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331.
Chandrinou S Stasinakis AS Thomaidis NS Nikolaou A Wegener JW 《Environment international》2007,33(2):226-232
Five bivalve species--Mytilus galloprovinciallis (Mediterranean mussels), Venus gallina (stripped venus), Modiola barbatus L. (bearded horse mussels), Pecten jacobeus (scallops) and Callista chione (hard clams)--were collected from seven areas in Aegean Sea, Greece, between August 2001 and January 2003 and analyzed for organotins (OTs). The concentrations (as geometric means) found were 17.1 ng g-1 for tributyltin (TBT), 18.8 ng g-1 for dibutytltin (DBT), 7.8 ng g-1 for monobutyltin (MBT) and 13.0 ng g-1 for triphenyltin (TPhT) (wet weight), which are at similar or lower levels than those reported worldwide. Studying OTs distribution between different bivalve species, lower concentrations were observed in mediterranean mussels, possibly due to their growth in water column (grown on sea net pens in mussel farms), in contrast to the free-ranging species, collected from fishing grounds. Concentrations of the OTs in the examined bivalves varied seasonally. 相似文献
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Mengnjo J. Wirmvem Takeshi Oh Wilson Y. Fantong Samuel N. Ayonghe Jonathan N. Hogarh Justice Y. Suil Asobo Nkengmatia E. Asaah Seigo Ooki Gregory Tanyileke Joseph V. Hell 《环境科学学报(英文版)》2014,26(4):801-809
Rainwater characteristics can reveal emissions from various anthropogenic and natural sources into the atmosphere. The physico-chemical characteristics of 44 monthly rainfall events (collected between January and December 2012) from 4 weather stations (Bamenda, Ndop plain, Ndawara and Kumbo) in the Bamenda Highlands (BH) were investigated. The purpose was to determine the sources of chemical species, their seasonal inputs and suitability of the rainwater for drinking. The mean pH of 5 indicated the slightly acidic nature of the rainwater. Average total dissolved solids (TDS) were low (6.7 mg/L), characteristic of unpolluted atmospheric moisture/air. Major ion concentrations (mg/L) were low and in the order K+ 〉 Ca2+ 〉 Mg2~ 〉 Na+ for cations and NO3 〉〉 HCO3 〉 SO] 〉 CI- 〉 PO3- 〉 F- for anions. The average rainwater in the area was mixed Ca-Mg-SO4-CI water type. The CI-/Na+ ratio (1.04) was comparable to that of seawater (1.16), an indication that N a+ and CI originated mainly from marine (Atlantic Ocean) aerosols. High enrichments of Ca2+, Mg2+ and SO2- to Na+ ratios relative to seawater ratios (constituting 44% of the total ions) demonstrated their terrigenous origin, mainly from Saharan and Sahelian arid dusts. The K+/Na+ ratio (2.24), which was similar to tropical vegetation ash (2.38), and NO3 was essentially from biomass burning. Light (〈 100 mm) pre-monsoon and post-monsoon convective rains were enriched in major ions than the heavy (〉 100 mm) monsoon rains, indicating a high contribution of major ions during the low convective showers. Despite the acidic nature, the TDS and major ion concentrations classified the rainwater as potable based on the WHO guidelines. 相似文献
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为提高颗粒活性炭同步去除水中铅、铬污染物的能力,分别使用氧化铁、氧化锰、十六烷基三甲基溴化铵(HTMAB)和氯化十六烷基吡啶(CPC)制作改性活性炭(Fe Cl3-AC,Mn O2-AC,HTMAB-AC,CPC-AC)。通过测定4种改性活性炭表面的等电点p H、酸碱官能团和扫描电子显微镜图像,研究4种改性活性炭吸附效果优异并分析其中原因。结果表明:Fe Cl3-AC同步去除铅、铬效果最佳,HTMAB-AC、CPC-AC与原炭效果持平,Mn O2-AC效果还不及原炭。从等电点p H来看,Fe Cl3-AC拥有较低的等电点p H,有利于静电吸附铬酸根阴离子团;从酸性基团数目来看,Fe Cl3-AC表面拥有较多酸性官能团,有利于离子交换作用,保证了对铅离子较高的吸附效率;从SEM来看,Fe Cl3-AC上Fe Cl3负载均匀,有效改善了活性炭表面特性,有利于吸附。 相似文献