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71.
The crab Pachygrapsus laevimanus and the zebra winkle Austrocochlea constricta were exposed for 40 d to uranium (1.5 to 10 mg l-1) in continuous-flow sea water in separate starved and fed treatments, and the kinetics of uranium bioaccumulation were estimated from an exponential model. Starved and fed crabs took up U at a similar rate, which suggests that sea water was the major source of U to the crab; the fed crabs excreted U more rapidly than the starved crabs and this led to a lower net uptake of U by fed crabs. Fed and starved winkles took up U at similar rates and excreted it at similar rates, so the sea water was also the major source of U to winkles. Crabs took up more U than winkles; the concentration factors were 7 to 18 and 4, respectively. Uranium turnover was quite slow for both species (11 to 36 d) as it was also for winkle shells (6 d); this suggests that the rate-limiting processes which control turnover are biological (e.g. growth or tissue replacement) or physical (e.g. diffusion into the shell) rather than chemical (e.g. precipitation, adsorption or exchange). There was no effect of increasing U concentration in water on the U kinetic parameters. 相似文献
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Nitrite occurs naturally in fresh waters as a result of nitrification of ammonia and denitrification of nitrate, and its concentration can be enhanced by partial oxidation of ammoniacal discharges. Nitrite is toxic to vertebrates including fish and a principal effect is the conversion of haemoglobin to methaemoglobin which is incapable of oxygen transport although there are circulatory and tissue effects as well. The toxic species is the nitrite ion (NO2) which is believed to enter the blood via the branchial chloride/bicarbonate exchange and fish such as salmonids with high chloride uptake rates are more susceptible than those with low chloride uptake rates, for example carp. Nitrite toxicity is strongly aleviated by chloride and the concentration ratio of these ions is of great importance in assessing toxicity. Short term and long term toxicity data for a variety of fish species are presented. There are no field data on fish populations in waters where nitrite was the only pollutant. However extensive field surveys indicated that, waters with a mean chloride concentration of 25 mg l-1 in good salmon fisheries were associated with concentrations of nitrite below 50 μg l-1 N · NO2, good coarse fisheries below 100 μg l-1 N · NO2. 相似文献
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Influence of Riparian Seepage Zones on Nitrate Variability in Two Agricultural Headwater Streams
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Mark R. Williams Anthony R. Buda Herschel A. Elliott Kamini Singha James Hamlett 《Journal of the American Water Resources Association》2015,51(4):883-897
Riparian seeps have been recognized for their contributions to stream flow in headwater catchments, but there is limited data on how seeps affect stream water quality. The objective of this study was to examine the effect of seeps on the variability of stream NO3‐N concentrations in FD36 and RS, two agricultural catchments in Pennsylvania. Stream samples were collected at 10‐m intervals over reaches of 550 (FD36) and 490 m (RS) on 21 occasions between April 2009 and January 2012. Semi‐variogram analysis was used to quantify longitudinal patterns in stream NO3‐N concentration. Seep water was collected at 14 sites in FD36 and 7 in RS, but the number of flowing seeps depended on antecedent conditions. Seep NO3‐N concentrations were variable (0.1‐29.5 mg/l) and were often greater downslope of cropped fields compared to other land uses. During base flow, longitudinal variability in stream NO3‐N concentrations increased as the number of flowing seeps increased. The influence of seeps on the variability of stream NO3‐N concentrations was less during storm flow compared to the variability of base flow NO3‐N concentrations. However, 24 h after a storm in FD36, an increase in the number of flowing seeps and decreasing streamflow resulted in the greatest longitudinal variability in stream NO3‐N concentrations recorded. Results indicate seeps are important areas of NO3‐N delivery to streams where targeted adoption of mitigation measures may substantially improve stream water quality. 相似文献
76.
Development of the Spatial Rainfall Generator (SRGEN) for the Agricultural Policy/Environmental Extender Model
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Jaehak Jeong Jimmy R. Williams Colleen G. Rossi Robin A. Taylor Xiuying Wang William E. Fox 《Journal of the American Water Resources Association》2015,51(1):154-167
Accurate spatial representation of climatic patterns is often a challenge in modeling biophysical processes at the watershed scale, especially where the representation of a spatial gradient in rainfall is not sufficiently captured by the number of weather stations. The spatial rainfall generator (SRGEN) is developed as an extension of the “weather generator” (WXGEN), a component of the Agricultural Policy/Environmental eXtender (APEX) model. SRGEN generates spatially distributed daily rainfall using monthly weather statistics available at multiple locations in a watershed. The spatial rainfall generator as incorporated in APEX is tested on the Cowhouse watershed (1,178 km2) in central Texas. The watershed presented a significant spatial rainfall gradient of 2.9 mm/km in the lateral (north‐south) directions based on four rainfall gages. A comparative analysis between SRGEN and WXGEN indicates that SRGEN performs well (PBIAS = 2.40%). Good results were obtained from APEX for streamflow (NSE = 0.99, PBIAS = 8.34%) and NO3‐N and soluble P loads (PBIAS ≈ 6.00% for each, respectively). However, APEX underpredicted sediment yield and organic N and P loads (PBIAS: 24.75‐27.90%) with SRGEN, although its uncertainty in output was lower than WXGEN results (PBIAS: ?13.02 to ?46.13%). The overall improvement achieved in rainfall generation by SRGEN is demonstrated to be effective in the improving model performance on flow and water quality output. 相似文献
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Hydrologic analysis for coastal wetland restoration 总被引:1,自引:0,他引:1
Increasing recognition of the value of tidal wetlands has led to interest in how to restore and enhance areas that have been modified by human activity. The policy of recognizing restoration or enhancement as mitigation for destruction of other wetlands is controversial. Once policy questions are separated from technical questions, the steps in a successful project are straightforward A key element in the design of a successful project is quantitative hydraulic and hydrologic analysis of alternatives. Restoration projects at two sites in California used a combination of empirical geomorphic relationships, numerical modeling, and verification with field observations. Experience with these and other wetland restoration projects indicates the importance of longterm postproject monitoring, inspection, and maintenance 相似文献
80.
Clare Palmer 《Conservation biology》2005,19(5):1674-1675