The Potential Use of Synthetic Aperture Radar for Estimating Methane Ebullition From Arctic Lakes1

Abstract: Arctic lakes are significant emitters of methane (CH₄), a potent greenhouse gas, to the atmosphere; yet no rigorous quantification of the magnitude and variability of pan‐Arctic lake emissions exists. In this study, we demonstrate the potential for a new method using synthetic aperture radar (SAR) imagery to detect methane bubbles in lake ice to scale up whole‐lake measurements of CH₄ ebullition (bubbling) to regional scales. We estimated ebullition from lakes, which is often the dominant mode of lake emissions, by mapping the distribution of bubble clusters frozen in early winter ice across surfaces of seven tundra lakes and one boreal forest lake in Alaska. Applying previously measured ebullition rates associated with four distinct classes of bubble clusters found in lake ice, we estimated whole‐lake emissions from individual lakes. The percent surface area of lake ice covered with bubbles (R² = 0.68) and CH₄ ebullition rates from lakes (R² = 0.59) and were correlated with radar return values from RADARSAT‐1 Standard Beam mode 3 for the tundra lakes, suggesting that with appropriate scaling and consideration for variability in lake‐ice conditions, this technique has the potential to be used for estimating broader‐scale regional and pan‐Arctic lake methane emissions.     

Long-term interactions between migratory caribou, wildfires and Nunavik hunters inferred from tree rings

Barren-ground caribou (Rangifer tarandus) herds in North America may reach considerable size and undertake large-scale seasonal migrations from the Arctic tundra to the boreal forest. To test the caribou decline hypothesis associated with native harvesting and fire, we have documented the long-term trends of caribou activity based on a novel approach which uses tree-ring dated trampling scars produced by caribou hooves in the extensive trails distributed over the summer and winter ranges of the Rivièreaux-Feuilles herd (RAF herd, east of Hudson Bay in northern Quebec). The age structure data of trampling scars from lichen woodlands distributed over the entire RAF range confirmed the overall trends of caribou activity from the late 1700s to present time. Over the last 200 years, the RAF herd has undergone two highs in the late 1700s and 1900s separated by a moderate activity pattern in the late 1800s. Native harvesting was possibly involved in the early 1900s decline, although at a moderate level. The reduced magnitude of caribou activity during this period has not modified the natural cycle of highs and lows, which suggests that other demographic factors were controlling the changing caribou abundance. Our data also show that only exceptionally large fires may have a minor, short-lived impact on caribou migrations but not on caribou numbers.     

Surfactant-assisted UV-photolysis of nitroarenes

Photochemical transformations (lambda-254 nm) of 2,4-dinitrotoluene (2,4-DNT) in aqueous solutions containing the cationic surfactant cetyltrimethylammonium (CTA) and the anionic nucleophile borohydride (BH4-) were investigated. The overall decay rate was enhanced at CTA concentrations above the critical micelle concentration (cmc) when stoichiometric excess BH4- was present in solution. A kinetic model that separates the overall reaction rate into micellar and aqueous pseudo-phase components indicates transformation in micelles is 17 times faster that in the homogeneous water phase under those conditions investigated. Intermediate products were identified by comparing the HPLC retention times and ultraviolet-visible absorption spectra of product peaks to those of analytical standards. 2-Methyl-5-nitroaniline, 4-nitrotoluene, 2-nitrotoluene, 4-methyl-3-nitroaniline, 2,4-diaminotoluene, o-toluidine, 1,3-dinitrobenzene, 3-nitroaniline, p-cresol, and 2,4-diaminophenol were identified as photo-transformation intermediates or products.     

HISTORICAL EVOLUTION OF FLOODING DAMAGE ON A USA/QUEBEC RIVER BASIN1

ABSTRACT: There is a general belief in the public eye that extreme events such as floods are becoming more and more common. This paper explores this hypothesis by examining the historical evolution of annual expected flooding damage on the Chateauguay River Basin, located at the border between the United States and the province of Quebec, Canada. A database of basin land use was constructed for the years 1930 and 1995 to assess anthropogenic changes and their impact on the basin's hydrology. The progressive modification of the likelihood of a flooding event over the same period was then investigated using homogeneity and statistical tests on available hydrometric data. The evolution of the annual expected flooding damage was then evaluated using a coupled hydrologic/hydraulic simulator linked to a damage analysis model. The simulator and model were used to estimate flooding damage over a wide range of flooding return periods, for conditions prevailing in 1963 and 1995. Results of the analysis reveal the absence of any increasing or decreasing trend in the historical occurrence of flooding events. However, a general increase in the annual expected flooding damage was observed for all studied river sections. This increase is linked to an historical increase in damages for a given flooding event, and is the result of unbridled construction and development within the flood zone. To assess for future trends, this study also examined the potential impacts linked to the anticipated global warming. Results indicate that a significant increase in seasonal flooding events and annual expected flooding damage is possible over the next century. In fact, what is now considered a 100‐year flooding event for the summer/fall season could become a ten‐year event by the end of this century. This shows that potential future impacts linked to climate change should be considered now by engineers, land planners, and decision makers. This is especially critical if a design return period is part of the decision making process.     

Social features of energy production and use in Brazil: Goals for a sustainable energy future

This paper focuses on the social features of ene rgy production and use in Brazil and discusses the role of the energy policy goals of accessibility, affordability and acceptability in defining a sustainable energy future for the country. The major findings are that social inequalities in Brazil regarding energy use continue to be substantial and important. This can be explained by the fact that, although recent decades have seen significant improvements in energy accessibility all over the country, much more needs to be done to provide affordable, and socially acceptable modern energy carriers to all socio‐economic groups in all regions.     

Compost, manure, and gypsum application to timothy/red clover forage

Some of the most fertile agricultural land in Atlantic Canada includes dykelands, which were developed from rich salt marshes along the Bay of Fundy through the construction of dykes. A 2-yr field experiment was conducted on dykeland soil to evaluate the effect of fertility treatments: source-separated municipal solid waste (SS-MSW) compost, solid manure, commercial fertilizer, and gypsum on (1) timothy/red clover forage productivity, (2) N, S, and other nutrients uptake, and (3) residual NO(3)-N and NH(4)-N in the soil profile. All fertility treatments increased dry matter yields from the two cuts each year relative to the control. Residual soil NO(3)-N and NH(4)-N concentrations in the fall of the second year decreased with depth, and beyond 20-cm depth were lower than 1 mg kg(-1). Gypsum application equivalent to 40 kg S ha(-1) increased dry matter yields and N uptake by forage, and increased soil Mehlich 3-extractable S, tissue S, and uptake of S, Ca, P, Cu, Fe, and Mn relative to the control. High rates of compost can provide sufficient N, S, and perhaps other nutrients to a perennial forage system under the cool wet climate of Atlantic Canada with no heavy metal enrichment of forage. However, the chemical N provided greater total N uptake than organic sources, except the high rate of compost, suggesting that the N availability from organic sources was not well synchronized with forage N demand. Municipal solid waste compost may also increase soil and forage tissue Na, which might be of concern.     

Über die Phasenprobe und die nächsten Abkömmlinge des Chlorophylls

The Science of Nature -     

Implementation of a continuous-flow stirred bioreactor system in the bioremediation of heavy metals from industrial waste water

The industrial applicability of immobilized non-viable yeast biomass (Saccharomyces cerivisiae) in continuous-flow stirred bioreactors was tested with respect to metal removal from electroplating effluent solutions containing Cu, Cd, Cr, Ni and Zn in excess of the stipulated water quality criteria. Two systems, a dual bioreactor and triple bioreactor system in series, were tested and compared regarding their efficiency of metal removal. The system containing two bioreactors linked in series provided a more efficient solution to the problem. The introduction of a third bioreactor into the system had a marginal effect on the amount of metal removed. Subsequent to treatment within the bioreactors the levels of Cu, Cr and Ni in the effluent complied with the stipulated drinking water quality criteria and, although in excess of these criteria only 18% of the initial Zn and 17% of the Cd remained in solution.