印铁涂装烘房有机废气的直接燃烧法处理实践

本文通过采用催化法和直燃法两种工艺处理印铁涂装生产的有机废气的工业实践,对设计和运行中的一些要点进行分析和探讨。     

大空间火灾烟气流动的动态显示研究

讨论了火灾烟气流动过程的计算机动态模拟方法。利用Ｄｅｌｐｈｉ可视化编程工具,建立了一个融区域模拟计算和计算机动态显示于一体的火灾发展的模拟软件,并以中国科技大学的大空间建筑火灾实验厅为对象,对典型火灾羽流及烟气层的发展过程进行了动态显示。     

民用建筑结构燃爆事故及防灾措施

收集了一些典型民用燃气爆炸事故的实例, 在此基础上对结构的破坏形式进行了分类,并分析了引起各种结构破坏的主要原因, 通过分析提出了防止结构破坏的具体措施     

Experimental study on the effect of fly ash content in cemented paste backfill on its anti-sulfate erosion

ABSTRACT

In order to study the effect of fly ash content in cemented paste backfill (CPB) on its anti-sulfate erosion, the apparent phenomenon, strength development, and hydration products change the law of CPB with different fly ash content under long-term soaking of 5% sodium sulfate solution were studied by the macrotest and microanalysis, in addition, the mechanism of CPB anti-sulfate attack was analyzed by combining with a scanning electron microscope (SEM). The results indicated that the effect of sulfate environment on the strength of fly ash cemented paste backfill (FCPB) was mainly determined by the hydration products in the FCPB at different soaking times. In the early soaking stage, the formation of ettringite (AFt) in FCPB could improve its compactness, which was conducive to improving the strength of FCPB. In the late soaking stage, there were ettringite-type erosion damage and gypsum erosion-type damage internal of the FCPB with low content fly ash, resulting in microfracture, cracking of the FCPB, and reducing the strength. CPB with an appropriate content of fly ash could improve the internal structure of the FCPB to achieve the purpose of anti-sulfate erosion.     

Effect of surfactants on solubilization and degradation of phenanthrene under thermophilic conditions

The bioavailability and biodegradation of polycyclic aromatic hydrocarbons (PAHs) can be increased through the addition of surfactants. Previous studies of this nature have been conducted under mesophilic conditions. Hence, the aim of the present study was to investigate the effects of synthetic surfactants and biosurfactants on solubilization and degradation of phenanthrene (PHE) in a series of batch solution experiments under thermophilic conditions. Tween 80, Triton X-100, and biosurfactants produced from Pseudomonas aeruginosa strain P-CG3 (P-CG3) and Pseudomonas aeruginosa ATCC 9027 (P. 9027) were used in this study. Surfactants effectively enhanced the solubility of PHE at 50 degrees C and the biosurfactant from P-CG3 was most effective with a 28-fold increase in apparent solubility of PHE at a concentration of 10 x critical micelle concentration (CMC) compared with the controls. However, addition of synthetic surfactants or biosurfactants inhibited the biodegradation of PHE in mineral salts medium by an isolate Bacillus sp. B-UM. Degradation of PHE diminished with increasing surfactant concentrations, and PHE degradation was completely inhibited for all the surfactants tested when the concentrations were greater than their respective CMC. The growth test suggested that Tween 80 and biosurfactants were degradable, but preferential utilization of these surfactants as substrates was not the mechanism for explaining the inhibition of PHE biodegradation. Because of the hydrophobic property of B-UM, degradation inhibition of PHE by surfactants was probably due to the reduction of direct contact between bacterial cells and PHE.     

高效生物处理技术在炼油厂碱渣废水处理中的应用

结合大港石化实际情况,在详细介绍柴油碱渣应用QBR高效生物处理技术取得成功的基础上,提出酸化回收粗酚或环烷酸并配套QBR、QBF等高效生物处理技术处理各种碱渣的新型工艺路线。经QBR处理后,出水COD去除率可达97%以上,石油类和挥发酚的去除率可达98%以上,硫化物去除率在99%以上。该技术的成功应用解决了困扰石化公司多年的碱渣废水处理的老大难问题,为炼厂碱渣废水乃至高浓度有机废水的处理开辟了一条新的途径。     

关于城市应急供水系统建设的思考

从城市应急供水系统建设的紧迫性和重要性出发,分析了目前我国城市应急供水系统存在的问题和造成城市非常供水的原因。构建了城市应急供水系统的框架,将其分成工程措施和非工程措施两部分,并阐述了工程措施的类型和实施方法,以及非工程措施的各项应急机制,对建立、健全城市应急供水系统进行了探讨。     

三江源生态移民对草地资源依赖性分析

基于移民、牧民访谈和问卷调查,对青海三江源泽库县生态移民的生活情况进行调查,分析移民对草地资源依赖性变化,以了解生态移民政策的成效与不足,并探讨现有政策中存在的相关问题,对三江源生态补偿政策和制度的制定完善提供参考和研究基础。研究结果显示:生态移民家庭经济收入有所提高,畜牧业收入占家庭总收入比例下降,生态补偿、务工、经商对于家庭收入的作用已明显显现。移民家庭从事畜牧业降为20.1%,务工家庭增加到37%,30.5%的移民参加过技能培训,但能源使用经济负担有所增加。53.90%的牧民愿意移民,但对移民后就业及生活设施建设仍有较大顾虑。总体而言,生态移民生活整体情况有所改观,移民后草地资源不再是家庭主要收入的基础。政府应完善技能培训体系,加快后续产业培育,重视生态移民工程前期规划,加大生态补偿资金支持力度。     

浅析生态文明理念对内蒙古草原旅游资源开发重要性

生态文明是继农业、工业文明之后,适应新形势而提出的.以直接解决与人类生存相关的生态问题为己任,用于指引人们实现可持续发展为目标.在内蒙古地区,草原是最具内蒙古特色和开发价值的资源,然而在近几十年的开发中严重违反了生态文明理念,以致出现草场退化、生物生存危机等状况.在当前内蒙古草原出现的严重问题的情况下,很有必要去探寻生态文明理念的重要价值.结合中国传统文化中天时地利人和的重要思想,实现在“因时制宜、因地制宜、以人为本及各方因素协调共促”理念下新的草原开发.     

Synthesis, crystal structure, photodegradation kinetics and photocatalytic activity of novel photocatalyst ZnBiYO4

ZnBiYO₄ was synthesized by a solid-state reaction method for the first time. The structural and photocatalytic properties of ZnBiYO₄ were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV-Vis diffuse reflectance. ZnBiYO₄ crystallized with a tetragonal spinel structure with space group I41/A. The lattice parameters for ZnBiYO₄ were a = b = 11.176479 Å and c= 10.014323 Å. The band gap of ZnBiYO₄ was estimated to be 1.58 eV. The photocatalytic activity of ZnBiYO₄ was assessed by photodegradation of methyl orange under visible light irradiation. The results showed that ZnBiYO₄ had higher catalytic activity compared with N-doped TiO₂ under the same experimental conditions using visible light irradiation. The photocatalytic degradation of methyl orange with ZnBiYO₄ or N-doped TiO₂ as catalyst followed first-order reaction kinetics, and the first-order rate constant was 0.01575 and 0.00416 min^-1 for ZnBiYO₄ and N-doped TiO₂, respectively. After visible light irradiation for 220 min with ZnBiYO₄ as catalyst, complete removal and mineralization of methyl orange were observed. The reduction of total organic carbon, formation of inorganic products, SO₄^2- and NO₃^-, and evolution of CO₂ revealed the continuous mineralization of methyl orange during the photocatalytic process. The intermediate products were identified using liquid chromatography- mass spectrometry. The ZnBiYO₄/(visible light) photocatalysis system was found to be suitable for textile industry wastewater treatment and could be used to solve other environmental chemical pollution problems.