全文获取类型
收费全文 | 234篇 |
免费 | 2篇 |
专业分类
安全科学 | 1篇 |
废物处理 | 9篇 |
环保管理 | 19篇 |
综合类 | 28篇 |
基础理论 | 38篇 |
污染及防治 | 88篇 |
评价与监测 | 27篇 |
社会与环境 | 22篇 |
灾害及防治 | 4篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 5篇 |
2020年 | 7篇 |
2019年 | 2篇 |
2018年 | 10篇 |
2017年 | 6篇 |
2016年 | 5篇 |
2015年 | 7篇 |
2014年 | 13篇 |
2013年 | 18篇 |
2012年 | 18篇 |
2011年 | 18篇 |
2010年 | 10篇 |
2009年 | 17篇 |
2008年 | 13篇 |
2007年 | 18篇 |
2006年 | 19篇 |
2005年 | 6篇 |
2004年 | 11篇 |
2003年 | 9篇 |
2002年 | 5篇 |
2001年 | 2篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1985年 | 2篇 |
排序方式: 共有236条查询结果,搜索用时 234 毫秒
101.
102.
103.
Fabio Parizia Valter Maurino Claudio Minero Davide Vione 《Environmental Chemistry Letters》2012,10(4):395-399
Atmospheric particulate matter is altering climate. For instance marine biogenic particles are cooling climate. Organic markers are major tools to elucidate the sources of atmospheric particulate matter. Formate is commonly used as a marker of continental aerosols, whereas methanesulphonate is used as tracer of biogenic marine aerosols. However, transformation processes during aerosol transport may modify their relative concentrations and, in turn, introduce a bias in the assessment of particle sources. Actually very little is known about the transformation of formate and methanesulphonate in aerosols. Therefore, we irradiated formate and methanesulphonate in the presence of nitrate and haematite. Nitrate and haematite are aerosol photosensitisers, producing reactive species that degrade organic compounds. The time evolution of formate and methanesulphonate was monitored by ion chromatography. Our results show that formate is transformed from 1.6 to 4.1 times faster than methanesulphonate. This trend is partly due to higher reactivity with the hydroxyl radical and partly due to additional reaction with other transients such as nitrogen dioxide. Such results strongly suggest faster formate transformation during particle transport. Therefore, when formate and methanesulphonate are used as particle tracers, an overestimation of marine biogenic versus continental particle sources is expected. This bias has major implications for climate prediction models, because marine biogenic particles have a cooling effect on climate. 相似文献
104.
Pratap Reddy Maddigapu Davide Vione Barbara Ravizzoli Claudio Minero Valter Maurino Laetitia Comoretto Serge Chiron 《Environmental science and pollution research international》2010,17(5):1063-1069
Background, aim and scope
Photochemical processes can decontaminate the aqueous environment from xenobiotics, but they also produce secondary pollutants. This paper presents field and laboratory evidence of the transformation of 4-chlorophenol (4CP) into 2-nitro-4-chlorophenol (2N4CP). 相似文献105.
Swapan Khanra Claudio Minero Valter Maurino Ezio Pelizzetti Binay K. Dutta Davide Vione 《Environmental Chemistry Letters》2008,6(1):29-34
Here we show that the photolysis of FeCl2+ upon UV irradiation of Fe(III) at pH 0.5, yielding Cl• and then Cl2−•, upon further reaction with Cl−, induces phenol degradation. The photolysis of FeCl2+ can be highlighted and studied as the huge interference by FeOH2+ can be avoided under such conditions. Our data allowed the assessment of a photolysis quantum yield for FeCl2+ of 5.8 × 10−4 under UVA irradiation, much lower compared to the literature value of 0.5. The discrepancy can be explained if the photolysis
process is efficient but photoformed Fe2+ and Cl• undergo recombination inside the solvent cage. 相似文献
106.
Lastre-Acosta Arlen Mabel Rocha Carolina Mendes Mendes Maria Anita Teixeira Antonio Carlos Silva Costa do Nascimento Claudio Augusto Oller 《Environmental science and pollution research international》2022,29(28):42231-42241
Environmental Science and Pollution Research - Polychlorinated biphenyls (PCBs) are a family of highly toxic, resistant, and persistent organic pollutants, among which 2-chlorobiphenyl (PCB-1) is... 相似文献
107.
Immature and adult stages of blowflies are one of the primary invertebrate consumers of decomposing animal organic matter. When the food supply is consumed or when the larvae complete their development and migrate prior to the total removal of the larval substrate, they disperse to find adequate places for pupation, a process known as postfeeding larval dispersal. Several important ecological and physiological aspects of this process were studied since the work by Green (Ann Appl Biol 38:475, 1951) 50 years ago. An understanding of postfeeding larval dispersal can be useful for determining the postmortem interval (PMI) of human cadavers in legal medicine, particularly because this interval may be underestimated if older dispersing larvae or those that disperse longer, faster, and deeper are not taken into account. In this article, we review the process of postfeeding larval dispersal and its implications for legal medicine, in particular showing that aspects such as burial behavior and competition among species of blowflies can influence this process and consequently, the estimation of PMI. 相似文献
108.
Bracchini L Cózar A Dattilo AM Loiselle SA Tognazzi A Azza N Rossi C 《Chemosphere》2006,63(7):1170-1178
Chromophoric Dissolved Organic Matter (CDOM) is an important component in freshwater and marine ecosystems and plays direct and indirect role in biogeochemical cycles. CDOM originates from the degradation process of organic materials, usually macrophytes and planktons. The present work examines the importance of wetland derived CDOM on the optical and bio-optical properties of two bays of Lake Victoria (Uganda, Africa). This was achieved by determining the attenuation and extinction coefficients of filtered and unfiltered water samples from two equatorial bays on the Ugandan coastline of Lake Victoria. Katonga Bay is a wetland lined bay that receives water from the Katonga river, while Bunjako Bay is an outer bay between Katonga Bay and Lake Victoria. The results showed that attenuation was highest in Katonga Bay and the role of CDOM is most dominant near the river inlet. The quantity and quality of CDOM is extremely different in the two bays: in Katonga Bay it is possible to hypothesize a terrestrial origin of CDOM (transported by the wetland river). On the contrary, in Bunjako Bay, spectral measurements of absorption indicate a modified CDOM and/or alternative CDOM source. The terrestrial CDOM in Katonga Bay is more capable of absorbing harmful UV radiation than the CDOM present in the Bunjako Bay. The resulting optical environment in the former bay presented a water column with a very limited penetration of harmful UV radiation, while a higher penetration was observed in the Bunjako Bay. 相似文献
109.
110.