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71.
Cíntia Melazo Dias Kristina Stenström Igor Luiz Bacelar Leão Roberto Ventura Santos Iêda Gomes Nícoli Göran Skog Peter Ekström Rosangela da Silveira Corrêa 《Journal of environmental radioactivity》2009
Atmospheric air samples were taken within 3 km from power plants encompassing five different distances and wind directions. Samples were taken between 2002 and 2005 aiming to evaluate the environmental 14C enrichment due to the operation of Brazilian nuclear power plants. The sampling system consisted of a pump connected to a trapping column filled with a 3 M NaOH solution. The trapped CO2 was analyzed for 14C by using a single stage accelerator mass spectrometry (SSAMS). 相似文献
72.
A Systematic Framework for the Design and Implementation of a Quality Management Practice: The Case of a Consulting Engineering Company 下载免费PDF全文
Herlander Mata‐Lima Fernando Morgado‐Dias Marina Carrato Galuzzi da Silva Kelly Alcântara José António Almeida 《环境质量管理》2016,25(4):49-61
Company productivity and competitiveness in today's marketplace requires creative design, innovation, and the reduction of nonconformances, which require costly rework and can damage a firm's reputation with its customers and potential customers. Using the International Organisation of Standardization's (ISO) 9000 and 14000 series of standards, the authors of this article walk readers through the rigorous process of obtaining upper management buy‐in and sponsorship and engaging workers in a bottom‐up approach to establish the procedures necessary to perform world‐class engineering services. 相似文献
73.
Herlander Mata‐Lima Andreilcy Alvino‐Borba Karen Akamatsu Bruno Incau Jakelline Jard Andreza Borba da Silva Fernando Morgado‐Dias 《环境质量管理》2016,26(2):89-104
This article proposes an integrated procedure to assess sustainability indicators that organizations can use to satisfy international requirements for sustainability. The indicators are related to key aspects of organizations, and their development includes comparing them to the results and policies of various other organizations that are seeking to achieve sustainability. The methodology we used is based on a bibliographic review, and it is intended to:
- Diagnose the state of the art of organizational sustainability,
- Provide organizations with tools to perform benchmarking based on the results, and
- Provide processes to identify best sustainability practices.
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Maria J. Lima M. Enis Leblebici Madalena M. Dias José Carlos B. Lopes Cláudia G. Silva Adrián M. T. Silva Joaquim L. Faria 《Environmental science and pollution research international》2014,21(19):11116-11125
The degradation of ciprofloxacin was studied in aqueous solutions by using a continuous flow homogeneous photo-Fenton process under simulated solar light. The effect of different operating conditions on the degradation of ciprofloxacin was investigated by changing the hydrogen peroxide (0–2.50 mM) and iron(II) sulphate (0–10 mg Fe L?1) concentrations, as well as the pH (2.8–10), irradiance (0–750 W m?2) and residence time (0.13–3.4 min) of the process. As expected, the highest catalytic activity in steady state conditions was achieved at acidic pH (2.8), namely 85 % of ciprofloxacin conversion, when maintaining the other variables constant (i.e. 2.0 mg L?1 of iron(II), 2.50 mM of hydrogen peroxide, 1.8 min of residence time and 500 W m?2 of irradiance). Additionally, magnetite magnetic nanoparticles (ca. 20 nm of average particle size) were synthesized, characterized and tested as a possible catalyst for this reaction. In this case, the highest catalytic activity was achieved at natural pH, namely a 55 % average conversion of ciprofloxacin in 1.8 min of residence time and under 500 W m?2. Some of the photocatalytic activity was attributed to Fe2+ leaching from the magnetic nanoparticles to the solution. 相似文献
76.
Richard Crawford Cristiane Q. Surbeck Steven B. Worley H. Q. Parker Capps 《补救:环境净化治理成本、技术与工艺杂志》2012,22(4):37-48
A common remedial technology for properties with subsurface soil and groundwater contamination is multiphase extraction (MPE). MPE involves the extraction of contaminated groundwater, free‐floating product, and contaminated soil vapor from the subsurface. A network of recovery wells conveys fluids to a vacuum pump and to the treatment system for the contaminated groundwater and soil vapor. This article describes a study of MPE operational data from nine similar remediation projects to determine the most important design parameters. Design equations from guidance manuals were used to estimate the expected radius of influence (ROI) based on measured field data. ROIs were calculated for the vapor flow rate through the subsurface and for the groundwater drawdown caused by the MPE remediation activities. The calculated ROIs were compared to the measured ROIs to corroborate the assumptions made in the calculations. Once it was established that the calculated and field‐measured ROIs were comparable, a sensitivity analysis determined ranges of different design and operational parameters that most affected the ROIs. © 2012 Wiley Periodicals, Inc. 相似文献
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Analysis of organophosphorus pesticides in whole milk by solid phase microextraction gas chromatography method 总被引:3,自引:0,他引:3
Solid phase microextraction (SPME) was used for the extraction of residual coumaphos and dichlorvos in whole milk. The residues were analyzed by capillary gas chromatography equipped with nitrogen phosphorus detector (GC-NPD). A manual SPME holder with a 100-microm polyacrylate fiber was used. The optimized conditions for extraction by SPME method were: sample agitation, absorption temperature of 30 degrees C, absorption time of 40 min, desorption time of 10 min, and sample volume was 16.0 mL in the vial. Under these conditions, the calibration graphs were linear in the range of 0.17 microgL-1 to 1.75 microgL-1 for coumaphos and 0.69 microgL-1 to 6.90 microgL-1 for dichlorvos. Precision was good with RSD values of 13% for coumaphos and 14% for dichlorvos. The detection limits (LOD) were 0.060 microgL-1 for dichlorvos and 0.052 for coumaphos. The quantification limits (LOQ) were 0.086 microgL-1 for dichlorvos and 0.066 microgL-1 for coumaphos. The results obtained in this study suggest that SPME is a suitable technique for residual pesticide analysis of milk. The data demonstrate that particular OP pesticides used in dairy farming in the region of Minas Gerais were found to contaminate cow whole milk, and the residues are not removed by treating the milk by boiling. 相似文献
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Alice Bosco-Santos Wanilson Luiz-Silv Emmanoel Vieira da Silva-Filho Monique Dias Corrêa de Souz Elton Luiz Dantas Margareth Sugano Navarro 《环境科学学报(英文版)》2017,29(4):69-76
Fractionation of rare earth elements (REE) and other trace metal concentrations (Th, U, Cd, Cr, Cu, Ni, Pb, and Zn) between mangrove sediments and claw muscles and shells of male crabs (Ucides cordatus) from a subtropical estuary highly impacted by fertilizer industry activities was investigated. This is the first record of REE distribution in these organisms, and the results showed higher accumulations of these metals, U and Th in shells, probably related to the replacement of Ca during molting. Contents of Cd, Cr and Ni were similar in both tissues, but Cu, Zn and Pb were mostly accumulated in the claw muscle with concentrations above those considered safe for human consumption according to the Brazilian legislation. REE fractionation was different in the analyzed tissues being softer in the shells. The results provided evidences that the water absorbed during molting controls the chemistry of REE in shells. In contrast, the chemistry of REE in the claw muscle, in which was observed preferential absorption of light REE, is controlled by diet. REE fractionation obtained for the claw muscles was closely correlated to the observed in the contaminated substrate and in materials related to the production of phosphate fertilizers (contamination source), which supports their transference to this Ucides cordatus tissue without fractionation by the ingestion of sediments. Our results showed the potential use of crab tissues for monitoring REE and trace element sources in mangrove areas, with claw muscle exhibiting the contaminant source fingerprint. 相似文献