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991.
992.
采用电沉积技术制备了铟掺杂PbO2电极 (In-PbO2). 利用扫描电子显微镜 (SEM)、X射线衍射 (XRD)、循环伏安 (CV)、极化曲线 (LSV)、强化寿命试验和荧光光谱分析了铟掺杂对电极物理、电化学性能的影响,并考察了铟掺杂PbO2电极对强力霉素模拟废水的电催化降解能力.结果表明,与未掺杂PbO2电极相比, In掺杂后PbO2电极表面更加平整致密,裂纹数量减少,晶粒明显细化,比表面积增加,产生羟基自由基的能力增强.当掺杂量为2g/L,制备的电极电化学性能最高,析氧电位最高(1.73V),电极强化寿命从84h提高到148h.电解150min后,强力霉素降解率、TOC去除率、矿化电流效率(MCE)分别为98.2%、30.4%和3.01%,优于未掺杂PbO2电极(90.1%、26.4 %、2.63%). 相似文献
993.
There are good prospects for phosphorus recovery from excess sludge by vivianite crystallization while a large number of extracellular polymeric substances in sludge will have impact on vivianite precipitation. In this study, as a representative of extracellular polymeric substance, the effect of sodium alginate (SA) on phosphorus recovery by vivianite precipitation under different initial SA concentrations (0–800 mg/L), pH values (6.5–9.0) and Fe/P molar ratios (1:1–2.4:1) was investigated using synthetic wastewater. The results showed that SA in low concentrations (≤400 mg/L) had little inhibitory effect on the phosphorus recovery rate. However, when the concentration of SA was larger than 400 mg/L, the phosphorus recovery rate decreased significantly with increasing SA concentrations. The inhibition rate of 800 mg/L SA was about 3 times as large as that of 400 mg/L SA. It was worth noting that the inhibitory effect of SA on vivianite precipitation decreased with increasing initial pH and Fe/P molar ratios. Additionally, SA has no obvious influence on the composition of products, but the morphology of harvested crystals was transformed from branches to plates or rods in uneven sizes. 相似文献
995.
使用USEPA Method 29方法对600MW燃煤电厂SCR、ESP和WFGD前后4个测点进行烟气痕量元素同时取样,研究了12种痕量元素(Cr、Mn、Co、Ni、Cu、Zn、As、Mo、Cd、Sb、Ba、Pb)的排放特性.结果表明:整个电厂系统、锅炉、SCR、ESP和WFGD中痕量元素的质量平衡率都在可接受范围内,实验结果准确可靠.这12种痕量元素主要分布于ESP飞灰中,相对分布率为69.97%~98.79%.底渣中痕量元素的相对富集指数在0.04~0.51之间,ESP飞灰中痕量元素的相对富集系数在0.3~1.23之间.ESP飞灰中的As、Cd和Pb以及WFGD废水中的Mn、Co和Ni可能会对土壤和地下水产生污染,需要引起关注.12种痕量元素向大气中的排放浓度位于0.02~12.57μg/m3之间,排放因子位于的0.01~2.13g/1012J之间,Ni、As、Cd和Pb这4种元素的排放浓度分别达到2.04、0.13、0.02和3.35μg/m3,都远超欧盟空气质量标准中的排放限值,需要加以重视进行限制. 相似文献
996.
Zhaojun Wen Xinping Duan Menglin Hu Yanning Cao Linmin Ye Lilong Jiang Youzhu Yuan 《环境科学学报(英文版)》2018,30(2):122-129
In this study, the effects of copper(Cu) additive on the catalytic performance of Ag/SBA-15 in complete soot combustion were investigated. The soot combustion performance of bimetallic Ag–Cu/SBA-15 catalysts was higher than that of monometallic Ag and Cu catalysts. The optimum catalytic performance was acquired with the 5 Ag_1-Cu_(0.1)/SBA-15 catalyst, on which the soot combustion starts at T_(ig)= 225°C with a T_(50)= 285°C. The temperature for 50% of soot combustion was lower than that of conventional Ag-based catalysts to more than 50°C(Aneggi et al., 2009). Physicochemical characterizations of the catalysts indicated that addition of Cu into Ag could form smaller bimetallic Ag–Cu nanolloy particles, downsizing the mean particle size from 3.7 nm in monometallic catalyst to 2.6 nm in bimetallic Ag–Cu catalyst. Further experiments revealed that Ag and Cu species elicited synergistic effects, subsequently increasing the content of surface active oxygen species. As a result, the structure modifications of Ag by the addition of Cu strongly intensified the catalytic performance. 相似文献
997.
Wenhui Li Haidi Liu Shuangde Li Weiman Li Yunfa Chen Jiajia Gao Yaqun Cao 《环境科学学报(英文版)》2018,30(2):190-196
A co-current flow rotating packed bed was applied to remove volatile organic compounds(VOCs) by sodium hypochlorite(Na Cl O) and surfactant(sodium dodecyl benzene sulfonate,SDBS) from air stream. Xylene was used as a model VOC herein. The effect of p H,concentration of Na Cl O and SDBS solution, liquid flow rate, gas flow rate and rotational speed on xylene removal efficiency and overall mass transfer coefficient(KGa) were discussed. Then, a correlation for KGa of the co-current rotating packed bed was proposed by fitting the experimental data of KGa and independent variables of liquid/gas ratio,rotational speed, p H, Na Cl O concentration and treatment time, which was in good agreement with the experimental data(the deviation ≤± 30%). 相似文献
998.
土壤作物系统镉污染及其防治研究 总被引:10,自引:0,他引:10
选择我国北方主要粮食作物冬小麦和夏谷进行盆栽试验,研究了土壤镉污染对作物生长发育和产量的影响及泥炭、羊粪两种不同类型的有机肥缓减土壤镉污染危害的作用;分析了镉在两种作物不同器官中的迁移效率和累积规律;认为施加有机肥是缓减土壤镉污染危害的有效措施,且施羊粪的效果比施泥炭好。 相似文献
999.
1000.