Use of denuder/filter apparatus to investigate terpene ozonolysis

A denuder/filter apparatus was used to collect the gaseous and particulate reaction products from ozonlysis of α-pinene, limonene and α-terpineol in an effort to develop sampling techniques for characterizing indoor environment chemistry. Carboxylic acids found in the particulate phase were derivatized to 2,2,2-trifuoroethylamides by reaction with 3-ethyl-1-[3-(dimethylamino)propyl]carbodiimide hydrochloride (EDC) and 2,2,2-trifluoroethylamine hydrochloride (TFEA). Carbonyl compounds collected in both gas phase and particulate phase were derivatized to their respective oximes by reaction with O-(2,3,4,5,6-pentafluoro-benzyl)hydroxylamine hydrochloride (PFBHA). The ozonolysis of α-pinene yielded the carboxylic acids: cis-pinonic acid and pinic acid and the proposed carboxylic acids methanetricarboxylic acid and terpenylic acid; the carbonyls: 4-oxopentanal, norpinonaldehyde, pinon aldehyde and the proposed carbonyl methylidenepropanedial. The ozonolysis of limonene yielded the carboxylic acids: limonic acid and pinic acid and the carbonyls: 1-(4-methylcyclohex-3-en-1-yl)ethanone (4AMCH), glyoxal, methyl glyoxal, 4-oxopentanal and 6-oxo-3-(prop-1-en-2-yl)heptanal (IPOH). The ozonolysis of α-terpineol yielded the proposed carboxylic acids: terpenylic acid and homoterpenylic acid and the carbonyls: (5E)-6-hydroxyhept-5-en-2-one, methyl glyoxal and 4-oxopentanal.     

Historic preservation,significance, and age value: A comparative phenomenology of historic Charleston and the nearby new-urbanist community of I'On

While the age of physical environments is the central tenet of historic preservation, there is a lack of empirical evidence about how everyday people actually value, perceive, and experience age as an intrinsic part of an urban environment. In order to ameliorate this knowledge deficit, this study employs phenomenology to understand the lived experience of being in a “new” versus an “old” or “historic” urban residential environment. The new environment is the I'On new urbanist development in Mt. Pleasant, South Carolina, and the old environment is the location of the United States' first historic district in Charleston, South Carolina. These locations are approximately within five miles of each other. In both places, the physical characteristics of the built environment are remarkably similar in density, form, layout, and design, but the age is dramatically different. Through photo elicitation techniques and interviews, the results of this study reveal that residents of historic Charleston and I'On value their built environments in remarkably similar ways. Surprisingly, elements that evoke a strong sense of attachment tend to be landscape features, such as gates, fountains, trees, and gardens rather than buildings. The informants valued the “mystery” that they felt was part of the landscape and which consisted of layered elements such as fences, gates, and paths, such that these features (including buildings) had to be “discovered.” Lastly, the informants strongly valued landscapes that showed “people care” through regular maintenance. The essential difference in people's experience and valuation of the new environment (I'On) and the old environment (historic Charleston) is in the older environment's ability to instill creative fantasies in the minds of the informants based on a hypothetical past of their own creation. The informants in I'On did not share these kinds of meanings.     

Continuous Emissions Monitoring Using Spark-Induced Breakdown Spectroscopy

ABSTRACT

A new technology for monitoring airborne heavy metals on aerosols and particulates based on spark-induced breakdown spectroscopy (SIBS) was evaluated at a joint U.S. Environmental Protection Agency (EPA)/U.S. Department of Energy test at the rotary kiln incinerator simulator (RKIS) facility at EPA/Research Triangle Park, NC, in September 1997. The instrument was configured to measure lead and chromium in a simulated combustion flue gas in real time and in situ at target levels of 15 and 75 u, g/dry standard cubic meters. Actual metal concentrations were measured during the tests using EPA Reference Method (RM) 29.

The SIBS technology detected both lead and chromium at the low- and high-level concentrations. Additionally, the hardware performed without failure for more than 100 hr of operation and acquired data for 100% of the RM tests. The chromium data were well correlated with concentration increases resulting from duct operations and pressure fluctuations that are known to entrain dust.     

Comparison of naphthalene bioavailability determined by whole-cell biosensing and availability determined by extraction with Tenax

A rapid biological method for the determination of the bioavailability of naphthalene was developed and its value as an alternative to extraction-based chemical approaches demonstrated. Genetically engineered whole-cell biosensors are used to determine bioavailable naphthalene and their responses compared with results from Tenax extraction and chemical analysis. Results show a 1:1 correlation between biosensor results and chemical analyses for naphthalene-contaminated model materials and sediments, but the biosensor assay is much faster. This work demonstrates that biosensor technology can perform as well as standard chemical methods, though with some advantages including the inherent biological relevance of the response, rapid response time, and potential for field deployment. A survey of results from this work and the literature shows that bioavailability under non-equilibrium conditions nonetheless correlates well with K_oc or K_d. A rationale is provided wherein chemical resistance is speculated to be operative.     

FOREST GROWTH IMPACT ON PEAK SNOW PACK MEASUREMENTS AT LONG TERM SNOW COURSES1

ABSTRACT: Snow course surveys in late winter provide stream‐flow forecasters with their best information for making water supply and flood forecasts for the subsequent spring and summer runoff period in mountainous regions of western North America. Snow survey data analyses are generally based on a 30‐year “normal” period. It is well documented that forest cover changes over time will affect snow accumulation on the ground within forests. This paper seeks to determine if forest cover changes over decades at long term snow courses decrease measured peak snow water equivalent (SWE) enough to affect runoff prediction. Annual peak SWE records were analyzed at four snow courses in two different forest types having at least 25 years of snowpack data to detect any decreases in SWE due to forest growth. No statistically significant decreases in annual peak SWE over time were found at any of these four snow courses. The wide range of annual winter precipitation and correspondingly highly variable peak snowpack accumulation, as well as many other weather and site variables, masked any minor trends in the data.     

BENTHIC INVERTEBRATES OF THE LOWER MISSISSIPPI RIVER1

ABSTRACT: In 1976–77, benthic invertebrates were sampled at four sites in a 410-kilometer reach of the lower Mississippi River to define the communities in the river and to determine differences between communities upstream and downstream from the industrial and municipal complexes of Baton Rouge and New Orleans, Louisiana. The most common and most numerous organisms collected were Corbicula and tubificid worms. The benthic community structure of the lower Mississippi River is influenced by substrate type and stability, channel geometry, river velocity, vegetation and organic detritus, and salinity. Sampling stations near the left and right banks had low velocities, and substrate types ranged from medium silt to very fine sand. Burrowing organisms such as tubificids, chironomids, and ephemerid-type mayflies dominated these environments. At the center, left-center, and right-center stations, velocities were higher and substrate materials were coarser than at the bank stations; only Corbicula was present in large numbers. Near the river mouth, salinity and aquatic vegetation greatly affect the benthic community structure. Differences in benthic community structure in the Mississippi River are due primarily to different hydrologic conditions. Industrial and municipal wastes discharged into the river appear to have little or no widespread effects on benthic populations.     

可持续建筑业的社会责任:国际劳工组织的观点

本文调查了可持续建筑业的社会形势,特别是发展中国家的可持续建筑业,一个有社会责任感的建筑产业,就是一个在保护劳工免受负面影响的同时努力加强正面影响作用的产业,这要求遵守劳动标准,正如"国际劳工组织(ILO)协定"和国家立法所表达的那样,志愿行动已经做出了积极的贡献,但是严格的计划将要求每一个人依照相同的游戏规则,要做到如此,全体利益相关者确定的统一行动是十分必要的,一个新的"社会责任感建设投资"行动,由国际劳工组织发起,它将把政府代表,雇主,工人和其他主要建筑利益相关者聚在一起,其目的是要制定战略和行动计划,以加强建筑作业中关键劳动标准的贯彻,以及推动建筑部门的生产性就业.     

The fatality consequences of the 65 mph speed limits, 1989

This study examined whether the number of fatalities on rural interstates in 1989 was higher than would be expected based on experience during 1982–1986 and experience on all other roads. Among the 40 states that increased the speed limit to 65 mph on rural interstates, the number of fatalities was 29% higher than expected. Among the eight states retaining a 55 mph maximum speed limit on rural interstates, the observed number of fatalities was 12% lower than expected, although this reduction was not statistically significant. After adjusting the fatality risk on rural interstates for differences in vehicle miles traveled on those roads and for higher passenger vehicle occupancy rates attributable to possible increases in vacation travel, the increased fatality risk was 19%. These data suggest that the majority of the estimated increase in fatalities on rural interstates in 1989 (almost 400 of the approximately 600 extra deaths) can be attributed to the higher speeds resulting from the higher speed limits. Changes in mileage account for the remaining 200 extra deaths.     

Characteristics of vehicle-animal crashes in which vehicle occupants are killed

During the past 10 years almost 1,500 people have been killed in motor vehicle collisions with animals. Police reports on 147 fatal vehicle-animal crashes during 2000-2002 were obtained from nine states. The goal was to determine common crash types, types of animals involved, and steps that could be taken to reduce the crashes and injuries. Seventy-seven percent of the struck animals were deer, but six other types of animals were involved including small ones such as dogs. Eighty percent of the crashes were single-vehicle events. In most of these cases a motorcycle struck an animal and the rider came off the vehicle, or a passenger vehicle struck an animal and then ran off the road; in a few cases the animal went through the windshield. Multiple-vehicle crashes included vehicles striking deer that went through the windshields of oncoming vehicles, vehicles striking animals and then colliding with other vehicles, and vehicles striking animals that subsequently were struck by other vehicles. Crashes occurred primarily in rural areas, on roads with 55 mph or higher speed limits, during evening or nighttime hours, and in darkness. Greater application of deer-vehicle collision countermeasures known to be effective is needed, but it is noteworthy that a majority of fatalities occurred from subsequent collisions with other vehicles or objects, not from animal contacts. Sixty-five percent of motorcyclists killed were not wearing helmets, and 60% of vehicle occupants killed were unbelted; many of these fatalities would not have occurred with proper protection.