and of blood vessels including cardiovascular, and cancers typically involving the skin, lung, and bladder. The skin seems to be quite susceptible to the effects of As. Arsenic-induced skin lesions seem to be the most common and initial symptoms of arsenicosis. More systematic studies are needed to determine the link between As exposure and its related cancer and noncancer end points.     

The effects of driver factors and sign design features on the comprehensibility of traffic signs

PROBLEM: This paper addresses the effects of driver factors and sign design features on the comprehensibility of traffic signs. METHODS: A survey was designed to capture subjects' personal particulars, ratings on sign features, and comprehension scores, and then administered to 109 Hong Kong full driving license holders. RESULTS: Years with driving license and education level were significant predictors of sign comprehensibility. Contrary to expectation, the driver factors of age group, years of active driving, hours of driving, last time driving, driving frequency, and non-local driving experience had no effect on comprehension performance. Sign familiarity was correlated with comprehension score for licensed drivers, whereas sign concreteness, simplicity, and meaningfulness were not. IMPACT ON INDUSTRY: The results of this study provide useful guidelines for designing more user-friendly traffic signs in the future. It identified particular driver groups who lacked good understanding of traffic signs, and this information may assist the relevant organizations to better allocate traffic training resources, and better target future studies of traffic sign comprehension.     

Comments on explosion problems for hydrogen safety

The future widespread use of hydrogen as an energy carrier brings in safety issues that have to be addressed before public acceptance can be achieved. The prediction of the consequences of a major accident release of hydrogen into the atmosphere or the contamination of high-pressure hydrogen storage facilities by air entrainment requires a good knowledge of the explosion parameters of hydrogen–air mixtures. The present paper reviews and comments on the current knowledge of dynamic parameters of hydrogen detonation for hazard assessment. The major problem that remains to be resolved involves the understanding of the effect of turbulence on the cellular detonation structure, the propagation of high-speed deflagrations and the transition from deflagration to detonations. It is recommended that future research should be aimed towards experiments that permit the quantitative understanding of the mechanisms of high-speed turbulent combustion rather towards large-scale tests in complex geometries where minimal quantitative information of fundamental significance could be extracted. In spite of its wide flammability and sensitivity to ignition and detonation initiation, it is felt that hydrogen can be produced, stored and handled safely with the appropriate considerations in the design of the hydrogen facilities.     

Examination of Salmonella and Escherichia coli translocation from hog manure to forage, soil, and cattle grazed on the hog manure-treated pasture

Use of hog (Sus scrofa) manure as a fertilizer is a practical solution for waste re-utilization, however, it may serve as a vehicle for environmental and domestic animal contamination. Work was conducted to determine whether pathogens, naturally present in hog manure could be detected in cattle (Bos taurus) grazed on the manure-treated pasture, and whether forage contamination occurred. During two 3 mo summer trials manure was applied to yield < or = 124 kg available N per hectare in a single spring or split spring and fall application. Samples of hog manure, forage, soil, and cattle feces were analyzed for naturally occurring Salmonella, Yersinia enterocolitica, and Escherichia coli. To follow movement of Salmonella in the environment isolates were identified to serovar and serotyped. Transfer of E. coli from hog manure to soil and cattle was examined by randomly amplified polymorphic DNA (RAPD) analysis of >600 E. coli isolates. While Y. enterocolitica was absent from all samples, in both years S. enterica Derby and S. enterica Krefeld were found in most hog manure samples, but were only on forage samples in the second year. Salmonella enterica Typhimurium, absent from hog manure was present on some forage in the first year. Cattle feces and soil samples were consistently Salmonella negative. These contaminations could not be traced to manure application. During this study, Salmonella and E. coli found in hog manure had different RAPD genomic profiles from those found in the feces of cattle grazing on manure-treated pasture.     

Study of the PM<Subscript>10</Subscript> concentration variations along two intra-urban roads within a compact city

Eighty-five measurement campaigns were performed repeatedly to compare the concentration variation profiles along two intra-urban roads—one with open configuration and the other with street canyon effect. Fixed-effects panel data analysis was applied for formulating a model to express the PM₁₀ concentrations along intra-urban roads in terms of parameters like nearby central monitoring data, traffic counts and meteorological conditions with an objective to analyze the PM₁₀ concentration variation patterns along the two roads. Our findings reveal that traffic intensity and metrological conditions exert influence on concentration variation for both types of road configurations while wind velocity only affect the pollutants removal effectiveness of open road configuration. Further analysis unveils that the PM₁₀ concentration distribution profiles within a compact city environment are not always uniform and are dependent on the road configuration. Considerable PM₁₀ concentration differences were observed along the street canyon, and 70% of their variations are attributed to variations in their road aspect ratios. By contrast, no significant concentration difference is observed at open road configurations.     

Hydrous ferric oxide nanoparticles hosted porous polyethersulfone adsorptive membrane: chromium (VI) adsorptive studies and its applicability for water/wastewater treatment

In this present study, adsorptive membranes for Cr(VI) ion removal were prepared by blending polyethersulfone (PES) with hydrous ferric oxide (HFO) nanoparticles (NPs). The effects of HFO NPs to PES weight ratio (0–1.5) on the physicochemical properties of the resultant HFO/PES adsorptive membranes were investigated with respect to the surface chemistry and roughness as well as structural morphologies using different analytical instruments. The adsorptive performance of the HFO NPs/PES membranes was studied via batch adsorption experiments under various conditions by varying solution pH, initial concentration of Cr(VI), and contact time. The results showed that the membrane made of HFO/PES at a weight ratio of 1.0 exhibited the highest adsorption capacity which is 13.5 mg/g. Isotherm and kinetic studies revealed that the mechanism is best fitted to the Langmuir model and pseudo-second-order model. For filtration of Cr(VI), the best promising membranes showed improved water flux (629.3 L/m² h) with Cr(VI) ion removal of 75%. More importantly, the newly developed membrane maintained the Cr(VI) concentration below the maximum contamination level (MCL) for up to 9 h.

     

Lichens as Bioindicators of Atmospheric Heavy Metal Pollution in Singapore

Lichens have been used as bioindicators in various atmospheric pollution assessments in several countries. This study presents the first data on levels of heavy metals (As, Cd, Cu, Ni, Pb, and Zn) in lichens at different locations in Singapore, Southeast Asia. Singapore is a fully industrialised island nation, with a prevailing tropical climate and a population of 4 million people within a confined land area of less than 700 km². The ubiquitous lichen species, Dirinaria picta was collected from six sample sites across Singapore and analysed for heavy metals using inductively coupled plasma mass spectrometry (ICPMS). No significant relationship existed between metal levels in lichen and soil, indicating that accumulated metals in lichen are primarily derived from the atmosphere. Peak concentrations of zinc (83.55 μg g⁻¹), copper (45.13 μg g⁻¹) and lead (16.59 μg g⁻¹) in lichens were found at Sembawang, Jurong and the National University of Singapore campus which are locations associated with heavy petroleum and shipping industries, and road traffic respectively. The mean heavy metal levels of lichen samples in Singapore were found to be at the upper range of values reported in the literature for temperate countries.     

Perceptions of implied hazard for visual and auditory alerting signals

Visual and auditory alerts are increasingly important and have many applications, particularly in the presentation of hazard information in transportation and many industrial systems. This paper is concerned with the factors that govern the relative effectiveness of alerting signals involving various combinations of visual and auditory signals. The visual variables were colour, flash rate, and flash mode, combined with or without an auditory alarm. It was found that the subjects associated different levels of hazard with different alerting light colours, flash rates, flashing modes, and with combinations of auditory and visual alerts. A red flashing light was perceived as the most effective hazard warning colour, with yellow and blue warning lights indicative of less hazardous situations. The faster the flash rate, the greater is the hazard perceived. A flash rate of 60 fpm (flashes per minute) was not as effective as the rates of 180 and 240 fpm, and 240 fpm was the most effective. This implies that hazard warning signal should flash at well above 60 fpm. Having a breakup in the flashing pattern so as to provide a double or triple flash mode also increases the effectiveness of the signal. There were significant interactions between the alert variables used. The difference in perceived hazard levels for the colours blue and yellow were statistically non significant, but blue was more effective in conveying hazard message than yellow at the high flash rates. When accompanied with auditory alarms, blue and yellow were perceived to convey the same perception level of hazard as red without auditory alarms. The effect of colour on perceived hazard was also found to vary with flash mode. As compared to either visual signal alone or a visual signal with other types of acoustic alarms, a siren type of auditory alarm was found more effective for eliciting perception of hazards. There was evidence that presenting alerting signal in triple-flash mode and at high flash rate could be annoying and might not help improving hazard awareness.     

The current municipal solid waste management situation in Tibet

The Tibetan Plateau has an average altitude of more than 4,000 m. The total area of Tibetan Plateau is 2,400,000 km2, which occupies 25% of the area of China. Due to the high altitude, the environment has low atmospheric pressure, low oxygen content, and low temperature, and is also fragile. Investigations concerning MSW generation and characteristics, MSW management, collection and transportation, and treatment and disposal of MSW covered four representative cities, including the urban areas of Lhasa city, Shigatse, Nedong of Lhoka and Bayi of Nyingtri. The results show that MSW generation in the urban areas of Lhasa city and Tibet were 450 t/d and 3,597 t/d, respectively, in 2006. However, accelerated economic development and flourishing tourism caused by the opening of the Qinghai-Tibet Railway (QTR) have greatly increased solid waste generation to a new high. It is predicted that MSW generation in Tibet will reach 4,026 t/d in 2010 and 4,942 t/d in 2020. MSW management and disposal lag behind MSW generation due to a number of factors such as equipment shortage, insufficient maintenance, exhaustion of waste treatment capacity and low recycling efficiency. Still, MSW in most areas is dumped in the open with no controls. Because no appropriate collection and treatment systems for leachate and landfill gas exist, untreated leachate is discharged directly into the environment, causing serious secondary pollution. Some suggestions on improving the MSW management system are presented in this paper.     

Effect of operational factors on bioregeneration of binary phenol and 4-chlorophenol-loaded granular activated carbon using PVA-immobilized biomass cryogels

The effects of dry biomass density in cryogel beads, shaking speed and initial concentration ratio of phenol to 4-chlorophenol (4-CP) on the bioregeneration efficiencies of binary phenol and 4-CP-loaded granular activated carbon (GAC) for phenol and 4-CP, respectively, were investigated under the simultaneous adsorption and biodegradation approach. The results revealed higher bioregeneration efficiencies of binary-loaded GAC for phenol and 4-CP at higher dry biomass density but moderate shaking speed. The optimum dry biomass density in cryogel beads and shaking speed for use in bioregeneration were found to be 0.01 g/mL and 250 rpm, respectively. With respect to the initial phenol to 4-CP concentration ratio, the bioregeneration efficiencies were lower under increasing phenol and 4-CP initial concentrations, respectively, with the effect being more conspicuous under increasing 4-CP concentration. Higher bioregeneration efficiencies were achieved with the use of immobilized rather than suspended biomasses.